Sharif Digital Repository

Studies on copper zinc tin sulpher selenide (CZTSSe) thin-film material and its applications as a base material are intensively being researched since it is an earth-abundant, inexpensive, flexible, and interesting material for next-generation optoelectronic technologies. Apropos, this study explores and reports the synthesis of CZTSSe thin films and their key optoelectronics characteristics. The reported films are fabricated on a soda-lime glass substrate by using a physical vapor deposition technique, and then annealed from 250 to 450 °C. From the X-ray diffraction analysis, the structure of the as-deposited thin films is found to be amorphous in nature. Annealed thin films of CZTSSe... 

In this study, 490 nm thin tin selenide thin films were deposited by facile co-evaporation techniques using Sn and Se sources on a clean glass substrate. The thin films were annealed at moderate annealing temperature followed by characterization and analysis. The thin annealed films possess polycrystalline nature and orthorhombic structure with an average grain size of 130 nm. The band gap assessed from absorption spectra for the highly annealed sample was 1.52 eV. The resistivity and sheet resistance were measured with four-probe techniques and the sheet resistance was =1.362 × 104 ohm for the highly annealed film. © 2021 John Wiley & Sons Ltd  

In the present study, a bioactive silicate-phosphate glass-ceramic scaffold was fabricated via the polymer-derived ceramics (PDC) method. K2HPO4 phosphate salt was used as the P2O5 precursor in this method. The effect of K2HPO4 wt% and heat treatment temperatures (900–1100 °C) was evaluated. It was observed that although increasing the wt% of K2HPO4 led to the formation of scaffolds with higher densities and strengths, it could also increase the formation of the calcium phase, which could result in improper release behavior of scaffolds. On the other hand, higher heat treatment temperatures enhanced the strength of the scaffolds but eliminated the bioactive octacalcium phosphate (OCP) phase.... 

Studies on copper zinc tin sulpher selenide (CZTSSe) thin-film material and its applications as a base material are intensively being researched since it is an earth-abundant, inexpensive, flexible, and interesting material for next-generation optoelectronic technologies. Apropos, this study explores and reports the synthesis of CZTSSe thin films and their key optoelectronics characteristics. The reported films are fabricated on a soda-lime glass substrate by using a physical vapor deposition technique, and then annealed from 250 to 450 °C. From the X-ray diffraction analysis, the structure of the as-deposited thin films is found to be amorphous in nature. Annealed thin films of CZTSSe... 

In this study, 490 nm thin tin selenide thin films were deposited by facile co-evaporation techniques using Sn and Se sources on a clean glass substrate. The thin films were annealed at moderate annealing temperature followed by characterization and analysis. The thin annealed films possess polycrystalline nature and orthorhombic structure with an average grain size of 130 nm. The band gap assessed from absorption spectra for the highly annealed sample was 1.52 eV. The resistivity and sheet resistance were measured with four-probe techniques and the sheet resistance was =1.362 × 104 ohm for the highly annealed film. © 2021 John Wiley & Sons Ltd  

The purpose of this article is to investigate the shielding performance of the B2O3-Bi2O3-ZnO-Li2O glasses against the gamma-ray. To this end, the attenuation parameters of the gamma-ray inside the B2O3-Bi2O3-ZnO-Li2O glasses were evaluated in the energy range of 200–1500 keV. It was found that the mass attenuation coefficient of the composites increases with increasing the Li2O content. The relative percent deviation between the results of simulation using the MCNPX and XCOM database in most cases was less than 2%. Additionally, the Mean Free Path (MFP) and Half-Value Layer (HVL) parameters were evaluated, and the shielding efficiency of samples was compared with some conventional shielding... 

Seven half-scale reinforced concrete (RC) columns with supporting beam were experimentally studied under combined axial and lateral cyclic loading. The specimens were categorized in two groups based on reinforcement ratios. Three specimens were strengthened with carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) sheets. Other specimens were strengthened using a high strength mortar reinforced with textile mesh (textile reinforced concrete (TRC)). Strengthening of specimens were carried out using a vertical layer and a horizontal layer of FRP sheet or two vertical and two horizontal layers of textile meshes for TRC specimens. Since the weight of each layer of... 

Oil polarity is an important property impacting the efficiency of low salinity waterflooding (LSWF). It directly affects fluid/fluid and rock/fluid interactions, controlling the interfacial properties and forces. However, the current findings in the literature on the effect of concentration of polar components on oil recovery by LSWF are contradictory. Therefore, the main objective of this paper is to investigate how the type of non-polar fractions and the concentration of acidic polar oil constituents change the trapped oil saturation at the pore-scale during LSWF. In this regard, we conducted a series of microfluidics LSWF experiments in both secondary and tertiary modes, using clay-free... 

In this study, the fatigue behavior of composite reinforced cracked aluminum 1050 plates is investigated experimentally and numerically. The tests are conducted in four different stress ratios between 0 and 1. At first step, plates with similar cracks and geometries have been prepared. Then the glass/epoxy patches have been attached to the cracked plates using Araldite 2015 adhesive. Fatigue load has been applied to three cases of samples including non-patch, one-side patch and two-side patch, where in all stress ratios the maximum force is considered constant. A three-dimensional finite element analysis is developed in ABAQUS. A good correlation between finite element results and the... 

Thanks to a wide range of pore sizes by nano/macro composites of SiOC/Al2O3, such composites can serve as different layers of the structure of Packed Bed Reactor Membranes (PBRM). In the present study, the Polymer-Derived Ceramics method (PDC) has been used to synthesize nano/macro structures. Firstly, the effect of toluene as an extra carbon source on structure and microstructure of SiOC glass-ceramics was evaluated, such that, 4% (Vol) toluene was recognized as the proper amount to facilitate the synthesis of β-SiC at 1300 °C proved by XRD, Raman spectroscopy, and HR-TEM. Moreover, the presence of micro/meso-porosities was assessed by BET and TEM, indicating the capability of SiOC to serve... 

In the present study, a bioactive silicate-phosphate glass-ceramic scaffold was fabricated via the polymer-derived ceramics (PDC) method. K2HPO4 phosphate salt was used as the P2O5 precursor in this method. The effect of K2HPO4 wt% and heat treatment temperatures (900–1100 °C) was evaluated. It was observed that although increasing the wt% of K2HPO4 led to the formation of scaffolds with higher densities and strengths, it could also increase the formation of the calcium phase, which could result in improper release behavior of scaffolds. On the other hand, higher heat treatment temperatures enhanced the strength of the scaffolds but eliminated the bioactive octacalcium phosphate (OCP) phase.... 

Preformed particle gels (PPGs) in solutions have been widely used to suppress excess water production in mature oil reservoirs and, in turn, to improve the amount of oil recovery in brown oil fields. In this study, PPG solutions were meticulously formulated and synthesized in order to be utilized in harsh environments in terms of pressure, temperature, pH, and salinity from a free radical polymerization process. In this work, nanosilica gel at different weight percentages was added to improve the mechanical and thermal stability properties of the PPG at harsh condition: high pressure, temperature, and strain. Moreover, the effects of nanosilica gel at various concentrations, ranging from 0.0... 

Organ-on-a-chip technology tries to mimic the complexity of native tissues in vitro. Important progress has recently been made in using this technology to study the gut with and without microbiota. These in vitro models can serve as an alternative to animal models for studying physiology, pathology, and pharmacology. While these models have greater physiological relevance than two-dimensional (2D) cell systems in vitro, endocrine and immunological functions in gut-on-a-chip models are still poorly represented. Furthermore, the construction of complex models, in which different cell types and structures interact, remains a challenge. Generally, gut-on-a-chip models have the potential to... 

In this research, the mechanical properties of various glass fibre reinforced polymer (GFRP) pultruded profiles exposed to seawater sea sand concrete (SWSSC) and its combination with UV radiation and water vapour condensation were studied. The effect of different conditions, duration of conditioning, and the profile cross-section configuration on the mechanical properties were investigated. Three-point bending, tension, and compression tests were carried out to obtain the mechanical properties, including flexural, tensile and compressive strengths and tensile elastic modulus. Furthermore, in order to scrutiny the mechanisms and extent of damage, scanning electron microscopy (SEM) was carried... 

This article presents an investigation on the durability of different glass-fibre-reinforced polymer composites when subjected to harsh outdoor conditions, including freeze/thaw cycles, ultraviolet radiation and moisture, as well as when used with seawater sea-sand concrete for construction applications. To achieve this, the effects of a number of parameters, including the environment of exposure, exposure time, profile cross-sectional configuration and orientation of fibres, on the mechanical properties of different glass-fibre-reinforced polymer composites were studied. To investigate the degradation of the mechanical properties, three-point bending, compression and tension tests were... 

In the present study, a rational two-step strategy is employed for the green, fast, very simple, and highly controllable synthesis of the bimetallic nickel-cobalt-based metal-organic frameworks (MOFs) on glassy carbon substrates by in situ transformation of nickel-cobalt-layered double hydroxide nanosheet (NiCo-LDHs NSs) intermediates into nickel-cobalt-benzene tricarboxylic acid MOFs (E-NiCo-BTC MOFs). The structural characteristics of the electrode materials in each step were investigated via Fourier transform infrared spectroscopy, X-ray diffraction, energy dispersive X-ray spectroscopy, elemental mapping, field emission scanning electron microscopy, and transmittance electron microscopy.... 

Assessment of mechanical properties of glass/metal joints is a challenging process, especially when the application relevant conditions of the joints have to be considered in the test design. In this study, a finite element method (FEM) is implemented to analyze a torsional shear strength test designed for glass-ceramic/steel joints aiming towards solid oxide fuel/electrolysis cells application. Deviations from axial symmetry of the square flanges (ends) of respective hourglass-shaped specimens and also supporting and loading sockets of the test set-up are included in the model to simulate conditions close to reality. Undesirable tensile stress and also shear stress concentration appear at... 

The structural integrity of the sealant is critical for the reliability of solid oxide cells (SOCs) stacks. In this study, elastic modulus (E), hardness (H) and fracture toughness (KIC) of a rapid crystallizing glass of BaO–CaO–SiO2 system termed “sealant G” are reported as determined using an indentation test method at room temperature. A wide range of indentation loads (1 mN–10 N) was used to investigate the load-dependency of these mechanical properties. Values of 95 ± 12 GPa, 5.8 ± 0.2 GPa and 1.15 ± 0.07 MPa m0.5 were derived for E, H and KIC using the most suitable indentation loads. An application relevant annealing treatment of 500 h at 800 °C does not lead to a significant change of... 

Mg-based metallic glasses are promising materials for biodegradable implants. Understanding atomistic mechanism behind glass formation in these glasses plays a critical role in developing them for future applications. In the present work, we perform a set of molecular dynamics simulations to study structural origin behind glass form ability of Mg-based Mg-Zn metallic glasses at a wide range of compositions. Pair distribution function, Voronoi tessellation and dynamical analysis were adopted to characterize local structures in these glasses. Structural analysis was performed considering both topological and chemical short-range orders. It was found that structure of Mg-Zn metallic glasses... 

The existence of universal semi-log linear relation between potential energy and cooling rate during the molecular dynamics simulations of metallic glasses for Cu-Zr system was formerly reported. For this purpose, different classes of metallic glasses are considered and the validity of this correlation is studied. It is shown that it holds for other thermodynamics potentials and some physical quantities like density and Wendt and Abraham parameter, too. This observation enables us to economically construct atomic scale metallic glass structures equivalent to very low cooling rates, more consistent to experimental works, not accessible using classic molecular simulations. © 2020 Elsevier B.V