Sharif Digital Repository

In recent years, the need to reduce environmental impacts and increase flexibility in the energy sector has led to increased penetration of renewable energy sources and the shift from concentrated to decentralized generation. A fuel cell is an instrument that produces electricity by chemical reaction. Fuel cells are a promising technology for ultimate energy conversion and energy generation. We see that this system is integrated, where we find that the wind and photovoltaic energy system is complementary between them, because not all days are sunny, windy, or night, so we see that this system has higher reliability to provide continuous generation. At low load hours, PV and electrolysis... 

In recent years, the need to reduce environmental impacts and increase flexibility in the energy sector has led to increased penetration of renewable energy sources and the shift from concentrated to decentralized generation. A fuel cell is an instrument that produces electricity by chemical reaction. Fuel cells are a promising technology for ultimate energy conversion and energy generation. We see that this system is integrated, where we find that the wind and photovoltaic energy system is complementary between them, because not all days are sunny, windy, or night, so we see that this system has higher reliability to provide continuous generation. At low load hours, PV and electrolysis... 

Used lubricating oil (ULO) is a heavy mixture of various hydrocarbons and needs to be treated before discharging. Considering ULO nature, it is more favorable to recover lighter hydrocarbon cuts from ULO, which not only improves the whole process economically, but also prevents the emission of hardly decomposable hydrocarbons into the environment. In this research, the potential of pyrolysis method for ULO recovery was studied. Furthermore, graphene nanoplatelets (GNP), γ- Fe2O3 and ZnO nanoparticles were used to improve the kinetics of the process and their impacts on the final product quality were evaluated. Based on the results, adding nanomaterials increased the tendency to produce gas... 

The fast growth of technologies most of which depend on natural sources of energy has resulted in a huge consumption of fossil fuels. In this regard, many solutions have been suggested to alleviate the side effects such as air pollution and global warming. Among these solutions, mobile storages like electric vehicles (EVs) and renewable generations, have grown significantly due to being more applicable. But uncoordinated operation and uncertain nature of these distributed energy resources (DERs) can bring forward new challenges and issues to the operators of power system. Thus, in many cases it is more efficient to co-operate them in a hybrid system. In this study, we address a virtual power... 

Worldwide energy and environmental issues are forcing researchers to develop a green approach to produce a clean energy. However, traditional methods in reforming of fossil fuels to produce hydrogen (H2) are causing CO2 emission. Hydrogen is therefore an indirect greenhouse gas with a global warming potential. Hydrogen with high specific energy density can be considered as an efficient energy carrier as compared to fossil fuels. But hydrogen production from water splitting reaction has low efficiency, which limits its generation by green approach. For addressing this issue, different chemical hole scavengers have been applied, which is causing further environmental and economic problems. By... 

A remote controllable working graphite nanostructured swimmer based on a graphene jet nanomotor has been demonstrated for the first time. Graphite particles with pyramidal-like morphologies were fabricated by the creation of suitable defects in wide high-purity graphite flakes followed by a severe sonication. The particles were able to be self-exfoliated in water after Na intercalation between the graphene constituents. The self-exfoliation resulted in jet ejection of graphene flakes from the end of the swimmers (with speeds as high as ∼7000 m/s), producing a driving force (at least ∼0.7 L (pN) where L (μm) is swimmer size) and consequently the motion of the swimmer (with average speed of... 

The present study was aimed at performance and energy analysis of a hybrid wind-hydrogen power system. Such system consists of wind turbines, batteries for the short time energy storage, electrolyzer, fuel cell and hydrogen tank for long time energy storage. The proposed configuration is used to supply energy demand of a region with discrete seasonal wind speed regime. Temporary wind energy profiles restrict using batteries for electricity storage as they lose much electrical stored energy for the long time. Based on direct wind turbine usage, batteries and hydrogen storage, different energy supply strategies are introduced and analyzed to power the household electricity demand. The energy... 

Performance of polymer electrolyte membrane fuel cells (PEMFC) at high current densities is limited to transport reactants and products. Furthermore, large amounts of water are generated and may be condensed due to the low temperature of the PEMFC. Development of a two-phase flow model is necessary in order to predict water flooding and its effects on the PEMFC performance. In this paper, a multiphase mixture model (M2) is used, accurately, to model two-phase transport in porous media of a PEMFC. The cathode side, which includes channel, gas diffusion layer (GDL), microporous layer (MPL), and catalyst layer (CL), is considered as the computational domain. A multidomain approach has been used... 

A gas turbine shaft is generally exposed to high-temperature gases and may seriously be affected and overheated duetotemperature fluctuationsinthe combustion chamber. Vortex flow inthe combustion chamber may increase the heat release rate and combustion efficiency, as well as control the location of energy release. However, this may result in excessive temperature on the combustor equipment and gas turbine shaft. In this study, a new gas turbine combustion chamber implementing a liner around the shaft and the liquid-fuel feeding system is designed and fabricated. The influences of parameters such as the Reynolds number and the equivalence ratio are studied. Experimental results are compared... 

Gas turbine shaft is generally exposed to high temperature gases and may seriously be affected and overheated due to temperature fluctuations in the combustion chamber. Considering vortex flow in the combustion chamber, it may increase the heat release rate and combustion efficiency and also control location of energy release. However, this may result in excess temperature on the combustor equipments and gas turbine shaft. Vortex flow in the vortex engine which is created by the geometry of combustion chamber and conditions of flow field is a bidirectional swirl flow that maintains the chamber wall cool. In this study a new gas turbine combustion chamber implementing a liner around the shaft... 

A soil microbial fuel cell was investigated that uses soil and groundwater to generate electricity. The cathode surface area and materials are always important for increasing power. Power density was shown to be a linear function of cathode surface area. Biofilm formation on the graphite cathode was observed to be helpful in enhancing power output and maximum performance reached 89.2 mW/m2. As an application for the insertion-type soil microbial fuel cell, nitrate removing was investigated in cathode. Nitrate was reduced in an aerobic cathode at the rate of 37.5 mg nitrate/lit/day and 55 mg nitrate/lit/day in anaerobic cathode  

Continuing an ongoing study, molecular dynamics (MD) simulations were performed to investigate the effects of methanol concentration on Nafion morphology, such as the size of solvent cluster, solvent location, and polymer structure via the sandwich model. Our survey shows that high methanol concentrations resulted in increment of solvent cluster size in Nafion membrane. The sulfonic acid clusters also befall much in order as subsequent layers of such ionic clusters are formed. The number of neighbouring hydronium ions around a sulfur atom is independent of methanol concentration, but the first shell of hydronium and water around sulfonic acid clusters is broader. Although methanol would... 

Molecular dynamics simulations are performed to obtain insight into the structural properties of hydrated Nafion using the sandwich model of the polymer membrane. It is shown that a larger distance between the sulfonate groups of a chain leads to the polymer forming a better inverted micelles structure. Water- and hydronium-polymer interfaces are investigated. Comparing our results with others indicates that, from the perspective of distance, the formation of shells of water and hydronium ions is independent of the model and monomer type, but depends on both if the coordination number is considered. The behaviour of water molecules and hydronium ions is also studied dynamically. Our survey... 

In pebble bed reactors, the core is filled with thousands of graphite and fuel pebbles. Fuel pebbles in these reactors consist of TRISO particles, which are embedded in a graphite matrix stochastically. The reactor core is also stochastically filled with pebbles. These two stochastic geometries comprise the so-called double heterogeneous nature of this type of reactor. In this paper, a pebble bed reactor, the HTR-10, is used to demonstrate a treatment of this double heterogeneity using the MCNP5 Monte Carlo code and MATLAB programming. In this technique, TRISO particles are modeled in a pebble using the expanded FILL and LATTICE features of MCNP5. MATLAB is used to generate random numbers... 

Electrical energy is very necessary for human life in the modern era. The rising energy prices, depletion of fossil fuels, and instability of the grid are alarming situations. So, it needs a smart solution to ensure the balance between pricing and saving natural resources. Some other issues like environmental change, limitations on installation of new transmission lines, reliability concerns, and considering the expansion in distributed energy generation technologies promise the implementation of distributed generation extensively. The integration of two or more energy supplies in a power system is known as distributed energy resource system. In this study, a university campus is taken as a... 

TiO2 has a high bandgap energy with light absorption in the ultraviolet region making it non-efficient under visible-light. The purpose of the present work is to modify the properties of TiO2 by adding carbon and copper to its structure, in order to acquire an active nanostructure for photocatalytic oxidative desulfurization of model liquid fuel under visible light irradiation. In this regard, carbon doped TiO2 was first synthesized by a hydrothermal method, then Cu (II) were impregnated on carbon doped TiO2. The resulting photocatalysts were characterized by techniques such as XRD, N2 physisorption, SEM, TEM, DRS, EDX, PL, and FTIR. The effects of parameters including calcination... 

Pool fire modeling and risk assessment is very important and essential especially in systems with large flammable fuel inventories, e.g., refineries, offshore oil platforms, or fuel transportation systems. Results obtained from pool fire risk assessment can be used in setting up safety measure or emergency planning. Pool fire modeling is used to evaluate the heat flux at various target points around the fire source. The two major approaches in pool fire modeling are semi-empirical models and Computational Fluid Dynamics (CFD), which are called field models. Semi-empirical models are based on correlations fitted to data from large-scale Experiments and are used more frequently than CFD models... 

In advanced combined-cycle power plants, significant improvements in the thermodynamic performance are mainly achieved by the development of more efficient gas-turbine systems. This paper evaluates the effect of selected decision variables in the steam system for optimization of Thermal Combined Cycle Gas Turbine (TCCGT) power plant using an iterative exergoeconomic. The design variables were the thermodynamic parameters that establish the configuration both of the steam and gas systems. The design data of an existing plant (Damavand power plant in Tehran-Iran) is used. Two different objective functions are proposed: one minimizes the total cost of production per unit of output, and the... 

The Iranian government has set a target of a 20% share of non-fossil fuel electricity generation by 2030, whose main result is reducing Green House Gas (GHG) emissions (about 182 million tonnes in 2017) to achieve the targets pledged under the Paris Climate Accord. So, this paper presents a comprehensive model on the expansion of non-fossil technology to evaluate the impact of increasing their share in Iran’s electricity supply system. This analytical approach is based on system dynamics (SD) that was developed based on dynamic behavior of electricity market, with an emphasis on the expansion of non-fossil fuels (solar photovoltaics, wind turbines, expansion turbines, and hydro power) in the...