Sharif Digital Repository

This paper describes the designing and evaluation of an alternative energy system which consists of PEMFC, PV, PEM electrolyser, methane reformer and hydrogen tank. In order to find out the minimum capacity of the components, a system sizing model is developed in MATLAB based on meteorological and electrical demand data. Three scenarios are considered based on different combinations of solar energy and fossil fuel energy as energy resources. The heating energy produced by the fuel cell is recovered for supplying domestic hot water while the system would supply electrical energy. Results show that system sizing strongly depends on scenarios and unit cost of electricity decreases through the... 

Despite the abundant renewable energy sources, the Iranian energy sector relies almost entirely on fossil fuel energy resources. Power sector is dominant source of CO2 emissions and responsible for about 35% of total CO2 emissions in the country. Additionally, long-term electricity demand of Iran is expected to grow quickly, which in turn requires extensive investment to meet the growing demand over the next decades. On the other hand, increasing domestic fossil fuel consumption had been a serious challenge due to high costs of oil and gas. Current study pays particular attention to the possible penetration rates of renewable electricity technologies and their implications for fossil fuel... 

In this study, the effect of adding walnut shell-based powdered activated carbon (WS) to a bench-scale dissolved air flotation (DAF) column on oil removal was investigated. All experiments were conducted using synthetically prepared wastewater containing low but stable concentrations of heavy fuel oil. After comparing the effect of different WS doses from 0 (blank) to 40 mg/L at the saturator pressure of 5 bar and 10 min flotation time, 20 mg/L WS was chosen as the optimal concentration. In order to find the best flotation time for efficient use of WS capacity, experiments were repeated with and without 20 mg/L WS at longer flotation times. According to the obtained results, by adding WS,... 

This paper develops a behavioral analysis of freight mode choice decisions that could provide a basis for an acceptable analytical tool for policy assessment. The paper specifically examines the way that truck and rail compete for commodity movement in the US. Two binary mode choice models are introduced in which some shipment-specific variables (e.g. distance, weight and value) and mode-specific variables (e.g. haul time and cost) are found to be determinants. The specifications of the non-selected choice are imputed in a machine learning module. Shipping cost is found to be a central factor for rail shipments, while road shipments are found to be more sensitive to haul time. Sensitivity of... 

The effects of intermediate nickel layer on seal strength and chemical compatibility of seal glass and interconnect materials for solid oxide fuel cells (SOFCs) were investigated. Two types of samples (metal/glass/metal sandwiches and glass coated metals) were prepared with the sheet of AISI 430 (nickel plated and uncoated) and slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples were heated at 850 °C for different time durations (0.5-100 h). Tensile and impact tests were performed and SEM micrographs were used to analyze the glass/metal interaction. The results indicate that nickel plated AISI 430 shows higher adhesion strength at short durations of heating due... 

The present study investigated the biological treatment of produced water in a microbial electrochemical cell (MXC). The main objectives were to develop a novel spiral microbial electrochemical cell (SMXC) and test its performance for produced water treatment under highly saline conditions (salinity > 200000 ppm). The bioelectrochemical performance of the system was also evaluated in terms of power and hydrogen production over time. The comparatively inexpensive material and ease of application increased the feasibility of the SMXC configuration for produced water treatment. Optimal SMXC performance as a microbial fuel cell was achieved at a maximum open circuit potential of 330 mV, maximum... 

The objective of this study was to construct a novel model to be applied in a general manner to simulate microbial electrochemical cells (MXCs); for both microbial fuel cell (MFC) and microbial electrolysis cell (MEC). The liquid bulk was modeled based on the organic matters degradation to acetate via the anaerobic digestion process. Biofilm simulation was established based upon one-dimensional distribution and the dynamical electron transfer was completed by means of the conduction-based mechanism. We, for the first time, introduced biofilm local potential modeling for MEC simulation with general and simplified linear boundary conditions. The MFC-related part of the model was evaluated... 

The aim of this paper is to investigate the implementation of a molten carbonate fuel cell (MCFC) as a CO2 separator. By applying multi-objective optimization (MOO) using the genetic algorithm, the optimal values of operating load and the corresponding values of objective functions are obtained. Objective functions are minimization of the cost of electricity (COE) and minimization of CO2 emission rate. CO2 tax that is accounted as the pollution-related cost, transforming the environmental objective to the cost function. The results show that the MCFC stack which is fed by the syngas and gas turbine exhaust, not only reduces CO2 emission rate, but also produces electricity and reduces... 

The present study aims to analyze a combined heat and power (CHP) system with an approach towards exergy analysis and employing biomass gasification. The cycle modeling was carried out using Cycle-Tempo and the main purpose was to achieve parametric analysis of the model. The systems function was studied by categorizing alternative biomass fuels, also qualitative and quantitative analyses of the biomass fuel samples were presented and considering the trade-off points, most appropriate biomass fuel with respect to exergy efficiency and delivered power were determined. The results indicated that the bagasse and wood chips had the total exergy efficiency of 54.5 and 57.1% in trade-off point,... 

In this paper, the effect of different parameters of power plants, such as height above sea level, performance, ambient temperature, fuel type on emissions in Iran's power plants is investigated. Based on that, a general strategy for selecting the type of power plant, fuel that fit with the geographical situation in the Middle East is presented. Results taken from this scientific study shows that using natural gas to generate power in the region should be a priority. As well as expected, the value of various emission factors decrease by increasing power produce. Also the emission factors of combined cycle power plants are the lowest as compared to other types of power plants  

Lack of a direct method to control combustion timing is one of the main disadvantages of homogeneous charge compression ignition (HCCI) engines. Fuel blending, in which two fuels with different auto-ignition characteristics are blended, can be used to control combustion timing. Utilizing different additives is another method for HCCI combustion control. The aim of this research is investigation on the effect of reformer gas addition on the availability terms in HCCI engines fueled with primary reference fuels (PRFs). A multi zone model (MZM) coupled with a semi detailed chemical kinetics mechanism is used for calculation of different terms of exergy analysis. Heat and mass transfer between... 

Use of computational modeling with a few experiments is considered useful to obtain the best possible result for a final product, without performing expensive and time-consuming experiments. Proton exchange membrane fuel cells (PEMFCs) can produce clean electricity, but still require further study. An oxygen reduction reaction (ORR) takes place at the cathode, and carbon-supported platinum (Pt/C) is commonly used as an electrocatalyst. The harsh conditions during PEMFC operation result in Pt/C degradation. Observation of changes in the Pt/C layer under operating conditions provides a tool to study the lifetime of PEMFCs and overcome durability issues. Recently, artificial neural networks... 

Depletion of fossil fuels has increased the pressure on energy systems to operate in the most efficient and economical mode. This tendency promotes energy systems to operate at optimum operating conditions, which maximizes the system profit over lifetime. Recently, there have been many attempts to maximize lifetime profit. Most of them concentrate on the power generation aspect without incorporating further aspects such as system degradation and profitability through lifetime. However, the main intention of the system operators is to optimize the profitability of system at the moment of operation and not the total profitability through the system lifetime. In this study a novel approach is... 

Macroscopic and microscopic characteristics of spray of a Modified Bio-diesel Fuel (MBF), applying direct injection system have been explored and compared with those of conventional diesel fuel. MBF is a new combination of bio-diesel, molasses bio-ethanol, and water, which has been kept as a single-phase bio-fuel, employing an emulsifier. Lower emissions and production costs, higher oxygen content and cetane number are the key advantages of the MBF to be replaced by conventional fossil fuels in internal combustion engines. Applying atomization model, the spray atomization properties such as Ohnesorge number and Sauter Mean Diameter (SMD) have been investigated. Air entrainment analysis has... 

A torsion test recently implemented for solid oxide fuel cell sealant materials is analyzed as a method for measuring the shear strength of sealant for solid oxide fuel cells. The finite element method is used to simulate the stress distribution in the hourglass-shaped steel specimens with intermediate sealant layer with different specimen's dimensions and configurations. Also, it is analyzed how stress concentration changes if the sealant does not completely fill the gap or is squeezed out of gap. The reduction of seal thickness to outer radius ratio results in an increase in stress concentration at the outer edge of sealant. The developed specimens with a hollow halve steel plate as well... 

One way to reduce vehicles' fuel consumption (FC) is to optimize different parts of its powertrain. Among different modern powertrains, continuously variable transmission (CVT) is one of the common types which changes speed ratio between engine and wheels, continuously. Therefore, the CVT allows the engine to operate at its fuel-optimal speed. Due to the limited power transmission capacity and speed ratio range of the CVT, researchers attempted to combine the CVT with a planetary gear train and a fixed ratio mechanism. This mechanism is called infinitely variable transmission (IVT). In this study, a multi-speed gearbox (MSG) is used in the IVT and its impact on the powertrain performance and... 

The possible interactions near the triple-phase boundaries (TPB) metal/glass/air, and their effects on joint strength are investigated. Two types of samples (joined couples and glass coated coupons) are prepared with the coupon of AISI 430 (nickel plated and uncoated) and a slurry of compliant silicate sealing glass (SCN-1). The joined and coated samples are heated at 850 °C for 1000 h in air. The joined couples are cooled using two different schedules and then tested in uniaxial tension. For investigating the metal-oxides precipitation procedure in glass near the TPB, glass coated coupons are either cooled at the rate of 5 °C min−1 or water-quenched from aging temperature. The mechanical... 

Macroscopic and microscopic characteristics of spray of a Modified Bio-diesel Fuel (MBF), applying direct injection system have been explored and compared with those of conventional diesel fuel. MBF is a new combination of bio-diesel, molasses bio-ethanol, and water, which has been kept as a single-phase bio-fuel, employing an emulsifier. Lower emissions and production costs, higher oxygen content and cetane number are the key advantages of the MBF to be replaced by conventional fossil fuels in internal combustion engines. Applying atomization model, the spray atomization properties such as Ohnesorge number and Sauter Mean Diameter (SMD) have been investigated. Air entrainment analysis has... 

A successful design, previously adapted for treatment of complex wastewaters in a microbial fuel cell (MFC), was used to fabricate two MFCs, with a few changes for cost reduction and ease of construction. Performance and electrochemical characteristics of MFCs were evaluated in different environmental conditions (in complete darkness and presence of light), and different flow patterns of batch and continuous in four hydraulic retention times from 8 to 30h. Changes in chemical oxygen demand, and nitrate and phosphate concentrations were evaluated. In contrast to the microbial fuel cell operated in darkness (D-MFC) with a stable open circuit voltage of 700mV, presence of light led to growth of... 

Effective diffusion coefficient is an important parameter which needs to be determined in different fields of study, such as cathode catalyst layers of PEM fuel. For this purpose, a Loschmidt diffusion cell can be used. When a porous medium is placed in Loschmidt apparatus, the effective gas diffusion coefficient (EGDC) of this section must be correlated by diffusion coefficient in absence of a porous medium. In the previous researches studying the Loschmidt diffusion cell, a simplifying infinite-length assumption was used in the analytical solution. Therefore, the solution is only applicable for a short time range, and this can result in high error. In order to overcome this challenge, the...