Sharif Digital Repository

Synthesis of dextran-graft-poly(hydroxyethyl methacrylate) gels as a new fluoride biosorbent was considered in this work. For this propose, the Taguchi experimental design method was used for optimizing the synthetic conditions of the gels to reach high level of fluoride absorbency. The effects of three main parameters including concentrations of monomer (hydroxyethyl methacrylate), crosslinking agent (ethylene glycol dimethacrylate), and initiator (ammonium persulfate) on the final properties of the prepared gels were investigated. The proposed mechanism for grafting and chemically crosslinking reactions was proved with equilibrium water absorption, Fourier-transformed infrared, scanning... 

Burr in drilling plays an important role on product quality, so analysis the burr height is essential at the final production. This paper presents the application of Taguchi method for survey the burr height by adding ultrasonic vibration to the process. In this paper L18 orthogonal array based on Taguchi techniques was used in the design of experiments. Analysis of Variance (ANOVA) was used to determination the effect of drilling parameter on burr formation. Influence of spindle speed, feed rate and percentage of SiC particle was investigated in with and without ultrasonic assisted drilling. In this paper drilling of Al/SiCp MMCs with 5, 15 and 20 wt% of particulate SiC in dry drilling... 

In conventional grinding of hard to cut materials such as Ti6Al4V alloys, surface burning, redeposition and adhesion of chips to the grinding wheel and workpeice occur visibly unless it is carried out at low speeds and with high volume of cutting fluid. Ultrasonic assisted grinding is an efficient machining process which improves the machinability of hard-to-cut materials by changing the kinematics of the process. In this research, the effect of imposition of ultrasonic vibration on the grinding of Ti6Al4V alloy is studied. Longitudinal vibration at ultrasonic frequency range (20 kHz) is applied on the workpiece and machining forces and surface roughness are compared between conventional... 

The present study attempts to use the methanol-silver nanofluid filled heat pipe heat exchanger and compares the effectiveness as well as the energy saving with pure methanol. A heat pipe heat exchanger has been tested in a test rig under steady-state conditions. The lengths of both the evaporator and the condenser sections of the heat exchanger were 700 mm, and its central adiabatic section had a length of 160 mm. The heat exchanger had 36 plate finned copper thermosyphons arranged in three rows. The inlet air temperature across the evaporator section was varied in the range of 33-43 °C while the inlet air temperature to the condenser section was nearly constant to be 13 °C. First, pure... 

An experimental study of wear characteristics of electroless Ni-10% P coating sliding against hard AISI 52100 steel pin is investigated. Experiments are carried out at room and 550°C temperatures. Heat treatment effects on tribological behavior of this coating are studied. The wear surface and the microstructure of the coatings are analyzed using optical microscopy, scanning electron microscopy, energy dispersion analysis X-ray, and microhardness testing equipment. It is observed that the forming of continuous oxide film on contacting surfaces of pin and disk improves wear resistance and decreases friction coefficient of the Ni-10% P coating. The results indicate that the wear resistance of... 

A sonochemistry-based synthesis method was used to produce nanocrystalline nickel oxide powder with ∼20 nm average crystallite diameter from Ni(OH)2 precursor. Ultrasound waves were applied to the primary solution to intensify the Ni(OH)2 precipitation. Dried precipitates were calcined at 320 °C to form nanocrystalline NiO particles. The morphology of the produced powder was characterized by transmission electron microscopy. Using sonochemical waves resulted in lowering of the size of the nickel oxide crystallites. FT-IR spectroscopy and X-ray diffraction revealed high purity well-crystallized structure of the synthesized powder. Photoluminescence spectroscopy confirmed production of a wide... 

In this study, copper oxide nano particles were synthesized by batchwise supercritical hydrothermal method. After preparation of CuO nano particles, they were immobilized into the porous matrix of sodium alginate. The drying process formed a very porous structure that is useful for enhancing of adsorption activity. Produced CuO particles were characterized by X-ray diffractometery (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and BET for measuring the surface area. The prepared materials were then used as adsorbent in the removal of toxic metal ions in aqueous solution. To optimize the adsorption system, the effect of various parameters such as adsorbent... 

In this study operation of an optical design based on the intensity modulation for the refractive index change has been described. The reported instrument measures the transmitted output power depending up on the medium refractive index in the light path of a fiber-to-fiber design. A liquid cell is located between the fibers in the light path and power variations for different cold and hot water levels in the cell are measured. By using a reference humidity meter the calibration curve representing the relative humidity (%RH) as a function of the transmitted output power is obtained. For the hot water with the final temperature of T = 32.7°C the output power range of 255.0 -313.OnW is... 

Metal matrix composites (MMCs) have received considerable attention due to their excellent engineering properties. However, poor machinability has been the main deterrent to their substitution for metal parts. The hardness and abrasive nature of reinforcement phase causes rapid tool wear during machining which results in high machining costs. In this study, the effect of SiC particles (5, 15 & 20 percent) on tool wear in turning process is experimentally investigated. Continuous dry turning of Al/SiC particulate metal matrix composite produced by powder metallurgy and utilizing titanium carbide inserts has been achieved as the test method. The influence of machining parameters, e.g. cutting... 

Water resources limitation in arid and semi arid regions on one hand and water demand increase on the other, have made the optimum utilization of existing water resources and systems necessary. In this context, researchers are trying to increase the accuracy and lag time of prediction by using various statistic and empirical models as well as different local and long-range variables in the last decades. Karoon River is the greatest and most important river in Iran because of agricultural water demand supply and hydroelectric power production. Therefore streamflow prediction of this river has considerable economical and social benefits. In this study the relationship between Karoon stramflow... 

In this paper, the effect of different parameters on the thermal operation of a Closed Loop Pulsating Heat Pipe (CLPHP) has been investigated. These parameters include the working fluid, the inclination angle, the filling ratio, and the input heat flux. The effect of nanoparticle mass concentrations has been analyzed as well. It was observed that the CLPHP can decrease thermal resistance up to 11.5 times compared to the same empty copper tube with thermal resistance of 9.4 K/W. Optimum thermal operation for a system with the water-silver nanofluid was achieved at conditions of the 50% filling ratio with thermal resistance of 0.9 K/W, and for the water-titanium oxide system, the optimal... 

Alumina-zirconia nanostructured coatings were formed on 7075 Al alloy through Plasma Electrolytic Oxidation (PEO) operated in aDC potentiostatic mode. The composite coatings were produced in the range of 425-500 V in an alkaline electrolyte containing 4 g/LK2ZrF6. Tribological properties of coatings were investigated using dry sliding wear test against WC balls with a pin-on-disc tribometer. Wear rates were evaluated using optical profilometer. It was shown that the nanostructured alumina-zirconia composite coatings can be formed at voltages 450 V. The coating thickness and roughness were in the range of 15.2-24.2 μm and 0.68-2.35 μm, respectively. The distribution of Al, Zr and O in the... 

We fabricated gas sensors based on field ionization from multiwalled carbon nanotube (MWCNT) arrays grown on porous silicon templates. MWCNTs were grown through thermal chemical vapor deposition. We measured breakdown voltages, discharge and pre-discharge currents of the device for various gases in different concentrations. Our gas ionization sensors (GIS) presented good sensitivity, selectivity and short response time. The GISs based on porous substrates showed higher discharge current and good mechanical stability in comparison to those which were fabricated on polished silicon substrates. Additionally, we applied a high electric field to align CNTs. This increased the pre-breakdown... 

Multi-Walled Carbon nanotube (MWCNTs) films were obtained by Thermal Chemical Vapor Deposition method and coated by palladium sputtering process. Raman spectroscopy was used to study alteration in quality of the carbon nanotubes after the sputtering process. Fourier Transform Infra Red (FTIR) spectroscopy showed that hydrogenation process can reduce the C{double bond, long}O to C-O and also produce O-H bond. Furthermore, the electrical resistance measurement for Pd/MWNTs films was performed in a chamber with 1% hydrogen gas in a constant dry air flow. Hydrogen sensing behavior of the films was investigated at 50 °C. Pd/MWCNTs films presented an irreversible gas response to hydrogen in the... 

In this paper, the stick-slip motion of a microrobot with two perpendicular vibrational actuators is studied. This motion is based on the friction drive principle. To determine the effective parameters in the motion of microrobot, the equations of motion of the microrobot are derived. To simplify the equations for determining the design parameters, the vibrational actuators are modeled with two perpendicular harmonic forces. To study the motion dynamics of the microrobot, its equation of motion is derived in a nondimensional expression by defining the nondimensional effective parameters. The Fourier expansion (F.E.) method is used to analyze the numerical results and it showed some... 

In this paper, the effect of several different parameters on the thermal resistance of a Closed Loop Pulsating Heat Pipe (CLPHP) has been investigated. These parameters include the working fluid, the inclination angle, the filling ratio and the heat influx. Also, the impact of using nanofluids with different nano-particle concentrations has been analyzed. It was observed that a CLPHP can increase the heat transfer up to 11.5 times compared to an empty pipe. Optimum performance for a system with the water-silver nanofluid was achieved at conditions of 50% filling ratio and 0.9 K/W of thermal resistance, and for the water-titanium oxide system, these optimal conditions were found to be 40%... 

The asphalt industry has been at the forefront of sustainable development. Warm Mix Asphalt (WMA) has been developed to cope with issues such as high energy prices and air pollution. These mixes require less energy and generate fewer pollutants during production in comparison with conventional Hot Mix Asphalt (HMA). Although a promising technology, the durability of WMA is not clear because long-term WMA field performance data is limited. This study investigated the susceptibility of Sasobit-modified WMA to moisture, since moisture damage is a major cause of premature pavement failure in asphalt concrete. To this end, WMA samples were made using different concentrations of Sasobit and the...