Sharif Digital Repository

Energy and the environment issues are among the most important concerns of the present age. Global demand for energy is growing rapidly and energy demand is projected to double within the next 15 years. However, today most of the energy consumption comes from fossil fuels, which have limited and unstable reserves and are among the sources of environmental pollution. Hence, the production and conversion of clean energy from renewable sources is considered as an intelligent solution to significantly reduce dependence on fossil fuels and protect the environment. Fuel cells, metal-air batteries, and water electrolysis are among the simplest, most efficient, and most reliable technologies among... 

Membrane bioreactors can replace the activated sludge process and the final clarification step in municipal wastewater treatment. The combination of bioreactor and crossflow microfiltration allows for a high chemical oxygen demand (COD) reduction of synthetic wastewater. In this study, experimental data from a laboratory scale membrane bioreactor are presented. In order to investigate the influence of various operating parameters such as hydraulic retention time (HRT), biomass concentration and organic loading rate on organic pollutant removal, the pilot scale submerged membrane bioreactor (SMBR) with a Polyvinylidene Fluoride (PVDF) hollow fiber membrane module was conducted using synthetic... 

Wetlands are valuable ecosystems that have a wide variety of functions to protect biodiversity, natural, economic and social values. Hydrological changes and nutrient enrichment, resulting from population growth, economic development and climate change are threatening the wetlands. Recently, assessing spatial and temporal variations of water quality has become an important aspect of the physical and chemical characterization of aquatic environments. Anzali wetland is one of the international wetlands in Iran, located in the southern part of the Caspian Sea in Gilan province. This wetland has been exposed to many pollution sources including agricultural, industrial, and municipal wastewater... 

We present a systematic study of the composition, electronic structure, and the band gap energy in pure, Cu-doped and O-vacancy@Cu-doped TiO2 using periodic density functional theory (DFT) calculations by several techniques implemented by Abinit code. Herein, the effect of Cu impurity and O-vacancy in three famous crystalline structures of TiO2 i.e. rutile, anatase and brookite, with 6.25% and 12.5% of Cu impurity were investigated. Bulk titania was modeled using 2×2×1, 2×1×1 and 1×1×1 super cells (24 atoms with formula of Ti8O16) and 2×2×2, 2 2×1 and 1×2×1 super cells (48 atoms with formula of Ti16O32) for rutile, anatase and brookite phases, respectively. One Ti atom replaces with Cu atom... 

Drug delivery systems (DDS), which, are sensitive to tumor medium have high importance. one of the most important problem of current treatment of cancer is damage of the normal tissue, which, it is expected to solve by smart drug delivery systems. In such cases, one or more features of cancer medium cause to release of the drug. One of features of cancer medium is high concentration of reactive oxygen species and hydrogen peroxide in the most common between them. The purpose of this study is to build a drug delivery system, which it is sensitive to hydrogen peroxide. This carrier has 4 main parts. The first part is anti-cancer drug, which, it is located in the carrier. Second part is... 

The study on the propane dehydrogenation process has been receiving significant attention due to the growing demand for propylene. The aim of this research is to develop an appropriate kinetic mechanism for dehydrogenation of propane over an industrial Pt–Sn/γ-Al2O3 catalyst in the presence of a very small amount of water. The reaction is carried out over the temperature range of 575 – 620 º C at atmospheric pressure. The results showed that a small amount of water and methanol can improve the performance of catalyst and also, increase the selectivity to COx. Addition the 0.5, 0.45, 0.3 water and 0.1, 0.05, 0.02 methanol are the optimum amount of these oxygenated compounds in order at... 

Today, due to the decreasing of fossil fuel reserves and the need to use clean fuels, hydrogen is a suitable alternative, and hydrogen production has received considerable attention. One of the best methods of hydrogen production is water splitting. Overall water splitting can be divided into two half reactions including the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), which selecting the appropriate electrocatalyst for these half reactions plays an important role. The four-electron transfer process in OER leads to slow kinetics of the reaction and a large overpotential. The noble metal-based oxides, including IrO2 and RuO2, are known as outstanding OER... 

Today cancer is one of the leading causes of death worldwide. It is caused by some cells that they gather together in part of the body and they have an abnormal and very high proliferation rate. Investigations on tumors have shown that when tumor volume increases, oxygen concentration in some regions of tumors decreases and this hypoxic condition leads to some cancer hallmarks, e.g. angiogenesis, deregulation of apoptosis, and shift in cell energy sources. So treatment strategies that can increase tissue oxygenation are good choices for cancers. Hyperbaric oxygen therapy (HBOT) which is used to treat diabetic ulcers and carbon monoxide poisoning, have been used experimentally for cancer and... 

In order to improve performance and optimize design of high pressure combustion devices such as liquid rocket engine, gas turbine engine, and diesel engine there is a need for comprehensive understanding of injection, mixing and combustion in supercritical condition. Under this condition chamber pressure is higher than critical pressure of fuel and oxidizer. The characteristic of supercritical condition, include changing thermophysical properties such as density, CP, and compressibility factor. Therefore under this condition ideal state equation cannot correctly predict the mentioned properties. These characteristics make supercritical combustion different from other combustion regimes.... 

In the present study, the electrochemical oxidation process was introduced as a green process for complete degradation and removal of non-biodegradable pollutants from aquatic environments and effluents of various industries without the need to use chemicals and toxins. Research stages include comprehensive preliminary studies in the field of electrochemistry and wastewater treatment, software design of electro-oxidation reactor using titanium mesh anode and stainless steel cathode mesh inside a body made of polypropylene, designed cell construction and then evaluation of device performance in polluting environment Are different. In software simulation using COMSOL MULTIPHYSICS software, it... 

In the present study , operation of a laboratory scale sequencing batch reactor (SBR) was evaluated to treatment of synthetic wastewaters containing ethylene glycol. Studies carried out with a plexiglass bioreactor whith effective volume of 18 lit.Aeration was supplied via two air diffusers that set at the bottom of the reactor. Synthestic wastewater containing ethylene glycol and molasses as carbon source and other nutrient such as diammonium hydrogen phosphate as phosphor source and urea as nitrogen source for biological activities was composed at the laboratory. To optimization of this reactor three parameters – aeration time, chemical oxygen demand and sudden change in arganic loading... 

Core-shell structures of Ag@Pt nanoparticles (NPs) dispersed on Carbon Vulcan XC-72, Multiwalled carbon nanotube and reduced graphene oxide (rGO) support containing different Ag:Pt mass ratios and applied to the oxygen reduction reaction (ORR) in a proton exchange membrane fuel cell (PEMFC) were synthesized by the ultrasonic and reduction treatment method. The morphology of as-prepared catalysts characterized by the high resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) and induced coupled plasma atomic emission spectroscopy (ICP-OES). The ORR activities and stabilities of catalysts were studied through electrochemical measurements utilizing the Cyclic Voltammetry... 

In the present study, a 3D combustion chamber was simulated using FLUENT6.32. The objectives were to obtain detailed information on the combustion characteristics and NO formation in the furnace, and also to examine the effect of Oxygen enrichment on the combustion process. The combustion chamber has internal dimensions of 60 cm wide, 90 cm high and 190 cm long. The fuel pipe diameter is 1.25 cm and the air pipe diameter is 3.5 cm. The 3-D Reynolds Averaged Navier Stokes (RANS) equations together with standard k-ε turbulence model are solved by Fluent 6.3. Air/fuel flow rate ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched flow rates are 28, 54, 68 lit/min. NO emission was... 

In various industries, for energy production, fossil fuels are burned. Oxygen needed for combustion, taken directly from the ambient air; So that the inert gas is about 80%. The presence of this inert gas, mainly nitrogen, reduce combustion efficiency and increase the use of combustible material. In this project with the help of membrane technology, was used to remove the amount of nitrogen in the air so that the incoming air into the combustion chamber is enriched with oxygen. For this purpose, several gas separation membrane was applied and evaluated. Then, according to the oxygen enrichment, fuel efficiency and the amount of savings, increasing chamber temperature, reduction manufacturing... 

The air cathode of li-air batteries has been identified as a key factor affecting the overall performance of Li-air batteries. Graphene-based cathodes have been investigated as cathode catalysts for lithium-air batteries due to their high activity in accelerating and facilitating oxygen reduction reaction (ORR). In this study at first, graphene oxide was synthesized using Hummers’ method, and then it has been reduced via hydrothermal methode. To increase electrocatalytic properties of the sample Cobalt oxide nanoparticles has been precipitated on reduced graphene oxide, and it has also been doped with Nitrogen. Three samples of reduced graphene aerogel (GA), Nitrogen doped graphene aerogel...