Sharif Digital Repository

Acidizing of carbonate oil-wet rocks saturated with oil and saline formation water is subjected failure in some cases due to acid-induced damage such as sludge and emulsion formations. This condition may also lead to mineral precipitation, oil film barrier between acid and rock and diversion chemical malfunctions. Therefore, pre-flush process has been proposed as one of the most efficient stage for oil-wells matrix acidizing to reduce these challenges significantly. Besides, the pre-flush stage would result in more clean rock as the reservoir fluids are pushed back from the near wellbore regions, restoring rock wettability to more water wet state, preventing direct acid-oil contact and... 

The main issue in heavy oils enhanced recovery methods is to reduce their viscosity in order to get a better mobility. This is commonly obtained by blending the oil with light hydrocarbons. Co-solvents are good candidates to improve the hydrocarbon recovery efficiency especially in miscible processes. However, the effect of co-solvents on miscible flooding of heavy oil reservoirs at different pore geometries is not well understood. In this work different one-quarter five-spot network patterns along with those generated from reservoir rocks' thin sections were etches on glass surfaces. The models that had been initially saturated with the heavy crude oil were used to perform a series of... 

A Green Element numerical formulation is used to solve the time-dependent nonlinear one-dimensional counter-current spontaneous imbibition diffusion equation in which water enters a water wet rock spontaneously while oil escapes by flowing in the opposite direction. The Green Element Method (GEM) is an element by element approach of the boundary element method. In this new method, by generating large sparse global matrices and yet taking advantage of properties of Green's function, solution of more complicated physical problem is achievable while at the same time much less computational effort is needed rather than boundary element method (BEM). By discretizing both the boundary and problem... 

Simulation of the in-situ combustion process is one of the most complex simulations amongst other reservoir flow simulations. Accurate simulation of the process is critical to obtain a successful implementation of the in-situ combustion process. Several factors impact performance of the simulation of this process. First are all the numerical models used for different sub-processes, such as reactions, fluid phase behavior, heat loss to surrounding formations and fluid physical properties. In the previous numerical models of the in-situ combustion process, very simplified models were used for the phase behavior of the fluid. Recent studies show that the fluid phase behavior model has a great... 

Most of the heavy oil reservoirs contain discontinuous shale which affects fluid flow through porous media as well as recovery efficiency during enhanced oil recovery processes. However, the role of shale geometrical characteristics (including orientation, length, discontinuity, and spacing of the shale) on oil recovery remains a topic of debate in the literature, especially during miscible injection of heavy oils and five-spot systems. Here, a series of hydrocarbon solvent injection tests have been performed on various five-spot glass micromodels containing barriers which are initially saturated with heavy oil under fixed flow rate conditions. Oil recoveries as a function of pore volumes of... 

Interaction between rock-fluid and fluid-fluid can have a significant effect on oil recovery. Changing the wettability of reservoir rock toward more water-wet or less oil-wet state is one of the expected mechanisms during low salinity water injection (LSWI). pH and salinity are of the most eminent factors of injection water controlling the wettability state of a crude oil/brine/rock system during any waterflooding operation. A small change in pH can affect the surface charges at the rock/water and oil/water interfaces leading to wettability alteration in a porous medium. In this study, the synergic effect of salinity and pH on the wettability state of carbonate rocks is evaluated through... 

In this work effect of composition changes of injection gas, CH4 + CO2, on the performance of immiscible WAG injection in light oil, 41 oAPI, which has been rarely attended in the available literature is investigated. Presence of CO2 helps to reduce the MMP of CH4 significantly. Core flood experiments are conducted at reservoir conditions and fixed flow rate of 0.5cc/min on a sandstone sample with the brine concentration of 5000 ppm, and the influence of injection gas composition as well as WAG ratio on oil recovery is investigated. Different mole percents of methane in mixture, 0%, to 100% are examined, and the tests continued to ten alternate cycles with a slug size of 0.1 pore volumes and... 

This paper studies a WAG process for improving the recovery efficiency in light oil reservoirs. Until now, few references have reported the role of CO2 mole percent on recovery improvement in light oil reservoirs. The injected gas was changed, and the effect of composition changes on performance of core flood experiments were conducted at fixed flow rate. Five series of experiments (varied in methane mole percentages, 0, 25, 50, and 75, 100) were systematically examined. The results indicated that the oil recovery efficiency improved with the increasing of CO2 mole ratio and there was also maximum recovery efficiency in this work. That would be helpful to better understanding the role of CO2... 

This study aims to investigate the role of fluid-fluid interactions during low salinity water flooding, using crude oil from an Iranian oil reservoir. To minimize the effects of mineral heterogeneity and wettability alteration, a synthetic sintered glass core was utilized and all coreflooding experiments were performed at low temperatures without any aging process. The effect of fluid-fluid interactions were investigated in both secondary and tertiary injection modes. pH measurements as well as UV-Vis spectroscopy and interfacial tension (IFT) analysis were performed on the effluent brine samples. Results: show that fluid-fluid interactions, mainly the dissolution of crude oil polar... 

The amount of residual oil trapped in the matrix of a fractured reservoir after water drive, either natural water drive or water injection, depends on the wettability of the matrix rocks. Gas oil gravity drainage (GOGD) has been proposed as the tertiary oil recovery process for this type of oil reservoir. The current work focuses on experimental investigation of tertiary GOGD in fractured porous media under different types of matrix wettability. Results of a set of experiments performed in artificial porous media composed of sand packs and glass beads of different wettability have been used to check the GOGD rate and the ultimate oil recovery for previously waterflooded models. A novel... 

Spontaneous water imbibition into the matrix blocks is known as the main mechanism for increased oil recovery from naturally fractured oil reservoirs. The rate of oil recovery and its ultimate value is mostly affected by wettability of the rocks and their pore structure. Oil viscosity also greatly influences the rate of oil recovery. A novel experimental model was utilized to study the imbibition mechanism under different wettability conditions. Matrix blocks made from different grain types and size distributions of glass beads were saturated with two different types of synthetic oil, to mimic the oil-saturated matrixes. The wetting characteristic of the models used in this study were... 

This work concerns with experimental investigation of CO2 WAG injection to light crude oil in near miscible conditions which has been rarely attended in the available literature. Here, several core flood experiments at three constant injection rates and four WAG ratios are conducted on sandstone rocks saturated with light crude oil in presence of saline water. The results showed that higher injection rate has a better performance regarding oil recovery for smaller PVs of injected fluids, while lower injection rate showed higher ultimate recovery for a 30% increase in injected PVs. Secondary continuous gas injection showed a superior performance than all the other WAG injections in different... 

Although alkaline-surfactant-polymer flooding is proved to be efficient for oil recovery from heavy oil reservoirs, the displacements mechanism/efficiency of this process in fractured systems needs to more discussion, especially in five-spot patterns. In this work, several ASP flooding test were performed on fractured micromodels which were initially saturated with heavy oil at constant flow rate and different fracture geometrical characteristics conditions. The ASP solutions are constituted from 5 polymers i.e. four synthetic polymers include three hydrolyzed polyacrylamide with different molecular weight as well as a non-hydrolyzed polyacrylamide and a biopolymer, 2 surfactants i.e. a... 

In fractured reservoirs, a large variation of permeability due to the presence of fractures leads to changes in the production mechanism compared to conventional reservoirs. Hence, an appropriate model with the ability to describe the reservoir properly can provide a more confident prediction of its future performance. One of the features of a representative model is the number and height of the matrix blocks. The determination of these two parameters is one of the decisive steps in the calculation of an accurate amount of oil production from these reservoirs. In fact, matrix height shows its effect as a gravity force, which is one of the driving mechanisms. If the matrix height is less than... 

The low salinity water injection has become one of the most important studies in the oil industry for improving oil recovery compared to conventional seawater injection. Thus, extensive studies have been conducted in carbonate and sandstone reservoirs to investigate how the physical properties of rocks and the chemical composition of fluids influence low salinity effect, while, the carbonate reservoir rocks requires more investigation of the effect of molecular and/or ionic interactions. In this experimental work, the effectiveness of various water flooding schemes in carbonate reservoir rock samples is investigated. In this regard, the oil recovery potential of seawater (SW), reservoir... 

Concerns about climate change have persuaded the researchers to examine CO2 injection in the form of carbonated water (CW) into oil reservoir as a safe and effective CO2 storage and enhanced oil recovery process. Although interfacial tension (IFT) between crude oil and injected fluid has a vital role on the displacement of fluids in porous media, the effect of CO2 and crude oil type on the dynamic IFT of crude oil under different operational conditions is not well understood. Accordingly, this study was carried out to assess the effects of temperature, pressure, crude oil type and CO2 on the dynamic IFT of crude oil/CW. To achieve this goal, two types of crude oil were provided from southern... 

During the low salinity waterflooding (LSWF) of a viscous asphaltic oil reservoir, fluid-fluid interactions have a large influence on the fluid flow, pore-scale events, and thus oil recovery efficiency and behavior. In-situ water-in-oil (W/O) emulsion formation is a consequence of crude oil and brine interfacial activities. Despite the published studies, the pore-scale mechanisms of W/O emulsion formation and the role of injected brine salinity, injection rate, and pore-scale heterogeneity on emulsion formation and stability requires a deeper understanding. To address these, a series of static and dynamic micro-scale experiments were performed. The salinity dependent oil-brine interactions... 

The concern over fossil energy shortage for the next decade leads to the extensive research activities in the area of enhanced oil recovery. Steam injection as one of well known EOR process has been used for about five decades to improve the oil production rate and recovery efficiency. Steam flooding is applied to heavy and extra-heavy oil reservoirs; however it could be used in light oil reservoirs in which water injection do not work effectively. Regardless of different performances, this method is an efficient EOR process for both heavy and light oil reservoirs. In this work, two separate numerical models were prepared to investigate steam flooding performance for the recovery of light... 

Many heavy oil reservoirs contain discontinuous shales which act as barriers or baffles to flow. However, there is a lack of fundamental understanding about how the shale geometrical characteristics affect the reservoir performance, especially during polymer flooding of heavy oils. In this study, a series of polymer injection processes have been performed on five-spot glass micromodels with different shale geometrical characteristics that are initially saturated with the heavy oil. The available geological characteristics from one of the Iranian oilfields were considered for the construction of the flow patterns by using a controlled-laser technology. Oil recoveries as a function of pore... 

In order to understand the potential role of divalent ions involved in smart water, fluid-fluid and rock-fluid interactions are studied through contact angle and interfacial tension (IFT) measurements. Then, the suitable brines in changing contact angle and IFT are brought into measurement with spontaneous imbibition experiments to evaluate the co-impact of fluid-fluid and rock-fluid interactions. The results show the importance of SO42− ions during smart water injection as removing them from the injection water leads to a sharp drop in ultimate oil recovery. Accordingly, when the concentration of SO42− within the injection water increases four times, 10% ultimate oil recovery is recovered....