Sharif Digital Repository

Fe3O4@SiO2-Ag catalyst was found to be highly active and selective in the N-alkylation of amines with a variety of aromatic and linear alcohols. The heterogeneous nature of the Fe3O4@SiO2-Ag catalyst allows easy recovery and regeneration by applying an external magnet for six subsequent reaction cycles. The prepared catalyst was characterized using electron microscopy techniques, X-ray diffraction, vibrating sample magnetometry and atomic absorption spectroscopy. Copyright © 2017 John Wiley & Sons, Ltd  

Metal Organic Frameworks (MOFs) have received enormous attention in catalysis field due to their special structures and various promising applications. One of the intriguing applications of MOFs is utilization of them as precursors for synthesis of metal oxide nanomaterials. Base on this strategy, in this work, we have applied Cu-MOF to prepare a series of noble metal nanoparticles (Ag and Au) decorated CuO (M/CuO) as efficient catalyst. As-prepared nanocomposites were characterized by various analytical techniques and their catalytic performances appraised by using of the catalytic reduction of p-nitrophenol to p-aminophenol as a reliable model reaction. Experimental results suggest that... 

This paper describes a simple and low-cost test strip for on-site monitoring of methiocarb insecticide. Hydrophilic filter paper soaked in agarose solution was bounded by hydrophobic solid wax and then was coated with unmodified gold nanoparticles (AuNPs). AuNPs aggregation caused by methiocarb served as colorimetric response. We demonstrated detection capability of methiocarb both in solution- and substrate-based sensor. A good linear relationship was obtained between the colorimetric response and the concentration of methiocarb ranging from 20 to 80 ng mL -1 with a limit of detection of 5 ng mL -1. Excellent selectivity toward methiocarb was observed among various pesticides and cationic... 

Phonon detector can be designed by using colloidal silver nanoparticle (Ag NP) in presence of 1-Ethyl-3-methylimidazolium Hexafluorophosphate [EMim][PF6] ionic liquid (IL) via computational technique as the first time for many and high performance biosensors applications. Density functional theory as a quantum chemistry calculation method has been used to get the potential interaction between silver metal and ionic solvent. Molecular dynamics simulation shows that in small sizes of colloidal Ag NP in [EMim][PF6], electrical effect of IL makes one main phonon peak and in big size of colloidal Ag NP, splitting of phonon density occurs with two peaks due to the lower electrical field of IL with... 

Nickel nanoparticles supported on MgO-Al2O3 and Al2O3 were synthesized by an impregnation method using dinitrobisethylenediamine nickel and nickel nitrate hexahydrate as precursors and were used as catalysts for CO methanation. Different MgO contents (1.5-11.25 wt %) were employed for the preparation of supports, and NiO loadings were in the range of 10-40 wt %. The optimum catalyst prepared from proper amounts of MgO (∼2 wt %) and NiO loading (20 wt %) with [Ni(en)2(H2O)2](NO3)2 as precursor and a mesoporous support with a wide range of mesopores resulted in highly dispersed nickel nanoparticles that exhibited moderate metal-support interactions, lower acidic surface sites, and enhanced... 

In this work, we compared formation and properties of heat-treated Ag nanoparticles in silica matrix synthesized by RF- reactive magnetron cosputtering and sol-gel methods separately. The sol-gel and sputtered films were annealed at different temperatures in air and in a reduced environment, respectively. The optical UV-visible Spectrophotometry have shown that the absorption peak appears at 456 and 400 nm wavelength indicating formation of silver nanoparticles in SiO2 matrix for both the sol -gel and sputtering methods at 100 and 800 °C, respectively. XPS measurements showed that the metallic Ag0 nanoparticles can be obtained from both the techniques at these temperatures. According to XPS... 

Gold-silver alloy nanoparticles with various Au concentrations in sputtered SiO2 thin films were synthesized by using RF reactive magnetron co-sputtering and then heat-treated in reducing Ar + H2 atmosphere at different temperatures. The UV-visible absorption spectra of the bimetallic systems confirmed the formation of alloy nanoparticles. The optical absorption of the Au-Ag alloy nanoparticles exhibited only one plasmon resonance absorption peak located at 450 nm between the absorption bands of pure Au and Ag nanoparticles at 400 and 520 nm, respectively, for the thin films annealed at 800 °C. The maximum absorption wavelength of the surface plasmon band showed a red shift with increasing... 

Nanomanipulation as a new emerging area enables precise manipulation, interaction and control at the nanoscale. Currently, the modeling schemes are based on continuum mechanics approaches. A main consideration in the nanomanipulation process is the fact that surface attraction forces are greater than gravitational forces at the nanoscale. In other words, surface area properties dominate volume properties. Especially at the nanoscale (i.e. the manipulation of fine nanoparticles with size of about 5 nm) the physical phenomena have not been completely understood. Along this line of reasoning, the aim of this paper is to conduct an atomistic investigation of physical interaction analysis of... 

Photodegradation of Escherichia coli bacteria in presence of Ag-TiO2/Ag/a-TiO2 nanocomposite film with an effective storage of silver nanoparticles was investigated in the visible and the solar light irradiations. The nanocomposite film was synthesized by sol-gel deposition of 30 nm Ag-TiO2 layer on ∼200 nm anatase(a-)TiO2 film previously doped by silver nanoparticles. Both Ag/a-TiO2 and Ag-TiO2/Ag/a-TiO2 films were transparent with a SPR absorption band at 412 nm. Depth profile X-ray photoelectron spectroscopy showed metallic silver nanoparticles with diameter of 30 nm and fcc crystalline structure were self-accumulated on the film surface at depth of 5 nm of the TiO2 layer and also at the... 

As the use of superparamagnetic iron oxide nanoparticles (SPION) in biomedical applications increases (e.g. for targeting drug delivery and imaging), patients are likely to be exposed to products containing SPION. Despite their high biomedical importance, toxicity data for SPION are limited to date. The aim of this study is to investigate the cytotoxicity of SPION and its ability to change cell medium components. Bare and poly(ethylene glycol)-co-fumarate (PEGF)-coated SPION with narrow size distributions were synthesized. The particles were prepared by co-precipitation using ferric and ferrous salts with a molar Fe3+/Fe2+ ratio of 2. Dulbecco's modified Eagle's medium (DMEM) and primary... 

ZnO nanoparticles were fabricated via hydrothermal method and an amorphous TiO2 layer was then coated on the nanoparticles via sol-gel route. X-ray diffraction (XRD) and transmission electron microscopy (TEM) studies showed that the synthesized ZnO nanoparticles were hexagonal with wurtzite structure and an average particle size of 38 nm. The thickness of the titanium oxide layer was determined to be 20-40 nm. The photocatalytic decolorization of Methylene blue under UV irradiation indicated that as-prepared TiO 2-capped ZnO is inferior than ZnO particles. Nevertheless, calcinations of the particles at 350 °C for 24 h significantly improved the photo-activity of the ZnO/TiO2 core/shell... 

The aim of this research is to conduct atomistic investigations of physical interaction analysis of nanoscale objects manipulation. The system consists of tip, particle and substrate. The manipulation tool moves with a constant speed while pushing the particle in a desired direction. The focus of the research is on ultra-fine metallic nanoparticles. To perform this research, Nose-Hoover dynamics and Sutton-Chen interatomic potential will be used to investigate the behavior of the aforementioned system which is made from different transition metals. The effects of size, material type and temperature on the success of the process have been investigated by planar molecular dynamics. © 2008 IEEE... 

An indirect colorimetric method is presented for detection of trace amounts of hydroquinone (1), catechol (2) and pyrogallol (3). The reduction of AuCl4- to Gold nanoparticles (Au-NPs) by these phenolic compounds in the presence of cetyltrimethylammonium chloride (CTAC) produced very intense surface plasmon resonance peak of Au-NPs. The plasmon absorbance of Au-NPs allows the quantitative colorimetric detection of the phenolic compounds. The calibration curves derived from the changes in absorbance at λ = 568 nm were linear with concentration of hydroquinone, catechol and pyrogallol in the range of 7.0 × 10-7 to 1.0 × 10-4M, 6.0 × 10-6 to 2.0 × 10-4 M and 6.0 × 10-7 to 1.0 × 10-4 M,...