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hydrophobicity
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Silica aerogel coated on metallic wire by phase separation of polystyrene for in–tube solid phase microextraction
, Article Journal of Chromatography A ; Volume 1500 , 2017 , Pages 69-75 ; 00219673 (ISSN) ; Bagheri, H ; Sharif University of Technology
Elsevier B.V
2017
Abstract
In this research, an attempt was made toward synthesizing a sol–gel–based silica aerogel and its subsequent coating on a copper wire by phase separation of polystyrene. Adaption of this new approach enabled us to coat the metallic wire with powder materials. The use of this method for coating, led to the formation of a porous and thick structure of silica aerogel. The coated wire was placed in a needle and used as the sorbent for in–tube solid phase microextraction of chlorobenzenes (CBs). The superhydrophobicity of sorbent on extraction efficiency was investigated by using different ratios of tetraethylorthosilicate/methyltrimethoxysilane. The surface coated with the prepared silica aerogel...
Free radical graft polymerization of 2-hydroxyethyl methacrylate and acrylic acid on the polysulfone membrane surface through circulation of reaction media to improve its performance and hemocompatibility properties
, Article Journal of Membrane Science ; Volume 564 , 2018 , Pages 762-772 ; 03767388 (ISSN) ; Mousavi, S. A ; Abdekhodaie, M. J ; Sadeghi, M ; Sharif University of Technology
Elsevier B.V
2018
Abstract
In this study, a new facile and cost effective method is used to modify polysulfone membrane surface in order to improve the hydrophilicity, antifouling, and blood compatibility. This modification was performed by adding two functional monomers on the dialysis membrane. Polysulfone (PSF) membranes containing polyvinylpyrrolidone were prepared via phase inversion technique. In the next step, free radical polymerization combined with surface polymerization was used to introduce acrylic acid (AA) and 2-hydroxyethyl methacrylate (HEMA) onto the polysulfone membrane surface via circulation of initiator and monomer solutions across the membrane surface, respectively. Various monomer concentrations...
Comparative structure-toxicity relationship study of substituted benzenes to Tetrahymena pyriformis using shuffling-adaptive neuro fuzzy inference system and artificial neural networks
, Article Chemosphere ; Volume 72, Issue 5 , 2008 , Pages 733-740 ; 00456535 (ISSN) ; Kyani, A ; Sharif University of Technology
2008
Abstract
The purpose of this study was to develop the structure-toxicity relationships for a large group of 268 substituted benzene to the ciliate Tetrahymena pyriformis using mechanistically interpretable descriptors. The shuffling-adaptive neuro fuzzy inference system (Shuffling-ANFIS) has been successfully applied to select the important factors affecting the toxicity of substituted benzenes to T. pyriformis. The results of the proposed model were compared with the model of linear-free energy response surface and also the principal component analysis Bayesian-regularized neural network (PCA-BRANN) trained using the same data. The presented model shows a better statistical parameter in comparison...