Sharif Digital Repository

The number of operating vehicles has increased in recent years and as a result global pollutants have widely spread. Therefore, the regulations on the vehicle exhaust emissions have become much stricter. For an automobile to pass the emission tests successfully an accurate calibration of the ECU tables is needed, especially the tables which have direct impact on the amount of pollutant emissions. To achieve the optimum performance of the catalyst existing in the exhaust system of the engine, the fuel/air ratio must have nearly stoichiometric value. The present research studies the ECU strategies for implementing this objective by appropriate management and control of catalyst and oxygen... 

Today, one of the main concerns of steelmakers is the production of clean steel and the removal of non-metallic impurities in the melt. And in the present project, which is the production of clean steel with the minimum amount of oxygen content, firstly, the studies of clean steels and impurities in steel, the quantity, quality and gender of the impurities and also the methods of reducing them until Achieving clean steel is also considered to deoxygenate the steel and reduce the amount of oxygen to the minimum amount. Of course, it should be noted that the type of inclusions investigated in this study will be aluminum inclusions and the results will be analyzed according to the presence of... 

The development of alternative energy sources is a prominent area of scientific research. Hydrogen, with its exceptional energy density, has emerged as a particularly promising candidate among these new energy sources. An effective technique for generating hydrogen is through the electrochemical process of water splitting. To enhance this process, it is crucial to investigate the development of electrocatalysts with high electrocatalytic activity. Among the potential options, sulfides of transition metals show promise. An essential difficulty in electrochemical water splitting is the development of a bifunctional catalyst that is both active and stable for both the hydrogen evolution... 

Decomposition of seawater with the help of sunlight is one of the most promising ways to produce hydrogen as a clean and acceptable fuel in the future. Tungsten photoelectrode is a suitable option for seawater decomposition due to its medium bandwidth, excellent load transfer properties, good chemical stability in acidic and neutral environments, abundance and cost-effectiveness. On the other hand, intermediate metal catalysts (Fe, Ni, Co) are very important due to their abundance in the earth's crust and their stability in alkaline and neutral environments instead of oxides of precious metals (RuO2, IrO2). In this study, tungsten plate (WO3) nanostructures were grown on the surface of a... 

This research is divided in three parts. In the first part of this research, we report the one-pot synthesis of carbonate-coated nanostructured LLO (Li2CO3@LLO) through a polyol-assisted method as a Li-ion battery cathode. Carbonate protects the cathode from adverse reactions with the electrolyte, also reduces the layered-to-spinel phase transition, thereby stabilizing the cathode structure. LLO nanostructure provides a fast Li+ diffusion. The target material exhibits excellent long-term stability with 77% capacity retention after 1000 cycles at 0.2C-rate. In the second part of research, Li(Na-doped)-Mn-Ni-O oxides were synthesized by different LiOH.H2O amount, type and amount of reducing... 

The air cathode of li-air batteries has been identified as a key factor affecting the overall performance of Li-air batteries. Graphene-based cathodes have been investigated as cathode catalysts for lithium-air batteries due to their high activity in accelerating and facilitating oxygen reduction reaction (ORR). In this study at first, graphene oxide was synthesized using Hummers’ method, and then it has been reduced via hydrothermal methode. To increase electrocatalytic properties of the sample Cobalt oxide nanoparticles has been precipitated on reduced graphene oxide, and it has also been doped with Nitrogen. Three samples of reduced graphene aerogel (GA), Nitrogen doped graphene aerogel... 

Depleting resources and heavy pollution of fossil fuels have drawn the world's attention to clean energy and the most ideal one is hydrogen. Water splitting is one of the most effective ways to produce hydrogen and due to slow kinetic rate different kind of catalysts (optical, electrochemical, etc.) are developed for this reaction. In this work a ZIF-67 and N-doped graphene quantum dots composite is developed and its electrocatalytic performance in oxygen evolution reaction is evaluated. The synthesized graphene quantum dots are between 2-4 nm and the incorporation of nitrogen atom in their structure was verified by FTIR analysis. The metal-organic framework which is produced in this work... 

The air cathode of li-air batteries plays a pivotal role in the overall performance of Li-air batteries. Graphene-based cathodes have been investigated as cathode catalysts for lithium-air batteries due to their extraordinary potential for accelerating and facilitating oxygen reduction reaction (ORR).In this study graphene oxide have been synthesized via modified Hummers’ method. Consequently, the as obtained graphene oxide have been reduced using chemical, electrochemical, and hydrothermal methods. Results of elechtrochemical evaluations demonstrate that the graphene oxide reduced via hydrothermal method possesses the most positive ORR onset potential (+0.55V vs SHE) among the other samples... 

For improving cost competitiveness of both SOEC and SOFC technology, it is desirable to reduce the temperature of operation preferably down towards 500 oC – 600 oC, as this will slow down the rate of various degradation processes and allow use of much cheaper materials for auxiliary components. In this range, the oxygen electrode typically dominates the cell resistance, and hence there is a need to develop cost effective electrodes with improved performance at low temperature. Whereas the oxygen exchange on Ruddlesden-Popper type Ni based compounds like Pr2NiO4 with interstitial oxygen defects is known to be very fast, reported electrode performance of micron-sized composites based on these... 

Development of active, durable, cost effective, and stable electrocatalysts are of urgent need for various industrial fields including renewable energy systems such as water splitting. State-of-the-art catalysts suffer from high cost, poor catalytic activity in alkaline medium due to sluggish kinetics. We used one-step electrochemical deposition technique to prepare NiFeCu layered double hydroxide and CoNiFeCu dendritic porous structure on Ni-foam and flexible three-dimensional graphene (3DG) networks, respectively. The fabricated 3D electrodes have a high surface area, high electrical conductivity, and multiple interfaces which along with the synergetic effect of transition metals provided... 

The enormous benefits of hydrometallurgical processes have led to the progressive metals extraction industry. Many studies are carried out on the application of these processes in the copper extraction industry. In this research, the oxygen pressure leaching of chalcopyrite concentrate was studied. Experiments were carried out under conditions of the solid-liquid ratio of 0.1, agitation speed of 750 rpm, and sulfuric acid concentration of 2M in a stainless-steel autoclave system. Central composite design (CCD) was used to design experiments, and three factors of temperature, time, and pressure of oxygen, were selected as design variables. The obtained model for %Cu includes parameters of... 

Solid oxide fuel cells as high temperature electrochemical devices draw much attention in the last decades due to their fuel flexibility, high efficiency and low pollution. However, lowering operating temperature from about 850°C to around 650°C without significant overpotential loss, in order to lower costs and increase cells life time has remained a challenge. Recently, a new family of mixed ionic and electronic conducting ceramics (MIECs) which are formulated Ln2NiO4+δ (Ln= La,Nd,Pr) and crystallized in Ruddlesden–Popper structure, have been regarded as appropriate cathode materials for the low or intermediate temperature solid oxide fuel cells (IT-SOFC). Amongst these compounds,... 

Titanium nitride-carbon nanocomposites are synthesized by the reaction of TiCl4 and NaN3 in supercritical benzene medium that also serves as a carbon source. In order to improve the crystallinity of the as-prepared precursor (SI), it is further heat-treated at 1000 ˚C for 3-10 h using anhydrous ammonia and UHP nitrogen atmospheres at 1000 ˚C (SIII-SV). Moreover, to improve electrochemical behavior, the synthesized nanocomposite (SIV) is modified with Pt nanoparticles using a polyol process. For better understanding of synthesized catalyst nature and justifying their variant ORR activity several analyses are done. X-ray diffraction (XRD), Raman spectrum, field emission scanning electron... 

Designing a system based on 2 to 5 MeV electron accelerators for X radiation of urban waste.Nowadays , the use of ionizing radiation in two cases of treatment and removal of contaminants in the waste including; 1) Pathological hospital waste 2) leachate from buried urban waste, which is studied and examined in this project. Buried urban wastes begin to break down under aerobic and anaerobic processes, and as long as the materials are not changed into sustainable materials, these processes will continue and results in landfill gas and leachate. Gas is produce due to anaerobic processes and leachate which is produced through water infiltration (atmospheric precipitation) in the landfill or... 

Prevent shrinkage and porosity in the melting parts expensive attention has been cast as a piece of low cost healthy and free from defects in casting production. Calculated feeding distance and the required number of risers. Also ensure that more tests were done with computer simulation compared the results acceptable to have the cast and expensive to produce a piece has nearly no troubleshooting. Variety of factors can affect the riser effect is melting parts Read some of these factors include alloy melting, superheat and mold .... . Oxygen factor in the project as one of the molten factors between feeding distance for molten plain carbon steel melting components and parts reviews and... 

The global energy outlook has been altered as a result of mounting concerns regarding fossil fuels. Electrocatalysts have become a favorable alternative for renewable energy production processes, particularly in the fields of hydrogen evolution reactions (HER) and oxygen evolution (OER). This study focuses on the production and enhancement of nanocatalysts, specifically materials based on ZIF-67, for the purpose of water splitting. The initial phase included the synthesis of the ZIF-67 structure through the simple room-temperature coprecipitation process, utilizing cerium as a dual-metal component. The molarity of the cerium was optimized in the ZIF-67 framework to achieve the most desirable... 

Today, due to the decreasing of fossil fuel reserves and the need to use clean fuels, hydrogen is a suitable alternative, and hydrogen production has received considerable attention. One of the best methods of hydrogen production is water splitting. Overall water splitting can be divided into two half reactions including the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), which selecting the appropriate electrocatalyst for these half reactions plays an important role. The four-electron transfer process in OER leads to slow kinetics of the reaction and a large overpotential. The noble metal-based oxides, including IrO2 and RuO2, are known as outstanding OER... 

During the last few decades, efforts have been made to replace fossil fuels with clean and non-absorbent energy sources. One of the promising strategies is energy production by hydrogen storage using water splitting. For this purpose, different methods of using light, heat and electricity are provided. Electrolysis of water with a simple environment such as very high purity of hydrogen produced, controllable, device, no need for high temperature and pressure in the reactor and huge potential for industrial applications has been very much considered. Water electrolysis consists of two reactions: reduction of water to hydrogen (HER) and oxidation of water to oxygen (OER). The second reaction... 

Photoelectrochemical (PEC) water splitting is exceedingly promising for converting solar energy into molecular hydrogen as a clean and sustainable fuel. However, the overall rate of water splitting reaction is severely limited by the sluggish kinetics of the anodic half-reaction, namely, the oxygen evolution reaction (OER). Bismuth vanadate (BiVO4) is a popular photoanode for PEC water splitting due to its high stability, low cost, narrow band gap (2.4 eV), high visible-light absorption, and environmental compatibility. However, BiVO4 suffers from poor charge transfer, fast recombination of electron-hole pairs, and inferior catalytic activity toward OER. An effective strategy to overcome... 

Nowadays, advanced and inexpensive pre-clinical methods for investigating the effects of anti-cancer drugs are expanding. One of the latest three-dimensional laboratory modeling for evaluating the effects of drugs is the use of tumor-on-chip technology, which actually models the physiological system of the body through three-dimensional scaffolds, multicellular cultures, and shaped vascular systems. In this study, three-dimensional culture of cancer cells was performed in the form of spheroids. A chip of U-shaped microstructures with and without gaps was used to trap cells and form cancer spheroids. We simulated the simultaneous effect of drug and oxygen concentration distribution inside the...