Sharif Digital Repository

In this thesis, functionalized Fe3O4 nanoparticles have been utilized as a support for immobilization of homogeneous catalysts. The catalytic activity of the supported heterogeneous nanocatalysts was investigated in hydrocarbon and sulfide oxidation reactions. In the first part of this research, imidazole functionalized Fe3O4 nanoparticles (Fe3O4@SiO2-Im) were used as a support to anchor manganese porphyrin complex, [MnT(4-OMeP)P]OAc; via axial ligation. Catalytic application of the immobilized manganese porphyrin was studied in oxidation of alkenes and sulfides. To find suitable reaction conditions, the effect of different parameters such as solvent and temperature on immobilization process... 

The theoretical and experimental investigation of quantum chromodynamics phase diagrams is one of the most important subjects in elementary particle physics. Some properties of this diagram are the existence of the hadron phase at low temperatures and chemical potentials, color superconductivity at low temperatures and high chemical potentials, and quark-gluon plasma at high temperatures and chemical potentials. In recent years, the main focus was on the study of quark matter at very high chemical potentials. In particular, the formation of magnetic dual chiral density wave was investigated using the Nambu–Jona-Lasinio effective model. In this thesis, we study, in particular, the phase... 

Micro-Robotics is implemented by researchers inclusively in last decades in different fields such as, biolotechnology, space, army and medical engineering. However, micropositioning is the main challenge in such projects, since determination and control of micro-robot’s position for drug delivery, artificial insemination and other medical applications are too significant. In this thesis, a method for controlling a microswimmer’s position in two dimention by an external magnetic field has been proposed. Modelling of magnetic field and magnetic gradient are some important challenges due to the fact that in control loop, a fast and optimal model for estimation of magnetic filed and gradient is... 

Physical properties of $Re_1 Ba_2 Cu_3 O_{7-\delta} (Re123)$ high-temperature cuprate superconductors attract many of physicists due to their high transition temperature (above Nitrogen boiling point), relatively simple synthesizing and high critical current density. Among this family, Nd123 and Sm123 single-crystal compounds have the highest transition temperature and critical current density in the magnetic fields less than 2 Tesla. In addition, due to the near ionic radius of Nd and Sm elements, it is possible to synthesize $Nd_{1-x} Sm_x Ba_2 Cu_3 O_{7-\delta} (0 \leq x \leq 1)$ compounds with no significant dislocation. In order to investigate the effects of such doping on electrical... 

Permanent magnets play an essential role in the structure of the electric motor, but due to limited resources, many efforts have been made to meet the need for them. One of the most important types of non-permanent electric motors is reluctance motors. Despite their antiquity in design, torque ripples have led to the limited use of reluctance motors, but advances in science have made it possible to control these ripples.As a result of the major advantages such as low manufacturing costs, high efficiency, and uncomplicated structure, these motors have been the subject of many researches. One way to eliminate the problem of torque ripples is to increase the number of teeth, but in the common... 

There are two ways for quality control testing of power transmission systems in various industries. A method of testing the specific positions of power transmission, and final testing (Automotive road tests), respectively. In various stages of design, manufacturing and quality control components, power transmission systems, require detailed information on the performance of parts. It's a special place for each transmission experiment designed and manufactured. Gearbox as an important component of the transmission of this issue is no exception. Magnetic gearbox has a new generation of power transmission systems in the last decade of the optimization is presented. In recent years, several... 

Spin-Transfer Torque Magnetic RAM (STT-MRAM) is the most promising nonvolatile memory to replace SRAM technology in the Last-Level Cache (LLC) due to its benefits such as high density, near-zero cell leakage, and immunity to soft errors.However, due to its high retention failure and read disturbance rates in the downscaled technologies and the low data access rate in the LLC and the high number of read accesses, retention failure and read disturbance have become the main reliability challenges for STT-MRAM cache memory. The existing approaches to overcome these challenges impose significant area and performance overhead or adversely affect the other types of failures. In this thesis, we... 

The heart is a vital part of the body whose primary function is to pump blood throughout the body. The world's leading cause of deaths is due to heart problems. Today, most countries invest heavily in solving these problems and preventing the resulting deaths. One solution for patients with advanced heart disease is to use ventricular assist devices. This device is Used in parallel to the patient's heart, completely or partially replaces the normal functioning of the heart and provides much of the blood needed by the body. The purpose of this study is to design, manufacture and parametrically optimize a ventricular assist pump and its driver system. Since blood is clotted in contact with... 

Liquid marbles are droplets enwrapped by a layer of micro/nanoparticles. Due to the insulation of inner fluid from the environment, the lower evaporation rate of the fluid, and the capability of motion even on hydrophilic surfaces, these liquid marbles, as an alternative to conventional droplets, have attracted the attention of researchers in digital microfluidics. Utilizing ferrofluid as the liquid core of the liquid marbles enables remote control over the liquid marbles by an external magnetic field. In this research, the dynamic behavior of ferrofluid liquid marbles under the magnetic field generated by an electromagnet is investigated. In this research, governing physics on the motion of... 

This study aims at investigating the vibration analysis and stability of Graphene Nano-Ribbon (GNR) under a magnetic field using continuum mechanics approach and an efficient hybrid modal-molecular dynamics method. The force distribution on the GNR due to the magnetic field is determined by Maxwell's equations, Biot-savart law, magnetic dipoles and Lorentz force law.
Using the continuum mechanics model, the vibration of the GNR in a magnetic field is investigated by some problems and the resonance frequencies, stability boundaries and critical load are studied.
Furthermore, in this present study, an efficient hybrid modal-molecular dynamics method is developed for the vibration... 

Transcranial direct current stimulation (tDCS) over the different brain regions has been documented in clinical and laboratory experiments. Anodal tDCS on the dorsolateral prefrontal cortex (DLPFC) has shown promising effects in enhancing cognition. Furthermore, such stimulations have been proposed in treatment of several neurological and psychological disorders. Investigations have verified the positive effect of such stimulations on drug addicts by diminishing their drug craving after stimulation. In spite of the extended research in this field, the effect of tDCS on different brain region and brain networks has yet not been studied through computational models. In this study, we evaluated... 

The main strategy for treating solid cancers is based on the very early diagnosis of a malignant tumor, and in general the smaller the tumor, the greater the likelihood of successful treatment. Magnetic Resonance Imaging (MRI), based on the nuclear magnetic resonance phenomenon, provides the possibility of detecting early malignant tumors with the assistance of appropriate contrast agents. Hence, researchers continue to develop novel magnetic materials to achieve this aim. Superparamagnetic nanoparticles have become the focus of these studies because their superparamagnetic, biocompatible and hydrophilic properties would be revealed after modifying the particle surface by suitable... 

In this investigation, effect of processing parameters on the soft magnetic properties of nanocrystalline Fe85Si10Ni5 (at. %)-phenolic resin composites were studied. The nanostructured powders were obtained by mechanical milling in a high-energy vibratory disc mill. Annealing was performed to decrease internal strains and density of dislocations. The microstructure, morphology and DC magnetic properties of the milled powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and a vibrating sample magnetometer (VSM). Bulk samples were obtained by compaction in different pressures and temperatures. The effects of different compaction treatments and annealing... 

Magnetic shape memory alloys (MSMAs) are a new kind of smart materials which are great alternatives for energy harvesting systems due to some unmatched characteristics such as reversible large strain, high cycle fatigue and fast time response. In this work, an energy harvesting system using MSMA is studied. For this goal, a 3-D thermodynamic-based MSMA model is applied for predicting magnetomechanical behavior of the MSMA sample which is used in the energy harvester system. Since demagnetization effect, which has a great influence on the model’s outputs, has been neglected in the selected MSMA model, a new approach is presented for inserting demagnetization coefficients, regarding to the... 

In present work, we fabricated novel heterojunction magnetic composite and the goo visible-light-harvesting photocatalysts through integration of ZnFe2O4 and MIL-53 by facile solvothermal method. To understand physical and chemical structure prepared material and morphology of samples, The XRD,FTIR, FESEM, DRS and VSM analysis were carried out. The ZFO/M53Fe/vis-light system reveled 92.3% dye degradation which enhanced photo catalyst reactivity for the decolorization of Direct red 23 as anionic dye under irraditation of LED lamp through AOP environment friendly technology, which are significantly higher than those of pure ZFO and M53Fe semiconductors. more ever ,aforementioned composite... 

This paper presents a scalable and ultrasensitive magnetic biosensing scheme based on on-chip LC resonance frequency-shifting. The sensor transducer gain is demonstrated as being location-dependent on the sensing surface and proportional to the local polarization magnetic field strength |B|2 generated by the sensing inductor. To improve the gain uniformity, a periodic coil is proposed as a substitution for the standard process coil. As an implementation example, the circuit is designed in a 65nm CMOS process. The spatially uniform sensor gain of the array is verified by COMSOL simulations. Overall, the presented sensor demonstrates an improvement in the uniformity of the inductor’s magnetic... 

In this study, the substituted barium hexaferrite nanoparticles with general formula Ba1-xCexFe12-xCoxO19 (x = 0, 0.1, 0.2 and 0.3) were prepared by the sol-gel auto combustion method. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), Mossbauer spectroscopy (MS), vibrating sample magnetometer (VSM) and performing network analyzer (PNA) were employed to investigation of structural, magnetic, dielectric and microwave properties of barium hexaferrite nanoparticles. Moreover, differential scanning calorimetry (DSC) were performed to observe the formation mechanism of barium hexaferrite. DSC studies showed that barium... 

Magnetic Resonance Imaging is one of the most advanced medical imaging procedure that noninvasively played in most applications. However, this imaging method is a good resolution, but not in the conventional high speed imaging method, in fact, the main problem is slow. In recent years many studies have been done to accelerate MRI that compressed sensing can be mentioned among them. Such methods, however, have had very good results but MRI systems are very complex. This project investigates the reconstruction of MR images using data from partial non-Cartesian samples aimed at reducing sampling time and also speed up the process of reconstruction of MR images have been studied. In this regard,... 

This research study presents an experimental investigation on forced convection heat transfer of an aqueous ferrofluid flow passing through a circular copper tube in the presence of an alternating magnetic field. The flow passes through the tube under a uniform heat flux and laminar flow conditions. The primary objective was to intensify the particle migration and disturbance of the boundary layer by utilizing the magnetic field effect on the nanoparticles for more heat transfer enhancement. Complicated convection regimes caused by interactions between magnetic nanoparticles under various conditions were studied. The process of heat transfer was examined with different volume concentrations... 

In this work we have studied conformation of ranitidine by dynamic nuclear magnetic resonance spectroscopy (DNMR) in four different solvents: chloroform, acetone, dimethylsulfoxide, and deuteriumoxide. Ranitidine has three tatumeric forms of enamine, nitoic acid, and imine, but its stable structure is enamine. Temperature dependent 1HNMR spectra of ranitidine which reportet at 500MHz were consistent with the following free activation of energies ΔG# (kcal mol-1): chloroform = 16.2; acetone = 15.4; dimethylsulfoxide = 15.1. The experimental results were confirmed by DFT theoretical calculations at the B3LYP/6-311++G (d, p) level of theory. It was also proved that ranitidine has the form of...