Sharif Digital Repository

Superalloys have a poor machinability and are often drilled using Electro Discharge Machining (EDM) methods. However EDM is a time-consuming process and has low surface integrity. Ultrasonic Assisted Drilling (UAD) technology is a modern method of drilling such materials. Although this method has very high capabilities, it has not been introduced widely to industry. In this study a special horn is designed and used to apply both rotation and vibration to drill bits. It can transfer power with high efficiency and has the capability to change tools easily. The setup is used to conduct deep drilling tests on Inconel 738LC with depth-to-diameter ratio of 10. The effect of ultrasonic vibration... 

In this study, the essential oil of aerial parts species of a plant called Spearmint was extracted by CO 2 to optimize the results of the supercritical extraction process. In order to achieve maximum total yield extraction and SF-CO 2 concentration, tests were done in a laboratorial pilot considering the Taguchi method under following condition: pressure. 90,100,140,170 bar, temperature. of 35, 40, 45, 50 °C, mean particles size: 250,500,710,1000 μm, flow rate 1,3,5,8 ml/s and dynamic time 30,50,90,120 min. The optimizing conditions for SCE and SF-CO 2 concentration are: 90 bar, 45 °C, 500 μm, 5 ml/s, 120 min and 90 bar, 35 °C, 250 μm, 1 ml/s, 30 min. SCE total yield and CO 2 concentration... 

This study focuses on the mode classification of phones speaker modes using GMM 1. In this regard, speech data in both enabled and disabled speaker modes of cell phones and telephones were collected, processed and classified into two different categories. The different mixture numbers (1 to 4) of GMM and wave files sizes of 10, 20, 40 and 80 kb were tested in order to obtain an optimal condition for classification. The GMM method attained 87.99% correct classification rate on test data. This classification is important for speech enabled IVR 2 systems [1], dialog systems and many systems in speech processing in the sense that it could help to load an optimum model for increasing system... 

Novel high capacity swelling nanoporous hydrogel (NPH) was synthesized via graft copolymerization of acrylamide (AAm) onto kappa-carrageenan (kC, as a polysaccharide) and gelatin (as a protein) hybrid backbone, after hydrolysis of this system. The Taguchi method as a strong experimental design tool was used for its optimized synthesis. The Taguchi method was applied for the experimental and standard 9 orthogonal array (OA) with four factors and three levels for each factor. A series of NPHs were synthesized by proposed conditions of Qualitek-4 Software. Considering the results of 9 trials according to analysis of variance (ANOVA), optimum conditions were proposed. The swelling behavior of... 

Green iron oxide pellets are indurated with thermal treatment in pelletizing plant to achieve sufficient mechanical properties and to be used in iron-steel industry. In the first stage, the pellets are dried with hot air coming from the firing unit. High heat transfer makes the evaporation rate exceeding the outgoing steam rate from the pellets and as a result, increasing the inner pressure of the pellets and fragment. On the other hand, low heat transfer causes low production rate. Using the related equations and considering the pellets' moisture and porosity and applying the pellets' condition on parameters such as specific heat capacity and heat conductivity, an acceptable standard is... 

In this work, a novel and facile synthesis process to fabricate single crystalline organometal halide perovskite nanowires has been successfully developed. Nanowires were grown in a high density ordered array from metal nanoclusters inside anodic aluminum oxide templates using a non-catalytic chemical vapor deposition method. Specifically, perovskite NWs were grown as a result of the reaction between methylammonium iodide (MAI) and the Pb/Sn (Pb or Sn) metal in anodic aluminum oxide templates under optimal conditions. The characterization results show that there is a reaction zone at the interface between the perovskite material and metal, at the bottom of the anodic aluminum oxide... 

This paper presents a new approach for determining the day-ahead bidding strategies of a large-scale hybrid electric energy company. The company has both energy generation and energy retailing businesses in a competitive electricity market. Demand response programs are also considered in the retail side of the company in order to hedge the risk of participation in wholesale market. This paper introduces a max-min bilevel mathematical programming with equilibrium constraint model for offering a strategy that manages the risk of uncertain forecasted rivals' bids by robust optimization. The max-min bilevel model is converted to its equivalent single-level optimization using Karush-Kuhn-Tucker... 

The production of protease by Bacillus licheniformis BBRC 100053 was studied. The most appropriate medium for the growth and protease production is composed of: lactose 1%, yeast extract 0.5%, peptone 0.5%, KH2PO 4 0.1%, MgSO4.7H2O 0.02%. Enzyme production corresponded with growth and reached a maximums level (589 U/ml) during the stationary phase at 35°C, pH equivalent to 10 and with 150 rpm after 73 hours. Protease activity was highest at pH 8 and 45°C. The best carbon sources are respectively lactose and maltose and the best nitrogen source is peptone. The protease was highly active and stable from pH 7.0 to 11.0 with an optimum at pH 7-8.... 

An attempt was made to produce an iron bearing and a titanium bearing product, using solid state reduction of Fanouj mine titanomagnetite concentrate. For this purpose, the concentrate was mixed with pulverised coal and sodium carbonate and was reduced in a muffle furnace. The product was then subjected to magnetic separation. In this work, the effect of temperature, time, added coal and additive amount on reduction was studied. The Separation Efficiency (SE) index was used for optimisation of the process. Using SE is more appropriate than degree of metallization, which is usually used, for optimising reduction processes. The results show that the optimal conditions are 1325°C, 2.5 h, 25... 

The widespread use of pesticides in pest management has boosted the demands for developing highly sensitive probes for on-site monitoring. Herein we presented a sensitive enzyme-free ratiometric probe for determination of methyl parathion (MP), as an organophosphate pesticide using TGA-capped CdTe QDs and carbon dots (CDs). Unlike previous methods in which hydrolysis product of MP is instrumental in the response of the sensors, here, self-assembly of cetyltrimethylammonium bromide (CTAB) on the surface of non-modified yellow-emissive CdTe QDs facilitates the quenching of CTAB-QDs upon addition of MP while the fluorescence intensity of CDs remains constant. Using a smartphone, the ratiometric... 

An attempt was made to produce an iron bearing and a titanium bearing product, using solid state reduction of Fanouj mine titanomagnetite concentrate. For this purpose, the concentrate was mixed with pulverised coal and sodium carbonate and was reduced in a muffle furnace. The product was then subjected to magnetic separation. In this work, the effect of temperature, time, added coal and additive amount on reduction was studied. The Separation Efficiency (SE) index was used for optimisation of the process. Using SE is more appropriate than degree of metallization, which is usually used, for optimising reduction processes. The results show that the optimal conditions are 1325°C, 2.5 h, 25... 

Surface-enhanced Raman spectroscopy is a highly sensitive phenomenon and a powerful fingerprint detection tool that reflects the small changes in polarizability on the pattern and intensity of Raman signals. The SERS enhancement signals elucidate with the surface-selection rules. In this regard, molecular configuration and adsorption orientation on the surface, in addition to the direction of external electric field, can lead to different patterns of SERS spectra. To evaluate how the variation of these features influences the pattern and reproducibility of the spectra, the chemical charge-transfer SERS spectra for pyridine on silver clusters are calculated for different field directions,... 

A glassy carbon electrode (GCE) is modified with platinum nanoparticle (PtNPs) decorated multiwalled carbon nanotube (MWCNT). The modified electrode is applied for the determination of ceftriaxone (CFX) in the presence of lidocaine. Different methods were used to characterize the surface morphology of the modified electrode. The electrochemical behavior of CFX was investigated at GCE, MWCNT/GCE and PtNPs/MWCNT/GCE. A factorial-based response-surface methodology was used to find out the optimum conditions with minimum number of experiments. Under the optimized conditions, oxidation peak currents increased linearly with CFX concentration in the range of 0.01-10.00 μM with a detection limit of... 

An immersed solvent microextraction (SME) method was successfully developed for the trace enrichment of aryloxyphenoxypropionate herbicides from aquatic media. A microdrop of toluene was used as the extraction solvent. Some important extraction parameters such as type of solvent, solvent dropsize, stirring rate, ionic strength and extraction time were investigated and optimized. The microdrop volume of 1.5 μL, a sampling time of 25 min, and use of toluene were major parameters for achieving high enrichment factors. The linearity was studied by preconcentration of 4 mL of the water samples spiked with a standard solution of aryloxyphenoxypropionates at the concentration range of 0.15 to 30 ng... 

A modified carbon paste electrode was prepared by incorporating the TiO2 nanoparticles in the carbon paste matrix. The electrochemical behavior of gallic acid (GA) is investigated on the surface of the electrode using cyclic voltammetry and differential pulse voltammetry. The surface morphology of the prepared electrode was characterized using the scanning electron microscopy. The results indicate that the electrochemical response of GA is improved significantly at the modified electrode compared with the unmodified electrode. Furthermore, the capabilities of electron transfer on these two electrodes were also investigated by electrochemical impedance spectroscopy. Under the optimized... 

Today, tailored welded blank sheets have found various applications in automotive, aeronautic and many other industrial fields. One of the most efficient methods for production of tailored welded blank sheets is application of the friction stir welding process. In the present article, the effect of friction stir welding parameters on the microstructure and mechanical properties of heterogeneous tailored welded blank sheets made from aluminium alloys of types 5083-H12 and 6061-T6 with the similar thickness of 1.5 mm is studied. The considered parameters are rotational speed of the tool, linear speed of the tool, pin diameter and shoulder diameter. In order to come by a tailored welded blank... 

The morphological manipulation, structural characterization, and optical properties of different cadmium selenide (CdSe) nanostructures are reported. Two different CdSe nanostructures, i.e., nanorods and nanoparticles, were grown by controlling the concentration of precursors (i.e., cadmium nitrate and selenium dioxide) in ethanolamine solvent. By manipulating the kinetic parameter of the process (i.e., growth rate) under constant growth driving force (i.e., degree of supersaturation), the morphology of CdSe nanostructures can be tailored from nanorods to nanoparticles. The optical properties of CdSe nanostructures were investigated using ultraviolet-visible (UV-vis) spectroscopy. The... 

The morphological manipulation, structural characterization, and optical properties of different CdSe nanocrystals were reported. Several different CdSe nanostructures, including nanowires, tetrapod crystals, and nanoparticles were grown by varying the volume ratio of triethylenetetraamine (TETA) and water (WA) in their mixed solution. By manipulating the growth driving force (i.e., the degree of supersaturation) and kinetics of the process (i.e., growth rate), the morphology and crystal structure of CdSe nanocrystals can be tailored. Growth driving force changed their morphology from nanowires to tetrapod structures and from the latter structure to nanoparticles. Moreover, kinetics of the...