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    Accurate analytical model for determination of effective diffusion coefficient of polymer electrolyte fuel cells by designing compact Loschmidt cells

    , Article Fuel ; Volume 199 , 2017 , Pages 551-561 ; 00162361 (ISSN) Izadmehr, M ; Abbasi, M ; Mansouri, M ; Kazemi, A ; Nakhaee, A ; Daryasafar, A ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    Effective diffusion coefficient is an important parameter which needs to be determined in different fields of study, such as cathode catalyst layers of PEM fuel. For this purpose, a Loschmidt diffusion cell can be used. When a porous medium is placed in Loschmidt apparatus, the effective gas diffusion coefficient (EGDC) of this section must be correlated by diffusion coefficient in absence of a porous medium. In the previous researches studying the Loschmidt diffusion cell, a simplifying infinite-length assumption was used in the analytical solution. Therefore, the solution is only applicable for a short time range, and this can result in high error. In order to overcome this challenge, the...