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    Molecular Dynamics Study of Tungsten and Iron Addition on the Glass Formability of Cobalt-based Electrodeposited Coatings

    , M.Sc. Thesis Sharif University of Technology Bayati, Mohammad Baher (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Recent research suggests that the electrochemical deposition of cobalt-based binary alloys, such as cobalt-tungsten and cobalt-iron, can lead to the formation of amorphous structures in the coatings. Theoretical studies suggest that these structures are equivalent to structures created by the melt cooling of the alloy at speeds of about 〖10〗^10 Kelvin per second. The formation of a glass phase can significantly increase the abrasion resistance and corrosion resistance of these coatings. Empirical studies show that the ability of the glass to become glassy, or more precisely, the transition from crystalline to amorphous, is largely a function of the chemical composition. Simulation of... 

    Synthesis, Characterization and Application of Porous Bioactive Glasses-Based Nanostructures in Bone Tissue Engineering

    , Ph.D. Dissertation Sharif University of Technology Aldhaher, Abdullah (Author) ; Bagherzadeh, Mojtaba (Supervisor) ; Baheiraei, Nafiseh (Co-Supervisor)
    Abstract
    In the upcoming research, with the aim of bone tissue engineering and achieving a new structure, a scaffold based on polyhema (PHEMA) and gelatin (Gel), which are biocompatible polymers for bone tissue, was made and evaluated. Also, in order to improve the bioactivity and mechanical properties, bioactive glass alone (BG45S5) or together with strontium (BG-Sr) was used in the scaffold structure. and chemical by conducting FTIR, XRD, SEM, mechanical strength, bioactivity measurement, contact angle, water absorption and degradation tests. Biological investigations were done using mesenchymal stem cells derived from human bone marrow and with the help of MTT evaluations and SEM photography. The... 

    Effect of Chemical Composition on Atomic Structure and Mechanical Properties of Mg-Zn Glass Alloys Using Molecular Dynamics Simulation

    , M.Sc. Thesis Sharif University of Technology Asl Roosta, Pouneh (Author) ; Tavakoli, Rohollah (Supervisor)
    Abstract
    In this research, Mg-Zn bulk metallic glasses have been investigated using molecular dynamics simulation. In order to study the structure of this alloy, coordination number, short and medium order of chemical range, Voronoi analysis, glass conversion temperature and atomic pair distribution function have been used. According to the results, the full icosahedral structure with IS connection type in comparison with other structures has an essential role in the stability of the system during cooling and creating medium-scale areas. The results show that the ability to form glass depends on the chemical composition and cooling rate. In this research, the cooling rate is considered to be 1011 K/s... 

    Introducing a Numerical Method for Estimating Median Crack Depth during Machining on Optical Glasses

    , Ph.D. Dissertation Sharif University of Technology Asqari, Mohammad Amin (Author) ; Akbari, Javad (Supervisor)
    Abstract
    In present research, a cohesive based finite element model has been introduced to estimate median crack depth during mechanical machining on optical glasses. Development of the machining numerical model has been initiated by investigating the indentation process. Experimental results of this step have been calibrated primary numerical model which has been used in the scratch process. Due to differences between the scratch mechanism and indentation one, mathematical bases fracture formulas and cohesive relations have been developed. After extracting primary result, using them in the scratch model and developing the primary model, ultimately numerical model has been evolved to an abstract... 

    Fabrication and Investigation of Structure and Mechanical Properties of Bagasse Fibers Reinforced PP: Role of Alkalization and Calcium Carbonate Filler

    , M.Sc. Thesis Sharif University of Technology Asgharpour, Ali (Author) ; Bagheri, Reza (Supervisor)
    Abstract
    The consumption of plastics in the world is increasing and this is accompanied by the challenges of production from oil products and carbon footprint, waste production and environmental issues. The solutions to these challenges are material recycling and the production of biocompatible plastics. Polypropylene is a widely used polymer that is commonly used in conjunction with reinforcements such as fiberglass. Natural fibers can be substituted to increase the biocompatibility of the composite, which, despite its many advantages, presents challenges. The most important challenge is the poor adhesion of the fibers and the matrix due to the hydrophilicity of natural fibers and hydrophobicity of... 

    Synthesis & Properties of Nd-doped Glass-ceramics in the SiO2-CaO-MgO System from Sol-gel Method Used as Solid Lasers

    , M.Sc. Thesis Sharif University of Technology Eslami, Masoud (Author) ; Hamnabard, Zohreh (Supervisor) ; Nemati, Ali (Supervisor)
    Abstract
    In this study, SiO2-CaO-MgO galsses and glass-ceramic powder doped with Nd3+ were synthesized with sol-gel method. Tetraethylorthosilicate (TEOS), Ca(NO3)2.4H2O, Mg(NO3)2.6H2O, Nd(NO3)3.6H2O, ethanol, distilled water, and HNO3 were used as starting materials. The synthesized powder’s properties were examined with STA, XRD, DRS, PL, FTIR and SEM analysis. From XRD patterns of glass samples, the role of dopant was introduced as intermediate oxide in glass matrix. The XRD patterns of glass-ceramic samples indicated that the bredigite and akermanite crystals were formed in glass matrix. The band gap energy of samples were calculated from DRS analysis and were seen with increasing the dopant... 

    Study of Structural and Mechanical Properties of Zr-, Ti- and La-based bulk Metallic Glasses

    , Ph.D. Dissertation Sharif University of Technology Asadi Khanouki, Mohammad Taghi (Author) ; Aashuri, Hossein (Supervisor) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    Bulk metallic glasses (BMGs), in contrast to conventional crystalline materials, are defined as metals with an amorphous and disordered atomic-scale structure. Due to the absence of dislocations and grain boundaries, BMGs have considerably unique mechanical properties such as high strength and elastic strain, high wear resistance and desirable corrosion resistance. However, they generally suffer from poor plasticity caused by an inhomogeneous deformation which leads to catastrophic failure by localization of strain into narrow regions, known as shear bands. This factor has extremely restricted their application as advanced structural materials. Furthermore, the recently discovered phenomenon... 

    Microfluidic Tensiometry and Investigation of Nanoparticles Adsorption at Liquid/Liquid Interfaces

    , M.Sc. Thesis Sharif University of Technology Arvahi, Milad (Author) ; Mohammadi, Ali Asghar (Supervisor)
    Abstract
    The present paper is an attempt to critically measure interfacial tension with microchannels and achieve the quantity of adsorption in the liquid – liquid interfaces and comparing the adsorption of surfactants and nanoparticles surface modificated as well. At this point we need to make emulsion and it is necessary for droplets to be monodispersed due to analyze these droplets in this paper. According to this condition for our droplets microsystems are the best options. As we know surfactants were already known as a stabilizing emulsion agent and in this paper nanoparticles are suggested as suitable alternatives for surfactants which can be absorbed as if they are in the water / oil... 

    Evaluation of Controlled Drug Release Chitosan-based Coatings on Titanium Implants: Microstructure, Bioactivity and Biocompatibility

    , Ph.D. Dissertation Sharif University of Technology Ordikhani, Farideh (Author) ; Simchi, Abdolreza (Supervisor)
    Abstract
    Implant-associated infections are one of the most serious complications in orthopaedic and trauma surgery as it may result in poor functional outcome, implant failure, chronic osteomyelitis or even death. Great concerns have been taken to reduce implant-associated infections through progressing in operating standards, minimizing the possibility of contamination during surgery, reducing the establishment of infection by perioperative antibiotic prophylaxis, and confining of pathogenic strains by patient isolation. In spite of these preventions, the percentage of postoperative infections is still rising. Composite coatings with bone-bioactivity and drug-eluting capacity are considered as... 

    Behavior of Concrete Slabs Reinforced with FRP Bars, Design and Analysis

    , M.Sc. Thesis Sharif University of Technology Adimi, Alireza (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Despite extensive studies on the behavior of reinforced concrete slabs, especially those reinforced with steel rebars, no comprehensive studies have been conducted on the behavior of concrete slabs reinforced with FRP rebars. Therefore, there are some ambiguities regarding the tensile and compressive behavior of these rebars in the load-bearing capacity of reinforced concrete slabs (depending on their amount in the slab and their combination with steel rebars). Hence, in this study, in order to ensure the accuracy of numerical simulations, the numerical 3D simulation of a one-way concrete slab reinforced with tensile FRP rebars was performed using the finite element Abaqus software.... 

    Experimental Investigations on Reinforced Concrete Slabs Strengthening by FRP Sheets

    , M.Sc. Thesis Sharif University of Technology Asna Ashary Esfahani, Mansour (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    A total of four reinforced concrete slabs with dimension of 2200×1000×100 mm strengthened with different layers of GFRP sheets were fabricated and tested. A loading of the slabs was performed using displacement control approach.In addition, nonlinear finite element analysis (NLFEA) using ANSYS package was used to simulate the behavior of the test specimens. After reasonable validation of NLFEA with the experimental test results of companion slabs, NLFEA was expanded to provide a parametric study of sixty two slabs. Forty two numbers of these sixty two slabs were without any opening and were modeled for different type of concrete strength, ratio of length/wide for slabs, type of FRP, number... 

    Numerical Investigation of the Performance of Concrete Beamcolumns with FRP Bars under Concentric and Eccentric Loading and Four-Points Bending

    , M.Sc. Thesis Sharif University of Technology Aghabozorgi, Pegah (Author) ; Khaloo, Alireza (Supervisor)
    Abstract
    Glass Fiber Reinforced Polymer (GFRP) bars with significant corrosion resistance lead to an improvement in the performance of concrete structures and a significant reduction in costs. High ratio of tensile strength to weight, non-conductive, and non-magnetic properties are other features of GFRP bars. Recent international design standards, such as ACI 440.1R-15 do not recommend including FRP reinforcement in compression, so they replace them by concrete in calculations. The purpose of this study was to investigate the effect of concentric and excentric axial loading on the axial capacity and ductility of GFRP reinforced concrete columns compared to steel reinforced concrete columns,... 

    Halogen-lithium exchange reaction using an integrated glass microfluidic device: an optimized synthetic approach

    , Article Organic Process Research and Development ; Volume 21, Issue 3 , 2017 , Pages 292-303 ; 10836160 (ISSN) Zeibi Shirejini, S ; Mohammadi, A ; Sharif University of Technology
    American Chemical Society  2017
    Abstract
    A telescoped approach was developed for the efficient synthesis of methoxybenzene through the generation of an unstable intermediate reagent, based on the Br-Li exchange reaction of p-bromoanisole and n-BuLi, followed by its reaction with water. In the first stage, p-methoxyphenyllithium was synthesized and consumed immediately in the second stage. For this purpose, an integrated glass microfluidic device was fabricated using laser ablation followed by the thermal fusion bonding method. The impact of various parameters, including solvent, reaction time, molar ratio, concentration of reagents, and flow rates were investigated to achieve the highest yield of the desired product, leading to an... 

    In vitro bactericidal and drug release properties of vancomycin-amino surface functionalized bioactive glass nanoparticles

    , Article Materials Chemistry and Physics ; Volume 241 , 2020 Zarghami, V ; Ghorbani, M ; Bagheri, K.P ; Shokrgozar, M. A ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Bioactive glass has been used clinically in bone repair applications for bone grafting because of its prominent physiochemical and osteogenic properties. Various attempts have been made to enhance bioactive glass efficiency in combination with other biomaterials such as antibiotics and growth factors. In present study, we developed a modification of bioactive glass nanoparticles that insured long term antibacterial effect. Bioactive glass nanoparticles (BGNs) were functionalized with (3-Aminopropyl) triethoxysilane (APTS), then vancomycin (VAN) was immobilized onto BGNs-APTS via EDC/NHS cross-linking process. Another study group namely BGNs-VAN was synthesized as a control group without any... 

    Improving bactericidal performance of implant composite coatings by synergism between Melittin and tetracycline

    , Article Journal of Materials Science: Materials in Medicine ; Volume 33, Issue 6 , 2022 ; 09574530 (ISSN) Zarghami, V ; Ghorbani, M ; Pooshang Bagheri, K ; Shokrgozar, M. A ; Sharif University of Technology
    Springer  2022
    Abstract
    Methicillin resistance Staphylococcus aureus bacteria (MRSA) are serious hazards of bone implants. The present study was aimed to use the potential synergistic effects of Melittin and tetracycline to prevent MRSA associated bone implant infection. Chitosan/bioactive glass nanoparticles/tetracycline composite coatings were deposited on hydrothermally etched titanium substrate. Melittin was then coated on composite coatings by drop casting method. The surfaces were analyzed by FTIR, XRD, and SEM instruments. Tetracycline in coatings revealed multifunctional behaviors include bone regeneration and antibacterial activity. Releasing ALP enzyme from MC3T3 cells increased by tetracycline, so it is... 

    An experimental investigation of the effect of fracture dip angle on oil recovery and drainage rate in free fall gravity drainage in fractured reservoirs using a glass micromodel (A pore level investigation)

    , Article Petroleum Science and Technology ; Volume 31, Issue 4 , 2013 , Pages 355-367 ; 10916466 (ISSN) Zareh, N ; Kharrat, R ; Ghazanfari, M ; Sharif University of Technology
    2013
    Abstract
    Gravity drainage is the main production mechanism in the gas invaded zone in naturally fractured reservoirs. However, there are large ambiguities and complexities, resulting from the dynamic of oil depletion from matrix blocks toward the fracture network. Visualization of drained oil at pore scale using glass micromodels provides the opportunity to better understand the effects of different parameters which might affect oil recovery from fractured reservoirs. In this work a micromodel apparatus generated by laser etching is used to perform some gravity drainage tests on the network patterns. The experiments were performed on double block systems using crude oil. The block to block... 

    Nano-coated condensation surfaces enhanced the productivity of the single-slope solar still by changing the condensation mechanism

    , Article Journal of Cleaner Production ; Volume 265 , 2020 Zanganeh, P ; Soltani Goharrizi, A ; Ayatollahi, S ; Feilizadeh, M ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    Solar stills are considered an environmentally friendly technique to produce fresh water. The condensation surface plays an essential role in controlling the efficiency of the solar still. This main parameter is critically affected by the wettability of the condensation surface that affects the condensation mechanism, namely drop-wise or film-wise condensation. This study aims to enhance the efficiency of solar stills by altering the surface wettability hence changing the condensation mechanism using nanomaterials. In this experimental work, different condensation surfaces were coated by silicone nanoparticles to change the condensation mechanism from film to dropwise. Scanning electron... 

    Efficiency improvement of solar stills through wettability alteration of the condensation surface: An experimental study

    , Article Applied Energy ; Volume 268 , 2020 Zanganeh, P ; Soltani Goharrizi, A ; Ayatollahi, S ; Feilizadeh, M ; Dashti, H ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    The condensation process is of great importance in many heat transfer devices in which a large amount of energy must be transferred. Furthermore, condensation is a crucial part of energy conversion and affects the energy efficiency of thermal desalination plants and solar stills. During the condensation process in solar stills, an essential part of the energy is transferred through the condensation surface to produce fresh water. Therefore, the condensation surface plays a significant role in the working efficiency of solar stills. The wettability of the condensation surface influences the condensation mechanism, which, in turn, affects the efficiency of solar stills. This study aims to... 

    Synthesis and characterization of diopside glass-ceramic matrix composite reinforced with aluminum titanate

    , Article Ceramics International ; Volume 35, Issue 4 , 2009 , Pages 1447-1452 ; 02728842 (ISSN) Yousefi, M ; Alizadeh, P ; Eftekhari Yekta, B ; Molaie, F ; Ghafoorian, N ; Montazerian, M ; Sharif University of Technology
    2009
    Abstract
    Glass-ceramic composites in the SiO2-CaO-MgO-(Na2O) system, reinforced with 5, 10 and 20 wt.% aluminum titanate were synthesized by pressureless sintering. Optimum sintering temperatures with maximum relative density were determined for each composition. The composites were fired above the crystallization peak temperature of glass-ceramic. Mechanical properties of glass-ceramic and sintered composites, such as fracture toughness, flexural strength and Vickers microhardness, were investigated. The sintered composites were characterized by scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS) and X-ray diffraction (XRD). The results showed that the composite containing 10... 

    Interaction of glazing parameters, climatic condition and interior shadings: performing energy and cost analysis in a residential building in Iran

    , Article Energy Efficiency ; Volume 13, Issue 1 , 21 December , 2020 , Pages 159-176 Yousefi, F ; Gholipour, Y ; Saboohi, Y ; Yan, W ; Sharif University of Technology
    Springer  2020
    Abstract
    In this paper, the interaction between various window specifications and different climate conditions is investigated. For this purpose, simultaneous effects of several aspects including glazing system, glass type, filling gas, glass thickness, window frame fraction, and interior shading are considered under three different climatic conditions. To evaluate the energy performance of various considered alternatives, the energy simulation of a base case building is evaluated in a computer environment. Using the validated model, the energy analysis is quantitatively performed, and cost-benefit analyses from the viewpoints of both residents and government are carried out based on the domestic and...