Sharif Digital Repository

Magnetite (Fe3O4) nanoparticles were synthesized and coated with Oleic Acid using the co-precipitation method. The particles were characterized using DLS, FT-IR, SEM, XRD, VSM and UV-Vis spectrophotometry analysis. The mean size of particles was 28.8 nm and the FT-IR analysis indicated that Oleic Acid was coated suitably on the nanoparticles. The vsm test indicated no hysteresis loop for the particles, defining the superparamagnetism of them. A nanofluid containing nanoparticles in 5wt% Acetic Acid in Toluene as the base fliud was prepared. The stability of this nanofluid was determined using UV-Vis spectrophotometry to be less more then 95% in the first two hours. This nanofluid is used as... 

The use of wind energy and wind generators as an inexpensive type of renewable energy sources is increasing. Wind farms and distributed wind generators connected to the power transmission and distribution systems and microgrids, and wind generators in standalone mode of operation affect the stability and power quality of the grid. In this thesis, the performance of a matrix converter in grid connection of variable speed PMSG–driven wind turbine is improved. In this way, by transferring the matrix converter modulation matrix into the synchronous reference frame and decomposing it into the singular values, a new general method is proposed for analysis, modelling and modulation of a matrix... 

Measuring the speed and position of the rotating part and using the speed and position information in the closed loop control of electric machines is very important. Various sensors are available for this purpose, including resistive sensors, capacitive sensors, encoders, synchros, resolvers, Halleffect sensors, and etc. Common encoders include optical and magnetic types. There are two main problems in using an encoder as a sensor: determining/maintaining accuracy during change of rotational direction and determining the absolute position. Both of the mentioned challenges have been investigated in the case of optical encoders and some solutions have been provided to overcome them. Although... 

Nowadays , application of enzymes as biocatalysts in wastewater treatment processes is increasing. It is economically important to reuse enzymes and increase their stability in these types of processes. Therefore, was immobilization of enzymes and using them in wastewater treatment have a great importance.In this project, Horseradish peroxidase enzyme, whose effect on phenol removal reactions in other studies has been proven before, was immobilized on the alginate-coated magnetic nanoparticles, to investigate the effect of immobilization on the stability and function of this enzyme for phenol removal. The enzyme was immobilized at the temperature of 25 ° C and pH = 8, according to the data... 

Magnetic elastomers are smart materials that consist of a combination of elastomeric matrix and magnetic particles. The mechanical and magnetic properties of this materials are changed by Applying an external magnetic field. The presence of an external magnetic field can cause these elastomers deform largely.Significant deformations of the magnetic elastomers, has made them suitable for a wide range of applications. The aim of this project is to solve the governing equations of magnetic elastomers with finite element method. Since there are no suitable models for the behavior of these elastomers in the commercial softwares, magnetic field module and solid mechanics module should be coupled... 

The use of tin-lead solder alloys (Pb-Sn) has been limited due to environmental problems in recent years, and several types of research are being carried out on lead-free solder alloys. However, these solders have weaker physical and thermal properties than Pb-Sn solders. In recent years, researchers have been trying to improve these solders' physical and mechanical properties by adding reinforcing particles to the solder and using a magnetic field during melting and solidifying the solder. On the other hand, with the growth path of miniaturization and, simultaneously, compaction and integration of electronic equipment, electronic circuits should have higher current density, better... 

In recent years, parallel to the development of industrial, the use of organic solvents and the environmental pollution caused by their increasing, more attention to remove these contaminants growing. Among the various absorbents to absorb pollutants from the environment, iron oxide nanoparticles have many applications in absorption and removal of environmental pollutions due to their high specific surface area, magnetic properties and ease of separation. The aim of this research is synthesis of a magnetic gel for absorption of organic solvents which in its structure magnetic nanoparticle and hydrophobic monomer is used. The most important advantages are the ease of isolation of the desired... 

In this thesis, marx pulsed power generators are investigated. Due to very large magnitude of its output voltage and very fast rise time, Marx generator is the first choice in lots of pulsed power applications. A significant barrier in the implementation of this generators are the switches with witch the structure is made. The short magnitude nominal voltage and current of the solid state switches lead to use of Spark Gaps in which the determinative parameter of the switch to turn on, is its breakdown voltage. These switches have some limitations in repetition rate and turn off ability. However due to very high range of nominal voltage and currents, they are an appropriate choice for marx... 

So far, investigations have shown that open dielectric resonator antennas (DRAs) offer several advantages at microwave and millimeter wave frequencies. These advantages include small size, large impedance bandwidth, high radiation efficiency, ease of manufacturing and simple feed-coupling mechanisms (such as probe coupling, aperture coupling or proximity coupling to micro-strip lines). Most microwave ferrites have dielectric constants in the desirable range and they can be used in place of dielectric materials. Such ferrite resonator antennas (FRAs) offer a potential advantage in that their permeability tensor can be controlled by applying an external magnetic field. Up to now and by the... 

Circulating tumor cells (CTCs) isolation from a blood sample has an important value in cancer research and its treatment. Microfluidics provides a great potential for target cell separation from biological samples by using different physical principles. Among the microfluidic cell separation methods, the inertial microfluidic devices are advantageous in handling samples for point-of-care diagnostics due to their simple structure, fast, label-free and low-cost characteristics. In this thesis, first, we designed and investigated the application of a symmetric serpentine inertial microfluidic device for the separation of CTCs from whole blood. For this purpose, numerical modeling was performed... 

Porosity and high surface area is a profound concept for creating advance materials. Nanofibers are an important class of nanomaterials with high surface to volume ratio as a result of long lengths and nano-to-micro-scale diameters. Electrospinning is a simple method for producing nanofibers from different polymers and composites and prepare highly efficient sorbents. Polymeric nanocomposites are claimed to exhibit markedly improved mechanical, magnetic, thermal and electrical properties. Magnetic iron oxide nanoparticles have gained great attentions due to their low toxicity, stability and biocompatibility and have been extensively used to induce magnetic property to the desired sorbents.... 

Current study reports a state-of-the-art approach for synthesis of nanocatalyst based on Oxo-vanadium Schiff base complex which itself is, covalently, immobilized on core-shell magnetic nanoparticles of silica-modified magnetite (Fe3O4@SiO2) and the substantial potential it offers as heterogeneous catalyst in selective oxidation of sulfides.Synthesized materials and complexes in this project were characterized by means of modern spectral devices such as FT-IR, XRD and SEM.Unlike routine process of the preparation of heterogeneous catalysts that requires further modification of the core-shell nanoparticles with capping agents, here we have been capable of cutting some time-consuming steps... 

Magnetic shape memory alloys (MSMAs) are a new class of smart materials which exhibit properties such as large reversible strains and high performance frequencies. These unique properties, offer magnetic shape memory alloys as an option in applications such as actuators, sensors and energy harvesters. In this thesis, the equations of magnetic shape memory alloys by considering nonlinear terms of Von karaman in strain-displacement relations, is expanded by using the theory of thin plates in two dimensions which can be used for plate equations with any boundary conditions by applying elastic boundary. In order to verify the obtained model, the equations of motions of magnetic shape memory... 

Quantum spin liquids are characterized by the lack of long range magnetic order at zero temperature due to strong quantum fluctuations in frustrated magnets, emergent fractionalized excitations coupled to gauge fields, pattern of long-range entanglements, and topological orders. Since the theoretical predictions dated back to the seventies, a huge amount of both theoretical and experimental efforts put forward to explore these emerging phenomena in real materials. Besides the organic compounds with spin liquid ground states, recent years have witnessed the dawn of new oxide materials such as α - RuCl3 and Na2IrO3 which may host spin liquid at low temperatures. The ground states of the latter... 

LED Drivers with near 1 power factor, Because of using electrolytic capacitors (to become flicker-free) have lifetime drawbacks. This research will focus on solutions to use magnetic energy storage instead of electrolytic capacitors (used for energy storage) to solve lifetime drawbacks and decrease output light flicker. Calculations show that magnetic energy density using iron powder cores are lower than electrolytic capacitors, also a little lower than ceramic capacitors, but obviously higher than film capacitors. After calculations, conventional isolated and non-isolated LED drivers will be reviewed and new non-isolated off-line 230v with 10w output power LED driver with magnetic energy... 

In this work ionic liquids as the new generation of solvents are studied. First, Ionic liquids are introduced and their applications and characteristics are briefly discussed. Then, one of the most potential applications of ionic liquids in separation process (Aromatic-Aliphatic separation) is studied and compared with the common and alterative separation processes. In experimental section, large amount of 1--ethyl 3-metyl pyridinium ethyl sulphate ionic liquid was synthesized with a purity of above 99%. Experimental studies of separation of toluene from its mixture with n-heptane with the aid of synthesized ionic liquid were conducted and acceptable results are obtained. Experimental LLE... 

Cancer diagnosis area has recently been in the limelight of the medical research and there exist an unremitting focus on the devices & technologies which enable cancer detection in its victims. Lately a genius diagnostic method based on isolation and entrapment of circulating tumor cells has been developed which pave the path for cancer identification. These circulating cells which are detached from the primary tumor are carried out through body by means of circulation system. They play key role in phenomenon called metastasis. Separating these rare cells from multifarious background blood cells, assessing their quantity can supply valuable information on the stage of disease as well as its... 

Magnetic levitation is an appropriate solution for noncontact 3D manipulation. Workspace of the previously proposed maglev systems is confined to a relatively small cube, which severely limits the application of this technology. In addition, most of the previously given mechanisms require the design and application of a subsystem in order to unify their magnetic field. In this paper, a moving magnet is proposed which results in a horizontally extendable workspace; moreover, the field unifying section is not needed since one electromagnet only is used. Further, details of the mechanism and finite element based design procedure of the magnet are presented. Dynamic equations of the system... 

In the present research the methods and challenges to ocular drug delivery have been investigated with more emphasis on ocular diseases that do not have any approved treatment. Periocular route is a promising alternative to the common routes of ocular drug delivery especially for treatment of posterior eye diseases. Based on barriers for efficient drug delivery to the eye, magnetic drug targeting revealed to be influential to eliminate some obstacles of this route which has not been worked before. It is hypothesized that the particles can pulled into the eye or will be trapped inside the sclera tissue or even if it is not happened, they can stay behind the sclera and magnetic force can... 

Magnetic shape memory alloys (MSMAs) are a new class of smart materials that exhibit characteristics of large recoverable strains and high frequency. These unique characteristics, make MSMAs interesting materials for applications such as actuators, sensors, and energy harvesters. This thesis presents a three-dimensional phenomenological constitutive model for MSMAs, developed within the framework of irreversible continuum thermodynamics. To this end, a proper set of internal variables is introduced to reflect the microstructural consequences on the material macroscopic behavior. Moreover, a stress-dependent thermodynamic force threshold needed for variant reorientation is introduced which...