Sharif Digital Repository

CeO 2-TiO 2 nanoparticles were prepared by the sol-gel process using 2-hydroxylethylammonium formate as room-temperature ionic liquid and calcined at different temperatures (500-700°C). CeO 2-TiO 2-graphene nanocomposites were prepared by hydrothermal reaction of graphene oxide with CeO 2-TiO 2 nanoparticles in aqueous solution of ethanol. The photocatalysts were characterized by X-ray diffraction, BET surface area, diffuse reflectance spectroscopy, scanning electron microscopy, and Fourier transformed infrared techniques. The results demonstrate that the room-temperature ionic liquid inhibits the anatase-rutile phase transformation. This effect was promoted by addition of CeO 2 to TiO 2.... 

Functionally graded cemented carbonitrides (FGCCs) are applied in cutting tools industry. Indexable inserts made from mentioned alloys have superior cutting performance and tool life thanks the formation of a surface modified layer with enhanced properties as well as crater wear resistance. Cemented carbonitrides are made of hard carbide/nitride/carbonitride particles that have been embedded in a metallic binder. Excellent wetting ability of tungsten carbide with cobalt has made this metal the first choice as binder. However, cobalt has high cost and environmental pollution impacts. Substitution of cobalt with other metals has always been figured out. Some other metals that have been used as... 

A new method has been employed in this research that optimizes a power generation system by maximizing the first and second law efficiencies and minimizing the entropy generation. Mass flow rates of pollutants and related external social cost of air pollution have been considered in estimating the electricity production cost. The effects of regenerative and CHP heat exchangers on power production, efficiencies, and production cost have been evaluated. The results show that a single regenerative heat exchanger lowers NOx, CO, and CO 2 emissions by 15%, 40%, and 0.4%, respectively, and decreases the electricity production cost by nearly 18%. A single CHP heat exchanger has little influence on... 

Adaptation of Penicillium simplicissimum with different heavy metals present in a spent hydrocracking catalyst, as well as one-step, two-step, and spent medium bioleaching of the spent catalyst by the adapted fungus, was examined in batch cultures. Adaptation experiments with the single metal ions Ni, Mo, Fe, and W showed that the fungus could tolerate up to 1500. mg/L Ni, 8000. mg/L Mo, 3000. mg/L Fe, and 8000. mg/L W. In the presence of multi-metals, the fungus was able to tolerate up to 300. mg/L Ni, 200. mg/L Mo, 150. mg/L Fe and 2500. mg/L W. A total of 3% (w/v) spent catalyst generally gave the maximum extraction yields in the two-step bioleaching process (100% of W, 100% of Fe, 92.7%... 

Increasing concerns about the lack of energy resources, global warming and environmental pollution have pushed the relevant organizations to develop energy saving strategies such as energy labeling programs. In this research, a new energy labeling program is developed and evaluated for the wet cooling towers in Iran. The cooling tower parameters, including its cooling capacity and the fan power consumption, are measured using an experimental setup. The experimental data are standardized to compensate the effect of the ambient wet bulb temperature on the cooling tower performance which cannot be controlled during the experiments. The results show that the cooling tower capacity and the fan... 

Since ultraviolet (UV) irradiation cannot be applied for a long time in practical applications, it is necessary to develop a narrow band gap photocatalyst to decompose environmental pollutants under visible irradiation. In this research, (WO3)x-(TiO2)1-x nano-porous layers were fabricated by micro arc oxidation (MAO) and influence of the electrical current type on their physical and chemical properties was investigated. Morphological studies, performed by SEM technique, revealed that pore size and roughness decreased with the frequency and increased with the duty cycle. The pulse-grown layers had a finer structure when compared to those fabricated under direct current. XRD and XPS results... 

When latent heat is transferred in a heat exchanger network, the formation of the second phase creates an opportunity for separation. This network is known as a Heat Induced Separation Network (HISEN). HISENs have been extended to include pressure adjusting devices for improving the thermodynamic feasibility of the network. This extended network is termed an Energy Induced Separation Network (EISEN). Most examples of EISENs in the literature are environmental pollution treatment case studies which do not require liquid phase mass integration or shaft power integration. They assume a predetermined extent of separation and mostly are based on conceptual methods of design. This paper explains... 

In this paper, the effect of wind power generation on power system reliability is investigated. Furthermore, reliability improvement of power system using integrated battery energy storage system and wind farm will be evaluated. Growing demand for electrical energy, gradual diminishing of fossil fuel resources and environmental pollution due to continuous exploitation of them, have led to inevitable change of energy sources in power generation. Due to the random nature of wind speed, the power output of a wind farm is fluctuating; as a result, it does not have a proper control capability. The growing penetration of wind power generation in power system could cause various problems in... 

Ethylene glycol is an environmental pollutant, which exists in airport runoff and industrial waste. In this article, biodegradation of ethylene glycol in a two-chamber, batch-mode microbial fuel cell was investigated. Glucose and ethylene glycol at different concentrations were used as carbon and energy sources. Chemical oxygen demand removal in the range of 92-98% indicated that microbial fuel cell can be used for biodegradation of ethylene glycol. Ethylene glycol also improved power generation and the maximum power density was 5.72 mW/m2 (137.32 mW/m3), with respect to the same glucose and ethylene glycol concentrations (500 ppm)  

Increasing concerns about global warming and environmental pollution control has pushed the relevant organizations to set regulations and to develop programs for energy saving. In addition, for many high energy using appliances, energy labeling provides the end user with important data to select energy-efficient equipments and encourage the manufacturers to enhance the performance of their productions. In this research, a new energy-saving program for wet cooling towers has been developed. Considering a thermo-hydraulic analysis, a novel Energy Index (IE) has been extracted which takes all aspects of the problem into account. The present index can be used as a proper criterion for energy... 

In this study, the optimal sizing and performance analysis of a standalone integrated solar power system equipped with different storage scenarios to supply the power demand of a household is presented. One of the main purposes when applying solar energy resource is to face the increasing environmental pollutions resulting from fossil fuel based electricity sector. To this end, and to compare and examine two energy storage technologies (battery and hydrogen storage technology), three storage scenarios including battery only, hydrogen storage technology only and hybrid storage options are evaluated. An optimization framework based on Energy Hub concept is used to determine the optimum sizes... 

Environmental degradation due to economic activities is a key challenge facing sustainable development. The fossil fuel production sector is a very polluting industry. In this research, the future trends of pollution accumulation in the region due to direct/indirect oily discharge into the semi-enclosed area of the Persian Gulf are studied. The purpose of the study was not only to alert policy-makers about potential future threats in the region but also to conduct a trial to develop potential solutions to these problems. Four different environmental cases were studied via the principle of system dynamic modeling simulation. The cases consisted of three situations: relaxed, simple policy, and... 

Limited fossil resources, daily increasing rate of demand for energy and the environmental pollution fact have made people revert to renewable sources of energy as a solution. One type of renewable energy is offshore wind energy which has high potential without any sound and visual noises. Recently, a lot of researchers have carried out on the issue of offshore wind turbine. Because of incapability of most of software programs to simulate gyroscopic effect of rotating rotors, in this articles a significant effort has been made to fabricate and test an offshore wind turbine under different rotor rotation velocities and different heading angle of wind so as to obtain the effects of these... 

E-waste has become one of the greatest sources of environmental pollution. Bioleaching is known as a new, simple, and environmentally friendly technology for metal recovery requiring low energy input, unskilled labor operations, moderate conditions, and low costs. Acidithiobacillus ferrooxidans is a famous and puissant mesophilic bacterium applied extensively to recover metals from ores and different industrial and municipal wastes. It is necessary to identify the parameters affecting consumers E-waste recycling. Separating and recovering different types of E-waste is impossible for small recycling units. There should be a specific combination of E-waste, enabling the extraction of the... 

Hexagonal core–shell SiO2[–MOYI]Cl–]Ag nanoframeworks were synthesized via surface modification of hexagonal silica nanoparticles prepared from perlite (EP) as a cheap and abundant raw material. The prepared samples were well characterized by X-ray diffraction powder (XRD), energy dispersive X-ray (EDX), diffuse reflectance spectroscopy (DRS), Brunauer–Emmett–Teller (BET) specific surface area analysis, fourier transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). The XRD patterns confirmed that Ag and AgCl crystalline phases were successfully loaded on the surface. The TEM images were also implied that the... 

Energy developments plays a crucial role in the political power, economic growth, social development and environmental degradation of developing countries. Energy consumption in residential sector is an essential issue for providing a large variety of services that are necessary for social life tasks such as heating, cooling, and lighting. Therefore, there is a need for depiction of energy outlook and selection of appropriate strategies as the main pillars of economic and political stability in each society. The main objective of this research is to design and apply a methodology that helps decision makers for simulation, optimization and analysis of the residential sector energy system. The... 

Activated carbon (AC) is an inert adsorbent material that has widely been used in water treatment or removing of environmental pollutants from water. In order to improve the adsorption of AC, which highly depends on its pore size and surface area, we prepared highly porous adsorbent composites of activated carbon (AC)/chromium-based MOF (MIL-101(Cr)). The composite has a high specific surface area of 2440 m2 g−1 and total pore volume of 1.27 cm3 g−1. To show the efficiency of the composite as an adsorbent, the removal kinetics of anionic dyes (Direct Red 31 and Acid Blue 92) from aqueous solutions dependent on the amount of composite, adsorption time, concentration of dye and pH is... 

Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF–5 families were chosen, and eleven MOF–based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL–101 and MIL–101–NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc–based structures including MOF–5, [NH2(CH3)2]2... 

Environmental pollutions with heavy metals pose serious health and ecological risks. Sabzevar in the northeast of Iran has natural chromic mines and then chromium-polluted soils and groundwater. In the present work, the metal-tolerant bacterial strain KR2 was identified as Shewanella sp. following 16S rDNA gene sequence analysis. Bioremediation ability of isolated bacterial from agricultural soils that irrigated by groundwater, Shewanella sp., was evaluated for uptaking of chromium with varying Cr(VI) concentrations from 50 to 500 ppm in aerobic conditions (pH 7.0, 37 °C). The Shewanella sp. strain KR2 showed an obvious heavy metal tolerant in the wide range of heavy metals including: Cr6+,...