Sharif Digital Repository

The goal of this project was study on coordination behavior of the 14-membered macrocyclic ligand of type N2O2 aza-crown while it is attached to fullerene C60 nano-particle. For this purpose, firstly the macrocyclic ligand (Fig 3-1, L1) was synthesized and then was reacted with C60 (Fig 3-1, L2) of which the product was characterized by elemental analysis. Since the product was insoluble in any solvents, further study on its coordination chemistry was impossible. In a second procedure, the macrocyclic ligand was reacted with benzylbromide. The reaction mixture gave two macrocyclic ligands with different number of benzylic pendant groups (Fig 3-1, L3-L4). The products were separated by column... 

A complte set of characteristic parameters of the sandpile models is still unknown. We have studied the existence of ”weak chaos” critical exponent in different sandpile models and we have shown that it is a characteristic exponent of deterministic models. We have shown that BTW and Zhang models do not belong to the same universality class (contrary to Zhang’s previous conjecture and contrary to Ben-Hur & Biham’s results.) Also we have shown that directed models, specificly Ramaswamy-Dhar’s directed model form a different universality class. ”Weak chaos” exponent in also studied in massive models and we have shown that by increase of dissipation, the exponent decreases rapidly to an... 

Purified RIPI–CNT was used as support material for the preparation of cobalt FTS catalysts. Carbon nanotubes supported catalysts (S1–S4) were prepared with loadings of 15, 20, 30 and 40 wt.%. The FT synthesis was carried out in a fixed-bed micro reactor. Deactivation factors of cobalt catalysts supported on carbon nanotubes in FT synthesis is investigated. Using carbon nanotubes as cobalt catalyst support was found to cause the reduction temperature of cobalt oxide species to shift to lower temperatures. The strong metal-support interactions are reduced to a large extent and the reducibility of the catalysts improved significantly. Then, the main reason for the catalyst deactivation will be... 

Signal Coordination is one of the appropriate methods for delay reduction in intersections. Static Traffic Assignment is unable to reflect the impacts of Signal Coordination in a network. One proper way to overcome this difficulty is to use Dynamic Traffic Assignment (DTA) that can model complex properties of traffic flow. This thesis presents a method to apply Signal Coordination in Cell Transmission Model. Neguin network is tested for different intersection's green start times. The results show that Signal Coordination has great influence on total travel time and route choice in this network. Finally, the results have been checked with AIMSUN NG, a microsimulator software.

 

The measure of success in a company is determined by a high performing workforce that demonstrates the competencies necessary to drive the business success, while meeting the organization's strategic goals. This is where competency-based human resource management becomes important. The main factor contributing to the above noted area is the identification of core competencies. There has been a lot of research in this area during the past few years. Each research demonstrates an approach for the development of critical human resource competency models in an organization. In order to determine the foregoing competency model, the early studies in this area have been focused on the distinction... 

Processor cores in embedded applications is one the of important part of System-on-Chip designs. Among the most successful (Reduced Instruction Set Computer) RISC cores are the (Million Instruction Per Second) MIPS processors used in applications such as DVD, automotive, broadband access, networking, etc. In this work we have designed and verified Transaction Level Modeling (TLM) architecture of the MIPS in SystemC TLM2.0. The TLM in SystemC is adopted so that abstract data types can be used for higher (abstract) level modeling and faster simulation design. We implemented the processor such that the instruction and data caches contain all the necessary instructions and data to eliminate... 

Dependence on fossil fuels as the main energy sources has led to serious energy crisis and environmental problems, i.e. fossil fuel depletion and pollutant emission. Compared with fossil fuel, biomass is a clean energy with zero CO2 emission, because CO2 is fixed by photosynthesis during biomass growth and released again during utilization. Due to its low energy density, direct use of biomass is not convenient. Thus, it is necessary to convert biomass to fuel gas, such as hydrogen, which can be used cleanly and highly efficiently. One of the promising hydrogen production approaches is conversion from biomass, which is abundant, clean and renewable. Alternative thermo-chemical and biological... 

In steel structured buildings the connection of columns to foundations is of practical significance. This connection customarily is performed by a base plate, which is connected to the foundation with bolts. The columns and base plates are usually prepared separately, and later are welded together by contractors. Due to the errors in the process of fabrication, these plates are proposed with larger dimensions than those suggested by the designers. However, it is believed that the utilization of stiffeners, which are welded to the columns in a perpendicular state, reduces the stress field inside the base plates significantly. Therefore, by use of stiffeners the thickness of base plates can be... 

One of the important problems in fulfilling the consumers' power demand that has been especially intensified after restructuring is transmission line congestion. To solve this problem, either new transmission lines should be constructed or the existing transmission lines should be better utilized. Construction of new transmission lines is both expensive and time consuming. Therefore, it is usually better to enhance the utilization of the existing transmission assets. FACTS devices have been introduced over the past decades to enhance power systems operation. However, wide scale deployment of them has not occurred yet due to their high initial investment cost and some other problems. In order... 

Epilepsy is one of the most significant neurological disorders that about one percent of people suffer from it. Epilepsy can only be controlled, and so far no cure for it has been provided. Despite the many advances in the treatment of diseases, for a quarter of patients there is no medical treatment solution for controlling epileptic seizures. In the studies of medical groups on the epilepsy, one approach is employment of some models for each type of epilepsy. These types may be created in the animals to allow studying of the mechanism of epilepsy and also finding drugs of treatment or controlling seizures for each type of epilepsy. There is a type of epilepsy that is called absence... 

In many structures, crack creation is one of the most significant fracture mechanisms. To predict these fracture mechanisms accurate numerical modeling is necssary. Finite Element Method (FEM) is one of the substantial methods in analysis of numerical fracture problems in recent past decades. But, this method has difficulties in remeshing of elements in each step of calculation in fracture mechanics or large deformation analysis. Therefore, the theory was defined that, without using elements, just with setting of characteristics nodes in geometry of problem, the differential equations can be solved. These methods are called Meshfree or Meshless methods. RKPM is a new meshfree method for... 

The objective of this project is to study the behaviour and performance of an innotative floating offshore platform. Such Platform not only can be used for exploring oil from offshore fields, but for creating artificial islands, where land is in short supply. Due to its specific and, at the same time, simple geometry (symmetric), its fabrication does ont involve much complexity. Studies carried out on this platform include the investigation into its structural behaviour under gravitational (including self weight) and bouyancy forces. Studied cases include a number of platforms with different (geometrical) sizes and under 3 various bouyancy conditions (percentage), namely 1) 50% of the height... 

This research focuses on the dynamic analysis of an exoskeletal system to assist a paraplegic motion. Research in powered human exoskeletons began in the late 1960s, almost in parallel between the numbers of research groups for different applications. The main challenges for the recent work in exoskeletons were focused on the design and demonstration of an initial prototype. To this point, the reported advantages of the autonomous exoskeleton systems are largely anecdotal. Indeed, there is a marked lack of published quantitative performance results for exoskeleton devices that reportedly improve human locomotion. Considering this, there are many design challenges remained that may lead to... 

Software development process is a base ground for all software activities and ensures all aspects of the software. No quality is guaranteed without a definite process. Model-Driven Software Development process proposes an industrial method for software companies to produce the required software through model(s) and tools. On the other hand, Software Product Line imposes a set of frameworks and principles. As a result a tangible decrement of development time and cost along with an increment of quality is achieved. Mixing both processes creates a stronger industrial process in order to decrease the development time and cost. In this thesis, through a survey on both of the processes and related... 

Recently in civil engineering prestressed concrete slab applications is increasing, and typically results in overall economy and provides satisfactory structural performance. In The present work, two-way prestressed concrete slabs have been considered and during designing process with the ACI-2005 code and due to economic plan, prestressed slabs were studied in transfer, service and final conditions. ACI code insists that two-way prestressed slabs shall be classified as class U (without cracking) that means section must be untracked in all conditions (code reference 18.3.3). In addition, two-way prestressed slabs must be prestressed in both directions for 100% of load, and this means that... 

The main objective of this project is to take the first steps in designing power plants governor in Iran. In this work, we obtain a realistic model of a hydro-power plant including hydraulic characteristics from the dam to the outlet tail water, mechanically including: the turbine, the gates and all mechanical and dynamic parts, and electrically including generators, transformers and the consumption network. The model is used to simulate different working modes of turbine operation. The Bond Graph method is used for deriving the system equations and MATLAB software for simulations. A conceptual design of the governor is done and the governor model is combined with the turbine model. Using... 

This study presents a modified Microplane model in two-dimensional space which is capable of modeling anisotropic materials accurately. The main idea of Microplane model is to write constitutive equations in terms of vectors rather than tensors. Material constitutive laws are written for planes of every possible orientation to calculate the response of each plane to a given loading. Then the results of all the planes, called microplanes, are added up using Principle of Virtual Work (PVW) to form together the macroscopic response of the material. Microplane model with kinematic constraint is used in this study. Kinematic constraint states that microscopic (local) strain vector acting on each... 

Considering high potential of solar energy and exhaustibility of fossil fuels in Iran, using solar energy seems to be inevitable. But one of the main problems in the application of these systems is high investment and maintenance costs. So, in this thesis, suitable solution is presented for decreasing cost and optimizing of a solar absorption refrigerator based on developed energy model. This system consists of two CPC solar collectors and a thermal energy storage system using phase change materials that provides input energy to the generator of absorption refrigerator. The exergy efficiency of system components is calculated by relations of energy model and exergy analysis. Then... 

This paper provides and empirical investigation of individual labor supply of Iranian spouses in a collective framework in which gender ratio and plays a central role in the decision process in household. The data set is taken from the socioeconomic characteristics of panel survey over 2001-2004 and ten yearly headcount of Iran. We have conducted the parameters estimation and hypothesis testing by Semykina, A. and Wooldridge, J.M., (2005) generalized procedure of sample selection in panel data model. Our findings explore that females’ labor supply is affected significantly and strongly by the gender ratio, (total number of males over the females in provinces, both in urban and rural areas).... 

The aim of this research was an investigation, development, and application of low- dimensional proper orthogonal decomposition (POD) method for simulation of unsteady flow around bodies. Since analytical methods have low accuracy and limitations and also experimental methods have other problems, researchers usually use computational approaches, which mostly do not have acceptable efficiency and speeds of computations (especially in 3-D unsteady flows). On the other hand, the idea of application of reduced order modelling, which orginally comes from control theories and structural analysis, have attracted many researchers in recent years. In this research, we also used POD for reduced order...