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hydrophobicity
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Development of a Paper-based Microfluidic Device for Biological Assay
, M.Sc. Thesis Sharif University of Technology ; Shamloo, Amir (Supervisor)
Abstract
All the biological diagnostic devices that are introduced to the consumers, must meet WHO criteria. Some of these criteria include being affordable, sensitive and deliverable to the user. In the last twenty years, there have been lots of efforts to use microfluidic devices for biological assay. Due to their expensive price and requirement of complex equipment for their fabrication, polymer-based microfluidic devices have not been able to be used in developing countries. It is to be hoped that introduction of paper for fabrication of microfluidic devices could make microfluidic devices meet WHO criteria. μPADs are divided into well-based and channel-based devices. In the present work, both...
The Impact of Temperature on Surface Activity and Stability of Surface Modified Nano Particles
, M.Sc. Thesis Sharif University of Technology ; Mohammadi, Ali Asghar (Supervisor)
Abstract
Surface modification is an important property of nano particles. In this project surface of silica nano particles modified with hydrophobic and hydrophilic groups to imrprove surface activity of nano particles. Purpose of this project is to study surface activity of surface modified silica nano particles in different temperatures from 20 to 70 degree centigrade. Also effect of salt and time on the surface activity is studied. At first nano particles modified just with haydrophobic groups and then just with hydrophilic groups (hydrophobic and hydrophilic nano particles) and after that, the surface modification done with both hyadrophilic and hydrophobic groups (amphiphilic nanoparticles)....
Application of Salt Fog Test and Lifetime Evaluation of Silicone Rubber Insulators in Atmospheric Conditions with Contamination and Humidity
, M.Sc. Thesis Sharif University of Technology ; Vakilian, Mehdi (Supervisor)
Abstract
Electricity distribution companies always strive to operate the power network efficiently and reliably so that their network be able to satisfy the growing needs for electricity. To achieve these goals in a power network, a comprehensive asset management plan with a sound policy for inspection, periodic maintenance, replacement, and disposal of depreciated equipment is required. One of the high-risk sectors of the electricity grid is the insulation section of distribution and transmission lines. In recent years, composite insulators have been used more widely because of their desirable characteristics such as: hydrophobicity, lower price, and lower weight if compared with the another...
Numerical Modeling of Electroosmotic Flow of Viscoelastic Fluids in Hydrophobic Microducts
, M.Sc. Thesis Sharif University of Technology ; Saeedi, Mohammad Hassan (Supervisor) ; Kazemzadeh Hannani, Siamak (Co-Advisor)
Abstract
The integrated development of small-scale electronic and mechanical systems has drawn attention, since they lead to increase in speed and decrease in volume of industry dimensions in the manufacturing sector. That is why microelectromechanical systems are highly considered. MEMS are widely used in Microfluidic systems that can be used in medicine, biology and drug injection. Due to the fact that consistent fluid velocity is necessary in biological applications, electroosmotic flow is more important than ever. To investigate the behavior of biofluids, Newtonian models cannot be used and it is required to use models that predict the behavior of these fluids accurately. In this research...
, M.Sc. Thesis Sharif University of Technology ; Mosavi, Abbas (Supervisor) ; Shojaei, Akbar (Co-Advisor)
Abstract
In this work nanocomposite CNT/polysulfone and CNT/polyethersulfone membranes for membrane contactor application in gas separation were fabricated. The two types of CNTs used for chemical and physical separation of H2S from a mixture of CH4 an H2S, had the outer diameter of 20-30nm and 50-100nm. One of the greatest concerns about using membrane contactors for gas separation applications is the wetting of membranes which consequently leads to decrease in separation performance. The aim of this study is to enhance the hydrophobicity of membranes by mixing hydrophobic carbon nanotubes in the polymeric matrix. The effect of factors like type of the polymer, diameter of the carbon nanotube and...
Drag Reduction Using Geometrically Structured Surfaces for Non-newtonian Multi-phase Fluids
, M.Sc. Thesis Sharif University of Technology ; Moosavi, Ali (Supervisor)
Abstract
With the advancement of the industry, microscale devices use due to its unique characteristics. On the other hand, it is essential to find ways to reduce drag inside microchannels because of The importance of energy. One of the methods is to optimize the contact surface using structured geometric surfaces. These hydrophobic surfaces reduce drag by trapping the air in roughness and creating a two-phase flow. The purpose of this project is to reduce the drag within the microchannel using structured geometric surfaces for non-Newtonian and multiphase flows. In most previous studies, with simplification, Newtonian and two-phase flows have been investigated. While most industrial fluids show...
Re-Creation of Lost Gas Layer on Superhydrophobic Surfaces with Micro/Nanostructures
, M.Sc. Thesis Sharif University of Technology ; Mosavi, Ali (Supervisor)
Abstract
Due to their unique characteristics, such as drag reduction, anti-fouling, and enhancing condensation, hydrophobic and superhydrophobic surfaces have attracted a lot of attention in the past decades. Since approximately 4% of the fossil fuel usage and 14-19% of the air pollution (including greenhouse gases, sulfur, and so forth) are attributed to naval activities, and the dominant form of drag on vessels is friction, drag reduction will not only reduce the cost and usage of fossil fuels, but it will also have numerous environmental benefits
Anomalous diffusion of proteins in sheared lipid membranes
, Article Physical Review E - Statistical, Nonlinear, and Soft Matter Physics ; Volume 88, Issue 3 , September , 2013 ; 15393755 (ISSN) ; Jalali, M. A ; Sharif University of Technology
2013
Abstract
We use coarse grained molecular dynamics simulations to investigate diffusion properties of sheared lipid membranes with embedded transmembrane proteins. In membranes without proteins, we find normal in-plane diffusion of lipids in all flow conditions. Protein embedded membranes behave quite differently: by imposing a simple shear flow and sliding the monolayers of the membrane over each other, the motion of protein clusters becomes strongly superdiffusive in the shear direction. In such a circumstance, the subdiffusion regime is predominant perpendicular to the flow. We show that superdiffusion is a result of accelerated chaotic motions of protein-lipid complexes within the membrane voids,...
Preconcentration and determination of carbaryl and carbofuran in water samples using ionic liquids and in situ solvent formation microextraction
, Article Analytical Methods ; Volume 5, Issue 9 , 2013 , Pages 2406-2412 ; 17599660 (ISSN) ; Givianrad, M. H ; Akhoundi, L ; Akhoundi, M ; Sharif University of Technology
2013
Abstract
In the present work, a novel microextraction method named in situ solvent formation microextraction (ISFME) using ionic liquids (ILs) for preconcentration of carbaryl and carbofuran in water samples is introduced. In this method, a small amount of sodium hexafluorophosphate (NaPF6), as an ion pairing agent, was added to a sample solution containing a small quantity of 1-hexyl-3-methylimidazolium tetrafluoroborate [Hmim][BF4] as a hydrophobic ionic liquid. A cloudy solution formed as a result of formation of fine droplets of 1-hexyl-3-methylimidazolium hexafluorophosphate [Hmim][PF 6]. After centrifugation, the fine droplets of the extractant phase settled to the bottom of the conical-bottom...
Simultaneous voltammetric detection of ascorbic acid and uric acid at a carbon-paste modified electrode incorporating thionine-nafion ion-pair as an electron mediator
, Article Electrochimica Acta ; Volume 51, Issue 13 , 2006 , Pages 2599-2606 ; 00134686 (ISSN) ; Ghalkhani, M ; Sharif University of Technology
2006
Abstract
The electrochemical behavior of ascorbic acid (AA) and uric acid (UA) at the surface of a carbon-paste electrode modified with incorporate thionine-nafion ion-paired was thoroughly investigated. The results show the presence of nafion inside the matrix of modified electrode, because of the effective ion-pairing and hydrophobic interactions, significantly enhances the stability of thionine as an electron mediator inside the modified electrode. A high reproducibility in voltammetric response to analyte species results because of this enhancement. The cyclic voltammetric studies using the prepared modified electrode show the best electrocatalytic property for the electro-oxidation of AA and...
Solute-solvent interaction effects on second-order rate constants of reaction between 1-chloro-2,4-dinitrobenzene and aniline in alcohol-water mixtures
, Article International Journal of Chemical Kinetics ; Volume 37, Issue 2 , 2005 , Pages 90-97 ; 05388066 (ISSN) ; Gholami, M. R ; Sharif University of Technology
2005
Abstract
The second-order rate coefficients for aromatic nucleophilic substitution reaction between 1-chloro-2,4-dinitrobenzene and aniline have been measured in aqueous solutions of ethanol and methanol at 25°C. The plots of rate constants versus mole fraction of water show a maximum in all-aqueous solutions. The effect of four empirical solvent parameters including hydrogen bond donor acidity (α), dipolarity/polarizability (π*). normalized polarity (ETN), and solvophobicity (Sp) has been investigated. This investigation has been carried out by means of simple and multiple regression models A dual-parameter equation of log k2 versus Sp and α was obtained in all-aqueous solutions (n = 41, r = 0.962,...
In Situ Preparation of Acrylamide-Styrene- Maleic Anhydride Nano Hydrogels and Investigation of their Properties
, M.Sc. Thesis Sharif University of Technology ; Ramazani Saadatabadi, Ahmad (Supervisor)
Abstract
Among the methods for increasing chemical oil extraction,the polymeric flood method has the most commercialization capability.However,most commonly used polymers such as Hydrolyzed Polyacrylamide (HPAM) are not able to withstand high levels of salinity and high temperatures.To overcome these problems,in this project,new types of polymer nanostructures were synthesized with hydrophobic groups consisting of styrene (hydrophilic monomer) and malic anhydride (hydrophilic monomer) acrylamide (hydrophilic monomer). These polymers were synthesized by reversible mini-emulsion by adjusting the synthesis conditions for the purpose of producing the terpolymer with suitable conditions for tolerating...
Hydrophobic nanocarriers embedded in a novel dual-responsive poly(N-isopropylacrylamide)/chitosan/(cyclodextrin) nanohydrogel
, Article Journal of Polymer Research ; Volume 20, Issue 10 , 2013 ; 1572-8935 (Online ISSN) ; Hemmatinejad, N ; Pourjavadi, A ; Sharif University of Technology
2013
Abstract
The incorporation of modified β-cyclodextrin (β-CD) into a poly(N-isopropylacrylamide) (PNIPAAm)/chitosan (PNCS) nanohydrogel was studied. β-CD was functionalized with acrylic groups, with different numbers of vinyl bonds added per β-CD molecule. The surfactant-free dispersion polymerization (SFDP) semi-batch method was used to synthesize the nanohydrogel. Increasing the number of vinyl groups per β-CDAC (β-CD acrylate) molecule induced the formation of smaller nanogels with diameters ranging from 142 to 68 nm. The cyclodextrin-modified dual-responsive nanogels obtained presented an LCST (lower critical solution temperature) in aqueous medium at around 31 C. The incorporation of β-CDAC into...
Wettability properties of PTFE/ZnO nanorods thin film exhibiting UV-resilient superhydrophobicity
, Article Applied Surface Science ; Volume 341 , 2015 , Pages 92-99 ; 01694332 (ISSN) ; Ebrahimi, M ; Nourmohammadi, A ; Moshfegh, A. Z ; Sharif University of Technology
Elsevier
2015
Abstract
In this research, initially anodization process was used to fabricate ZnO nanorods on Zn substrate and then RF sputtering technique was applied to grow a thin layer of polytetrafluoroethylene (PTFE, Teflon) on the coated ZnO nanorods for producing a superhydrophobic surface. According to scanning electron microscopy (SEM) observations, ZnO nanorods were formed with average diameter and length of about ∼180 nm and 14 μm, respectively. Superhydrophilic property of ZnO nanorods and superhydrophobic property of PTFE/ZnO nanorods was investigated by water contact angle (WCA) measurements. It was found that the contact angle varied with the PTFE deposition time. The highest contact angle...
Environmentally responsive surface-modified silica nanoparticles for enhanced oil recovery
, Article Journal of Nanoparticle Research ; Volume 18, Issue 9 , 2016 ; 13880764 (ISSN) ; Mohammadi, A ; Sharif University of Technology
Springer Netherlands
Abstract
Environmentally responsive surface-modified nanoparticles are colloidal nanoparticles coated with, at least, two physicochemically distinct surface groups. Recent advances in the synthesis and production of nanoparticles have enabled the production of environmentally responsive surface-modified nanoparticles with both hydrophilic and hydrophobic surface groups. These nanoparticles act like colloidal surfactants. In this paper, environmentally responsive surface-modified silica nanoparticles are synthesized and used for enhancement of oil recovery. For this purpose, silica nanoparticles are coated with polyethylene glycol chains as hydrophilic agent and propyl chains as hydrophobic agent at...
Improvement of non-aqueous colloidal gas aphron-based drilling fluids properties: role of hydrophobic nanoparticles
, Article Journal of Natural Gas Science and Engineering ; Volume 42 , 2017 , Pages 1-12 ; 18755100 (ISSN) ; Ghazanfari, M. H ; Sharif University of Technology
Abstract
Application of the colloidal gas aphrons (CGAs) in minimizing formation damage by plugging pore mechanism is now wildly accepted due to numerous successful field experience. One of the pivotal factors which affects the pore blockage ability of micro-bubbles is their stability. This experimental study tries to investigate the possible synergistic effect of nanoparticles on improving the stability and other properties of non-aqueous CGA drilling fluids, in both bulk and porous media. In particular, two types of hydrophobic nanoparticles including silicon dioxide nanopowder coated with 2 wt% Silane and nanoclay, in presence of a treated version of bentonite (Bentone 34) as a stabilizer and...
Facile fabrication of superhydrophobic nanocomposite coating using modified silica nanoparticles and non-fluorinated acrylic copolymer
, Article Polymer Bulletin ; Volume 75, Issue 10 , 2018 , Pages 4641-4655 ; 01700839 (ISSN) ; Esmaili, H ; Nazari, M ; Sharif University of Technology
Abstract
A superhydrophobic nanocomposite coating was fabricated using a simple procedure. The nanocomposite is composed of an acrylic copolymer and modified silica nanoparticles. The acrylic copolymer was prepared by free radical copolymerization of methyl methacrylate and dodeycl methacrylate monomers. Silica nanoparticles were synthesized and modified with an alkyl silane reagent, hexadecyltrimethoxysilane. A mixture of acrylic copolymer and modified silica nanoparticles, dispersed in dichloromethane, was then sprayed on glass and filter paper surface. Chemical composition and structure of the coatings were investigated by FTIR, FESEM, AFM, 1H-NMR and GPC. The wettability of the prepared coating...
Experimental investigation on asphaltene biodegradability using microorganism: cell surface properties’ approach
, Article Journal of Petroleum Exploration and Production Technology ; 2018 ; 21900558 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Springer Verlag
2018
Abstract
Asphaltene precipitation is known to be responsible for serious challenges in oil industry such as wellbore damage, oil flow reduction, and plugging of transportation lines. The traditional methods to remove asphaltene deposition are mostly based on chemical solvent. One of the recent proposed green and cost–effect remedial methods is the application of microorganisms capable of consuming the heavy hydrocarbon chains. The cell surface hydrophobicity among others effectively manipulates the efficiency of the microorganism for asphaltene degradation. Besides, surface active agents would affect the microorganism adhesion and cell surface properties, and alters its hydrophobicity. Investigating...
Pressure drop reduction of power-law fluids in hydrophobic microgrooved channels
, Article Physics of Fluids ; Volume 31, Issue 7 , 2019 ; 10706631 (ISSN) ; Moosavi, A ; Sharif University of Technology
American Institute of Physics Inc
2019
Abstract
Using hydrophobic surfaces is one of the efficient methods to preserve energy in fluid transfer systems. However, the studies have been concentrated on Newtonian fluids despite the wide applications of non-Newtonian fluids in daily life and many industries such as the biological, foodstuff, chemical, petroleum, cosmetic, and lab on a chip fields. In this study, we consider power-law fluids as a typical example of non-Newtonian fluids and investigate the effect of hydrophobic microgrooves on the pressure drop in channels by utilizing the phase field method. We demonstrate that the optimum size of the rectangular microgrooves in which the maximum pressure drop reduction (PDR) happens for both...
Experimental investigation on asphaltene biodegradability using microorganism: cell surface properties’ approach
, Article Journal of Petroleum Exploration and Production Technology ; Volume 9, Issue 2 , 2019 , Pages 1413-1422 ; 21900558 (ISSN) ; Ayatollahi, S ; Sharif University of Technology
Springer Verlag
2019
Abstract
Asphaltene precipitation is known to be responsible for serious challenges in oil industry such as wellbore damage, oil flow reduction, and plugging of transportation lines. The traditional methods to remove asphaltene deposition are mostly based on chemical solvent. One of the recent proposed green and cost–effect remedial methods is the application of microorganisms capable of consuming the heavy hydrocarbon chains. The cell surface hydrophobicity among others effectively manipulates the efficiency of the microorganism for asphaltene degradation. Besides, surface active agents would affect the microorganism adhesion and cell surface properties, and alters its hydrophobicity. Investigating...