Sharif Digital Repository

In this study, In order to reduce volatile organic component (benzene, toluene, xylene and ethyl benzene) some appropriate nanostructures were used. First the appropriate nano structures were identified, then modified and optimized and finally characterized by XRD, SEM, ASAP. Appropriate nano adsorbent such as nano active carbon, single wall and multi wall nano carbon tubs , nano fiber carbon, graphene oxide, aluminum oxide particles, nano-zinc oxide , titanium oxide particles, 13x zeolite and extruded nano carbon tubes, were prepared and optimized, than evaluated from perspective of the crystal structure, surface area and porosity. nano active carbon, single wall and multi wall nano carbon... 

Due production and use of large amount of chemical and emissions of pollutants in air, detection and control of these compounds are necessary. One of the common methods to detect these pollutants in the ambient is using metal oxide semiconductor sensors. However, these types of sensors suffer from low selectivity toward a certain compound in the mixture of different gas components. In this study, the object was to investigate the effect of different amount of CNTs on performance of tin oxide to improve their selectivity for detection of 50 ppm of hydrogen sulfide at low temperature. To perform the study, nanoparticles of pure tin oxide and SnO2 base hybrids containing 0.25wt%, 0.5wt%, 2.5wt%... 

After proteins, one of the important biological macromolecules, are synthesized by ribosomes,they automatically reach their own special 3-D structure. This native structur or better known as folded state is what determines the function of a protein. In some situations, the proteins become misfolded leading to its lack of biological function through aggregation or fibril formation known as "amyloid". The amyloid fibrils have been shown to be a causative factor in nerve decay such as Alzheimer's. Therefore, inhibition of amyloid formation using different approaches such as synthetic organic and natural compounds has, recently, been under spotlight. A pyridazine basedcompound (RS-0406) has... 

At the molecular level, proteins control almost all the biochemical reactions in the cells. In order for proteins to function, they must be able to fold into their unique 3D structure. Deformation of protein structure due to some environmental phenomena such as pH, high temperature, and stress may cause unfolding of proteins and finally result in formation of protein fibrils called "amyloid". Amyloid has been found in a number of human diseases such as Alzheimer, type II diabetes, and Parkinson. Recently pyridazine has been under spotlight due to its unique chemical properties such as high dipole moment and higher solubility in biological solvents. In this study, we aim at using a... 

Combustion sources such as diesel vehicles are the most of the particular matter sources in ambient air. Near the tailpipe, exhaust is very hot, condense and have high velocity. This properties cause to need special methods and instrument to collect them. Numerously of combustion sources will emitted the VOCs, IVOCs, and SVOCs. This component mixed with ambient air and changing to particle phase from gas phase. Reaction between nitrogen oxides with sunlight cause to damage ozone layer and tissue in long time. Furthermore, breathe of VOCs gases cause to eye irritation, gastrointestinal effects, Damage to the nervous system, headache, dizziness, fatigue, vibration and loss of organ... 

In recent years, one of the most important air pollution in Tehran in terms of creating unhealthy air quality is particulate matter and especially PM2.5. Particulate matter in Tehran is released from various sources. Identification of components and estimating the contribution of each emission sources, helps governers to find air pollution control strategies. To find out major components of PM2.5 in Tehran, a one year sampling to collect PM2.5 was conducted from February 2014 through February 2015 in AQM station at Sharif University of Technology located west of Tehran. 24-hour integrated samples collected on a 1-in-6 day schedule on both Teflon and quartz filters. TOT analysis was done for... 

Particulate matter (PM) with aerodynamic diameter less than 2.5 micron (PM2.5) is cause of dangerous diseases, like respiratory and cardiovascular and it is one of the main causes of poor air quality in the city of Tehran. Despite the importance of the issue, there is no complete information on the chemical components of the PM2.5 in Tehran. In this study, 24 samples of particulate matter PM2.5 collected during one year in each 6 days at the station of Air pollution monitoring station related to Air Quality Control Company (AQCC) at the Sharif University of Technology. Chemical analysis was performed on samples to determine the composition of particulate matter include organic carbon,... 

In this work, a new catalyst based on gold nanoparticles immobilized on magnetic GO (graphene oxide) has been introduced. A new ligand based on pyridine has been used to the functionalization of GO to design robust heterogeneous catalyst for reduction in a short time using a low amount of the catalyst. The prepared catalyst was employed in the synthesis of aromatic amines using various types of nitroarnes in water. This catalyst is readily prepared from available starting materials and also is a reusable catalyst having very good stability to air and moisture. The proposed procedure applied here can conduct the reactions under milder reactions. Finally, due to total removal of the... 

Focus of the present research is on the study and cognition of sources of carbonaceous compounds present in PM2.5, particularly secondary organic carbon. For this purpose, two different approaches were used. The first approach investigates the SOA formation from internal combustion engines exhaust and unburned fuel (bottom-up approach). The second approach studies the contribution of each of the primary and secondary sources to PM2.5 mass, whereby secondary organic carbon share is obtained (top-down approach). Modeling SOA formation from vehicles exhaust showed that diesel vehicles have greater SOA formation potential than gasoline vehicles, due to large amount of S/IVOCs present in their...