Sharif Digital Repository

Cylindrical pipes are installed to a line-focusing solar system with a linear receiver tube for transmitting thermal energy to the working fluid. In this study, the effects of a novel forward ring step inside circular pipes on the heat transfer performance of linear solar receiver tubes were investigated using computational fluid dynamics. The rings are perforated, and their cross section is triangular. Although the applied heat flux is consistent with a solar collector with a linear receiver tube, the analysis can be performed for any given heat flux distribution on circular pipes. The model was verified by comparing the predicted Nusselt numbers to those of the Gnielinski correlation, and... 

A novel thermosensitive hydrogel was synthesized by block copolymerization of monomethoxy poly(ethylene glycol) macromere (PEG) onto chitosan backbone, using potassium per sulfate as a free radical initiator. This block copolymer exhibits a thermoreversible transition from an injectable solution at low temperature to a gel at body temperature. Synthesized copolymers were characterized using FT-IR, 1H NMR, 13C NMR, and DSC techniques. Solubility test was performed to compare water and organo-solubility of chitosan before and after copolymerization. Sol-gel transition behavior was investigated using the vial inversion method and viscosity measurements. The gelation behavior makes the... 

In the present study, a new swirling flow generator is studied which aims to enhance the convective heat transfer rate in a heat exchanger tube. This device has a four-point star cross section. The study mainly investigates the effect of swirl generator on heat transfer rate and pressure drop along the test tube which is under a constant and uniform heat flux. The working fluid in the experiments is the water–ethylene glycol mixtures with Prandtl numbers ranging from 5 to 150 at different Reynolds numbers from 12,000 to 27,000. The results clarify the potential of the applied swirl generator to make a significant enhancement in the heat transfer rate with a satisfactory rise in the pressure... 

Ethylene dichloride thermal cracking is one of the conventional methods for hydrogen chloride production. A critical issue concerned with this method is to provide thermal energy for cracking reaction, which is generally provided by the flammable gasses inside the furnace. Utilizing renewable energy sources can be an interesting topic in this case. Hence, in this paper, the thermal integration feasibility of an ethylene dichloride cracking unit with a hybrid renewable plant, based on geothermal and wind energies, is investigated, while the case study for wind turbines system (Alstom ECO 74/1670/ Class II model) is Meshkin Shahr, located in Iran. To utilize geothermal energy, a... 

Hybrid nanoparticles possess better chemical stability, mechanical resistance, thermal conductivity, physical strength and so forth as equated to pure nanoparticles. The present work describes the novel features of hybrid nanoparticles such as Titanium oxide (TiO2) and Copper (Cu) in the flow of Ethylene glycol (EG) under the induced magnetic field environment. The analysis covers the features of both pure nanofluid Cu/EG and hybrid nanofluid Cu-TiO2/EG. The concentration equation is amended by the activation energy term. The amalgamation of Cu-TiO2/EG exhibits improved and embellished thermal characteristics. A persuasive numerical technique named “Successive over Relaxation” is used to... 

Hybrid nanoparticles possess better chemical stability, mechanical resistance, thermal conductivity, physical strength and so forth as equated to pure nanoparticles. The present work describes the novel features of hybrid nanoparticles such as Titanium oxide (TiO2) and Copper (Cu) in the flow of Ethylene glycol (EG) under the induced magnetic field environment. The analysis covers the features of both pure nanofluid Cu/EG and hybrid nanofluid Cu-TiO2/EG. The concentration equation is amended by the activation energy term. The amalgamation of Cu-TiO2/EG exhibits improved and embellished thermal characteristics. A persuasive numerical technique named “Successive over Relaxation” is used to... 

In this study, the performance of a Photovoltaic Thermal-Organic Rankine Cycle (PVT-ORC) system combined with a Proton Exchange Membrane Electrolysis Cell (PEMEC) is investigated. A combined numerical/theoretical model of the system is developed and used to evaluate the effect of various system design parameters. In addition, the effects of using water, ethylene glycol, and a mixture of water and ethylene glycol (50/50) as the working fluid of the PVT system and R134a, R410a, and R407c as the working fluid of the ORC cycle on the performance of the PVT-ORC-PEMEC system are studied. Based on the results, R134a and water demonstrated the best performance as the working fluid of the ORC and PVT... 

A series of biodegradable acrylic terminated polyurethanes (APUs) based on poly(ε-caprolactone) diol (PCL), aliphatic 1,6-hexamethylene diisocyanate (HDI) and hydroxyethyl methyl acrylate (HEMA) was synthesized as potential materials for hard tissue biomedical applications. PCLs with low molecular weights of 1000 and 2000 g/mol were employed to provide different amounts of end capped urethane acrylate in APUs. To control crosslink density, a mixture of two different reactive diluents including mono-functional HEMA and bi-functional ethylene glycol dimethacrylate (EGDMA) with different weight ratios was incorporated into the APUs, called here PUAs. Morphological characteristics and mechanical... 

Surface-modified magnetite (Fe3O4) nanoparticles with an average size of 22 nm were prepared. The nanoparticles had a saturation magnetization of 50.7 emu g-1. Then magnetite and drug-loaded microspheres of poly (lactic acid)/poly (ethylene glycol) were prepared at various compositions. The microspheres were spherical in shape and had smooth surface. The diameter size of the microspheres ranged between about 0.2 and 4 μm. Doxorubicin hydrochloride for cancer treatment was the drug that loaded into the microspheres. The prepared microspheres were characterized by FTIR, XRD, VSM, SEM and drug-release measurements. It was found that the drug cumulative release percentage was proportional to... 

A novel high-throughput device based on 96-micro-solid phase extraction (96-μ-SPE) system was constructed for multiresidue determination of nine pesticides in aquatic samples. The extraction procedure was performed on a commercially available 96-well plate system. The extraction module consisted of 96 pieces of 1cm×3cm of cylindrically shaped stainless steel meshes. The prepared meshes were fixed in a home-made polytetrafluoroethylene-based constructed ninety-six holes block for possible simultaneous immersion of meshes into the center of individual wells. Dodecyl methacrylate and ethylene glycol dimethacrylate was copolymerized as a monolithic polymer and placed in the cylindrically shaped... 

The reaction pathway (including the transition state) of ethylene addition to permanganate (MnO4-) in the presence of ethylene glycol (EG) has been qualitatively and quantitatively studied by means of B3LYP/6-311++G* theoretical analysis. Interestingly, by cluster formation of the EG with permanganate, oxidation reaction becomes thermodynamically and kinetically more favorable. The influences of electron-withdrawing as well as electron-donating substituents were also explored. Results of the quantum theory of atoms in molecules and natural bond orbital analyses revealed that [3 + 2] addition reaction of alkenes in the presence of EG as hydrogen bonding donor to MnO4- becomes more exothermic.... 

The adsorption of chromium compounds from solutions by a composite of polyaniline/poly ethylene glycol (PANi/PEG) was investigated in this study. Experiments were conducted in batch mode under various operational conditions including agitation time, solution pH, PANi/PEG dose and initial concentration of chromium salts. Results showed that concentration of PEG at synthesizing stage has a significant effect on the capacity of produced composite for removal of chromium. Morphologically, PANi/PEG composite is closely dependent on the concentration of PEG. Maximum removal of hexavalent chromium was experienced when 2. g/L of PEG was used in synthesis of PANi/PEG. Removal of hexavalent chromium... 

Inkjet printing of colloidal metals is an attractive method for direct patterning of electrically conductive structures and interconnects in electronic devices, owing to low-cost, low-waste and simplicity of the process. In the present work, mixtures of well-dispersed silver nanoparticles and ethylene glycol were prepared for the inkjet printing process. Three different surfactants including PVP, MSA and AOT were added to study the stability of the nanosilver colloids. The effect of high-intensity ultrasonic treatment and temperature on the rheological properties was investigated utilising a rheometer in plate-plate geometry. It is shown that the viscosity of the ink increases with... 

Homopolymer hydrogel of 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and its nanocomposite counterpart were prepared to study their swelling properties. The hydrogels showed ability to absorb and retain electrolytes as well as binary mixtures of water and organic solvents (i.e., methanol, ethanol, acetone, ethylene glycol (EG), polyethylene glycol, N-methyl-2-pyrrolidone (NMP), and dimethylsulfoxide (DMSO). The nanocomposite gel exhibited lower swelling in all solvent compositions in comparison with non-composite gel. Unlike conventional acrylic acid-based hydrogels, the poly(AMPS) gels showed superabsorbing capacity in pure ethanol, methanol, EG, DMSO and NMP. Meanwhile, swelling... 

In this work, an artificial neural network model was used to obtain the partition coefficients of biomolecules in polymer-polymer aqueous two-phase systems. In the artificial neural network, the partition coefficient of a biomolecule depends on the difference between concentrations of poly (ethylene glycol), dextran in the top and bottom phases, temperature and molecular weights of poly (ethylene glycol), dextran, and the biomolecule. The network topology is optimized and the (6-1-1) architecture is found using optimization of an objective function with sequential quadratic programming (SQP) method for 450 experimental data points. The results obtained from the neural network of the... 

Linear-dendritic ABA triblock copolymers containing poly(ethylene glycol) (PEG) as B block and hyperbranched poly(citric acid) (PCA) as A blocks were synthesized through polycondensation. The molecular self-assembly of synthesized PCA-PEG-PCA copolymers in water led to formation of nanoparticles and fibers in different sizes and shapes depending on the time and size of PCA blocks. Ten days after dissolving PCA-PEG-PCA copolymers in water, the size of fibers had reached several millimeters. Mixing a water solution of fluorescein as a small guest molecule and PCA-PEG-PCA copolymers led to the encapsulation of fluorescein by products of molecular self-assembly. To investigate their potential... 

A template-directed synthetic method, using surfactant cetyltrimethylammonium bromide (CTAB) as a template and co-surfactant polyethylene glycol (PEG600) as a co-template under hydrothermal conditions, has been applied to obtain dandelion-like HAp. The morphology, size, crystalline phase, chemical composition, physical characteristics, and thermal behavior of the product were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), Fourier ransform infrared spectroscopy (FTIR), induced coupled plasma spectroscopy (ICP), BET (Brunauer, Emmett, and Teller) method, and simultaneous thermal analysis (STA). SEM and TEM... 

As the use of superparamagnetic iron oxide nanoparticles (SPION) in biomedical applications increases (e.g. for targeting drug delivery and imaging), patients are likely to be exposed to products containing SPION. Despite their high biomedical importance, toxicity data for SPION are limited to date. The aim of this study is to investigate the cytotoxicity of SPION and its ability to change cell medium components. Bare and poly(ethylene glycol)-co-fumarate (PEGF)-coated SPION with narrow size distributions were synthesized. The particles were prepared by co-precipitation using ferric and ferrous salts with a molar Fe3+/Fe2+ ratio of 2. Dulbecco's modified Eagle's medium (DMEM) and primary... 

A new technique for preparation of an unbreakable solid-phase microextraction (SPME) fiber, using sol-gel technology is developed. Primarily, an ultrathin two-dimensional intermediate film was prepared by hydrolysis of 3-(trimethoxysilyl)-1-propanthiol self-assembled monolayer grafted onto gold, then a stationary phase by electrodeposition of 3-(trimethoxysilyl) propylmethacrylate as a precursor, tetramethyl orthosilicate and polyethylene glycol as a coating polymer was produced. The scanning electron microscopy images revealed that the new fiber exhibits a rather porous and homogenous surface. The thermal stability of the fabricated fiber was investigated by thermogravimetric analysis. The...