Sharif Digital Repository

Conversion of CH4 molecule into higher hydrocarbons using two different wavelengths of 248 nm KrF laser and 355 nm of third harmonic of Nd:YAG laser is studied experimentally and theoretically. The stable products are analyzed and the effect of pressure on conversion of methane is measured. The detected reaction products are C2H2, C2H4, and C2H6. The conversion efficiency of 33.5% for 355 nm in comparison to 2.2% conversion for 248 nm for C2H2 is achieved. The potential of laser parameters as an important variable in controlling of final products is investigated  

The lasing mechanism and temporal output profile of distributed feedback dye lasers is investigated, using a model based on induced polarization in the dye solution, where a more accurate behavior of the laser output is predicted. It is found that the temporal output profile of the laser is mostly determined by the concentration of dye solution and the lifetime of the upper laser level of dye molecules. To a large extent, the results of this work agree with experimental studies, even at high-level pump intensities where the self Q-switched model fails to be applied. Especially, the experimentally observed irregular intensity profile of laser output is explained. It is also shown that, when... 

In this work, we introduce a new ellipsoid model to describe bubble acceleration of electrons and discuss the required conditions of forming it. We have found that the electron trajectory is strongly related to background electron energy and cavity potential ratio. In the ellipsoid cavity regime, the quality of the electron beam is improved in contrast to other methods, such as that using periodic plasma wakefield, spherical cavity regime, and plasma channel guided acceleration. The trajectory of the electron motion can be described as hyperbola, parabola, or ellipsoid path. It is influenced by the position and energy of the electrons and the electrostatic potential of the cavity. In the... 

The important role of collagen fibers in LILT has been observed. However there is still unclear information about light characteristics, such as coherence and polarization. Collagens behavior in response to different polarization is presented in this study. We investigate the distribution and structure of collagen bundles in full-thickness human skin in response to laser with different polarization by ellipsometry technique. For this study, we chose skin from the back part of a white man. The light source is HeNe laser. Samples are irradiated by three different polarizations. Sample S is irradiated using the electric field vector of the polarized laser radiation aligned in parallel with the... 

Laser-directed energy deposition is a fast-growing method for manufacturing complex geometries and materials that are hard to shape with conventional manufacturing methods. However, there are some aspects of this process that need more researches and experiments to be completely understood. Two of these are laser attenuation and laser intensity distribution on the workpiece surface. In this paper, a new method is proposed for calculating laser attenuation without simplification applied in previous works. Despite other studies that consider a predefined powder distribution, the result of a developed 3D CFD model of the powder stream is utilized for defining the position of particles in the... 

Here we report on the production of highly directed ion blocks by plasma interaction of ultraviolet wavelength light produced from a KrF laser. This may support the requirement to produce a fast ignition deuterium-tritium fusion at densities not much higher than the solid state by a single shot petawatt-picoseconds ultraviolet laser pulse. Using double Rayleigh initial density profiles, we are studying numerically how the nonlinear force necessary to accelerate plasma blocks may reach the highest possible thickness. Propagation of plasma blocks and the volumetric hot electrons can be shown in detail. Results of computations for wavelengths of two lasers are compared, which show that the... 

The multielectron dissociative ionization of CH4 and CH2O molecules has been investigated using optimum convolution of different dual tailored short laser pulses. Based on three dimensional molecular dynamics simulations and TDDFT approach, the dissociation probability is enhanced by designing the dual chirped-chirped laser pulses and chirped-ordinary laser pulses for formaldehyde molecule. However, it is interesting to notice that the sensitivity of enhanced dissociation probability into different tailored laser pulses is not significant for methane molecule. In this presented modifications, time variation of bond length, velocity, time dependent electron localization function and evolution... 

Machining of ceramics often involves many challenges due to their high hardness, brittleness, and low-thermal conductivity. Laser Assisted Machining (LAM) is a promising technology for improving the machinability of hard-to-cut materials. In this work, the effect of laser heating in the LAM process on Slip Cast Fused Silica (SCFS) ceramics is investigated by conducting a numerical thermal analysis of laser effects on material behavior. A transient three-dimensional heat transfer analysis for Laser Assisted Turning (LAT) of SCFS is performed using finite-element method. Temperature distributions in SCFS cylindrical specimens are obtained. Moreover, the influence of laser parameters, such as... 

Machining of ceramics often involves many challenges due to their high hardness, brittleness, and low-thermal conductivity. Laser Assisted Machining (LAM) is a promising technology for improving the machinability of hard-to-cut materials. In this work, the effect of laser heating in the LAM process on Slip Cast Fused Silica (SCFS) ceramics is investigated by conducting a numerical thermal analysis of laser effects on material behavior. A transient three-dimensional heat transfer analysis for Laser Assisted Turning (LAT) of SCFS is performed using finite-element method. Temperature distributions in SCFS cylindrical specimens are obtained. Moreover, the influence of laser parameters, such as... 

Optomechanical and electromechanical cavities have been widely used in quantum memories and quantum transducers. We theoretically investigate the robustness of optomechanical and electromechanical quantum memories against the noise of the control laser. By solving the Langevin equations and using the covariance matrix formalism in the presence of laser noise, the storing fidelity of Gaussian states is obtained. It is shown that the destructive effect of phase noise is more significant in higher values of coupling laser amplitude and optomechanical coupling strength G. However, by further increasing the coupling coefficient, the interaction time between photons and phonons decreases below the... 

Effect of nanosecond lasers on the methane dissociation is experimentally studied by using three different laser wavelengths at 248 nm, 355 nm and 532 nm. C2H2 generation is measured as a major reaction product in experiments and the energy consumptions in production of this component are measured as 5.8 MJ/mol, 3.1 MJ/mol and 69.0 MJ/mol, for 355 nm, 532 nm and 248 nm wavelengths, respectively. The mechanism of conversion and production of new stable hydrocarbons is also theoretically investigated. It is found that in theoretical calculations, the ion-molecule reactions should be included and this leads to a unique approach in proper explanation of the experimental measurements  

A high intensity laser normal incident (1020 W/cm2) on a vacuum-plasma interface produces high harmonics in reflected components. Efficiency of high harmonics increases with the intensity laser incident. So the non-relativistic velocities of the particles vary to the relativistic velocities. Consequently, electrons in such high fields are predicted to quiver nonlinearly, moving in figure eight patterns, rather than in straight lines, and thus to radiate photons at harmonics of the frequency of the incident laser light. To meet the challenge of high power, short wavelength coherent radiation generation, it is quite to investigate the conditions under which harmonics generation efficiency can... 

A Gaussian laser beam tightly focused through a high-numerical-aperture objective lens, so-called optical tweezers, is widely used for piconewton-range force spectroscopy. Utilizing a proper value for parameters such as bead size, numerical aperture of the objective, and power of the laser is always a challenge. Here, we show which set of values for the parameters can maximize lateral trapping efficiency. Our results show that for a high-numerical-aperture force spectroscopy, a bead with a diameter of 4–5 µm is suitable, and that for manipulation using large beads, utilizing a proper value for laser power and numerical aperture of the objective is crucial. We present a practical method for... 

A Gaussian laser beam tightly focused through a high-numerical-aperture objective lens, so-called optical tweezers, is widely used for piconewton-range force spectroscopy. Utilizing a proper value for parameters such as bead size, numerical aperture of the objective, and power of the laser is always a challenge. Here, we show which set of values for the parameters can maximize lateral trapping efficiency. Our results show that for a high-numerical-aperture force spectroscopy, a bead with a diameter of 4–5 µm is suitable, and that for manipulation using large beads, utilizing a proper value for laser power and numerical aperture of the objective is crucial. We present a practical method for... 

In this paper, two-axis dielectric laser acceleration is proposed by introducing a dual-grating base laser accelerator structure excited with two orthogonal propagating ultrashort laser pulses. A 2D periodic structure is designed that provides phase synchronicity between the relativistic particle beam and orthogonal propagating laser pulses. In this way, the particle beam can gain energy from both laser pulses simultaneously. It is numerically demonstrated that utilizing this method increases both the acceleration gradient and acceleration factor up to90%in comparison with dual-grating dielectric laser acceleration. Also, deflecting force elimination, particle beam quality, and bunch... 

In this study WO x films were deposited by laser ablation of ultra-pure (5N) tungsten trioxide targets onto SiO2 or silicon substrates at 250°C temperature, 100 mTorr oxygen partial pressure and 1×10-5 Torr vacuum. Surface chemical states and compositions of the deposits were determined by X-ray photoelectron spectroscopy. The results showed that deposits in oxygen partial pressure contain W6+ with x ∼ 3.1, while vacuum-deposited films have different W states with various percentage distributions as W4+>W5+>W 6+>W0, and x ∼ 1. We used fast electrical resistance measurement as a probe to study the deposition process. Film resistance as a function of deposition time in vacuum revealed some... 

Laser Powder Deposition (LPD) process is an advanced material processing technique which has many applications. Despite this fact, reliable and accurate control schemes have not yet fully developed for the process. In this paper, the problem of controlling the clad height in the LPD process is studied. Due to a faster response of the process to change in scanning velocity over the laser power, the scanning velocity is selected as the input control variable. Since the governing equations of the LPD process are complex for designing a controller, an identified nonlinear dynamic model is used. The model is a Hammerstein model with a linear dynamic and a nonlinear memoryless block. The model... 

In the present work, the densification and microstructural evolution during direct laser sintering of metal powders were studied. Various ferrous powders including Fe, Fe-C, Fe-Cu, Fe-C-Cu-P, 316L stainless steel, and M2 high-speed steel were used. The empirical sintering rate data was related to the energy input of the laser beam according to the first order kinetics equation to establish a simple sintering model. The equation calculates the densification of metal powders during direct laser sintering process as a function of operating parameters including laser power, scan rate, layer thickness and scan line spacing. It was found that when melting/solidification approach is the mechanism...