Sharif Digital Repository

Polycarbonate (PC) and polyethylene-terephthalate (PET) are important engineering thermoplastics. During last decades these polymers and their blends have been studied extensively due to their wide range of applications. Blends of PET and PC combine mechanical properties and chemical resistance together, which make applicable in various components such as automotive, electrical and of medical parts. It has been accepted that PET/PC immiscible blends are subjected to transesterification reactions during thermal processing, which produces PET-PC copolymer chains. In fact, scissioning and substitution of ester/carbonate functional groups of PC and PET at the interface, transforms the initial... 

In this study, copper-alumina composite specimens with different reinforcement content were produced in two routes, i.e. in-situ and ex-situ; one specimen as functionally graded material (FGM) was also produced. In first method, copper and aluminum powders were initially alloyed by mechanical alloying route and then the copper oxide powder was added as oxidizer. For the fabrication of Cu-Al2O3 composites using ex-situ method, alumina nano particles powder was added to elemental copper powder. FGM specimen consists of five layers, i.e. pure copper, copper matrix composite having 2, 3, 4, and 5 volume percent alumina. To reduce the particles agglomeration and homogeneous distribution of... 

Reservoir simulation models are profound tools in reservoir management. Number of grid blocks in a simulation model is much less than the number of grid blocks in geological model, therefore geological model must become upscaled in order to construct simulation model with convenient dimensions. This causes loosing of some details and introduces errors due to discretization and homogenization. One method of construction of an efficient computational grid is use of adaptive mesh refinement (AMR) methods. These methods refine computational grid in regions needing further resolution. An error indicator is used for determining regions candidate for refinement or coarsening. In present study... 

Alumina as an engineering ceramic has special characteristics such as hardness, high abrasive, fatigue and corrosion resistance but suffers from low toughness. One effective method in improving toughness is adding second phases such as tetragonal zirconia and carbon nanotubes.
In this research, alumina- zirconia nanopowders has been prepared by solution combustion method and carbon nanotubes was added to it by two different ways: 1) in situ synthesis of CNTs by CVD 2) dispersion of CNTs by heterocoagulation method. In the case of in situ synthesis of CNTs in AZ matrix, the synthesis temperature and flow ratio of N2/C2H2 gases was investigated and optimum conditions were 800̊C and 300/30,... 

For application such as electrical contacts and spot welding electrodes, both high electrical conductivity and wear resistance are required. Additionally, such parts should have structural stability at evaluated temperature. Copper based composites containing carbides or oxides reinforcement can be the good choice for production of such parts. In present work, in-situ Cu/NbC composite via mechanical alloying with homogenous distribution of nano reinforcement particle has been produced. For this purpose, in first stage, copper powder was milled with 5, 8, 10 and 12 wt. % of niobium powder in two types of mills, i. e. vibratory dicky mill and planetary ball mill for 5 and 32 h respectively. At... 

Hydraulic fracturing process as one of the most important ways to inhanse of production requires careful study and investigation and due to its importance has been studied for decades. The effect of this process on the production at oil and gas industry has many complexities and these complexities with the complex structure of natural gaps, would be multiplied. In this thesis effect of hydraulic fracturing operation on the production of natural fractures at naturaly fractured reservoirs from two aspects of hydraulic and geomechanics will be investigated. First we provide models for fractures network by using UDEC software after that investigate the effect of hydraulic farcture on the natural... 

Friction Stir Processing (FSP) was used to fabricate Al1050/Fe3O4 nanocomposite in three different weight percent (2.5%, 4% and 5.3%). The effects of rotational speed (1200-1600 rpm), traverse speed (5-15 cm/min) and the number of FSP passes (1, 2, 3 and 6 passes) on microstructure and mechanical properties were investigated. In order to study microstructure evolution, optical and field emission scanning electron microscopes were used. Micro hardness, longitudinal and transverse tensile and wear test were carried out to investigate mechanical properties of the obtained composites. Results showed that increase of the rotational speed and decrease of the traverse speed in 1 pass processed... 

Myocardial Infarction occurs due to sudden blockage in a coronary artery and causes necrosis of myocardial tissue. Since myocardium is unable to self-regenerate, cardiac tissue engineering has become a promising therapeutic approach for MI treatment by restoring heart function via combination of cells, biomaterials and signaling factors. For this purpose, myocardial extracellular matrix (ECM) is an attractive biomaterial providing better biomimetic for cultured cells. In this project, we synthesized an in situ forming hydrogel derived from myocardial ECM and for improving mechanical and electrical properties of ECM hydrogel we added oxidized alginate (OA) with 5% oxidation degree and APTMS... 

Metal matrix composites (MMCs) reinforced with ceramic particulates have been attractive as high specific strength materials utilized in automobile and aerospace industries. In order to enhance refinement and dispersibility of the ceramic particulates, the synthesis process with in-situ reactions has been investigated. The in-situ synthesis can avoid complexity and harmfulness.processes of powder handling and produce fine inclusions in the matrix with rather lower costs than conventional fabrication methods. In this study, the Al-based composites with TiC, TiB2 and Al2O3 particulates have been prepared by the by mechanically activated self-propagating high-temperature synthesis (MASHS) on... 

Since cartilage has limited self-regeneration, in-situ forming hydrogels can act as an ideal scaffold for cartilage tissue engineering to fill the defect gap due to their ability to homogeneously encapsulate the desired cells, efficient mass transfer and minimally invasive characteristics. In this project, an injectable hydrogel with improved structure by adding silk fibroin (SF) nanofibers and better biochemical properties by employing the cartilage extracellular matrix (ECM) was fabricated. The in-situ forming hydrogel is consisted of different concentrations of ionic crosslinked alginate incorporated with different concentrations of SF nanofibers and 1% w/v enzymatically crosslinked... 

Basically, it is required that the materials used as electrical contacts should have good thermal and electrical conductivity and certain strength. The copper base composites with fine TiO2 particles as reinforcement have almost identical electrical and thermal conductivity with copper; in addition, they have the advantage over pure copper in high strength owing to the dispersion of the fine TiO2 particles, which improve copper matrix strength through impeding dislocation movement. In this present work, at the initial stage, Cu and Ti powders were mechanically alloyed for 60h under Argon atmosphere, and then added Cu2O powders as oxidant. The specimens, containing different amounts of TiO2,... 

Effects of temperature on the behavior of soils and rocks have been studied widely in recent years. Following the need for understanding the effects of temperature on the behavior of clayey soils, several experimental and numerical studies on thermo-mechanical behavior of clayey soils have been carried out and a number of thermo-mechanical constitutive models have been developed for saturated and unsaturated clayey soils. In this research, a two-yield surface thermo-plastic constitutive model developed by Abuel-Naga et al. (2007, 2009), has been chosen for THM analysis of the behavior of saturated clayey soils. This constitutive model is based on Modified Cam-Clay (MCC) model. The MCC model... 

Periodontitis is a common inflammatory disease that affects the periodontium.Periodontium includes two hard tissues of cementum and alveolar bone and also soft tissue of periodontal ligament. The appropriate function is based on the consistency and accurate interaction of them. The complex structure, the low potential of the body for spontaneous healing, and technical problems such as bacteria accumulation, limited access, and small operating field cause no complete treatment can be achieved until now.In this project, at first collagen type I was extracted from Bovine Achilles tendon. Then, polymer modification was done to 39.95 µg/mg (Tyramine/ Collagen). An In situ gel based on modified... 

In this study, in situ Al-Al3Ti-Al2O3 nanocomposite has been fabricated on thermal decomposition of tialite (Al2TiO5 or AT) precursor in the aluminum matrix through powder metallurgy method. The high-temperature mechanical property of Al-Al3Ti-Al2O3 on this procedure has been investigated. In the first step nano-structured tialite were synthesized through citrate sol-gel methods. Then 3.5 wt.% tialite powder was mixed with aluminum by high energy vibratory milling for 3 hours. In the next step, green compacts of mechanically milled powder mixtures were sintered at 530°С for 6 hours under argon atmosphere. In the final step, hot extrusion as a consolidation method reduces the sample voids,... 

A broad range of plain carbon steels have ferrite-pearlite microstructures, which are used in many industrial applications due to the good strength and formability provided by the typical combination of ferrite grains and pearlite colonies. The mechanical behavior of ferrite-pearlite steels inherently originates from the configurations of ferrite grains and pearlite colonies, which comprised alternating lamellae of cementite with randomly distributed orientations in a ferrite matrix. In this thesis, three different experimental-numerical approaches were employed to investigate the deformation behavior, damage mechanisms, and formability of the ferrite-pearlite steels. At the first step, two... 

In this study polyoxotungstate-based inorganic-organic hybrid [C272H162N80Cu16.5W36O129Na9] .80.5H2O was synthesized in situ. This inorganic-organic hybrid resulted from the reaction between copper salt and sodium tungstate with the benzimidazole ligand. Combining inorganic-organic hybrid with polyoxotungstate improved the ability of this catalytic system in oxidation and cycloaddition reactions. The resulting product was identified by IR, X-ray diffraction (XRD), elemental analysis (CHNS), inductively coupled plasma (ICP-OES), field emission scanning electron microscope (FE-SEM) and EDX were technique. The catalyst was used in optimal conditions in sulfide oxidation and azide-alkyne... 

Diagnostic Fracture Injection Test (DFIT) uses to identify the characteristics of the reservoir, including minimum horizontal stress, permeability, initial reservoir pressure, etc. The general steps of this process include fluid injection, fracture initiation in the matrix, fracture propagation and its closure due to fluid leak-off. The results of DFIT are analyzed in two stages based on the fracture closure event. The objective of this study is to investigate the effect of leak-off mechanisms on pressure-dependent leak-off (PDL), tip extension and fracture storage. To do so, different methods are used for identifying the cooperating parameters at each step. In order to analyze DFIT, a... 

In this research, aluminum titanate or tialite with the chemical composition of Al2TiO5 was synthesized as nanostructured form using the sol-gel method with the aim to serve as a chemical source for aluminum and titanium elements within the fabrication of in-situ Al2O3-Al3Ti-reinforced aluminum matrix nanocomposites. Since the aforementioned nanocomposite is produced based on the thermal decomposition of tialite, the thermar decomposition of this material in air atmosphere, under applied mechanical strain, and direct contact with the underlying aluminum was comprehensively evaluated. The empirical results showed that as tialite is exposed to aluminium, the reaction starts from low... 

Shape memory polymers have the potential to use in the field of biomedical applications. In this research, polyurethane structures have been synthesized based on the Diol mixtures, consisting of polycaprolactane diol (PCL-diol) and poly (lactic acid) diol (PLA-diol). Aim of reasearch is about evaluating poly (lactic acid) effect in structure of the polyurethane. At the same time, cellulose nanocrystals (CNC) have been added to polymer matrix to improve properties. The synthesis of acrylated polyurethane, included the synthesis of polyurethane acrylate prepolymer. Next, this prepolymer has been cured by adding the reactive diluent and some polyol. The cured systems were investigated, finally,...