Sharif Digital Repository

In this research, the effect of Ni, Pd and Ni-Pd catalysts have studied on morphology and structure of synthesized multi-wall carbon nanotubes (MWCNTs). Initially, thin films of Ni (with two thicknesses of 10 and 20 nm), Pd/Ni (5/10 nm) and Pd (10 nm) were deposited as catalysts on SiO 2 (60 nm)/Si(1 0 0) substrates, using dc magnetron sputtering technique. The deposited films were annealed at 900 °C in ammonia environment for 45 min, in order to obtain nano-structured catalyst on the surface. Using scanning electron microscopy (SEM), the average size of Ni nano-islands (synthesized by the 10 and 20 nm Ni films), Pd and Ni-Pd nano-islands were measured about 55, 110, 45 and 50 nm,... 

Porous silicon samples are obtained by electrochemical method on n-type wafers in room light. Scanning electron microscopy showed that the porous structure consisted of macropores under a thin microporous layer. Placing the samples in Pd-electroless solution causes the crakes inside the microporous layer and growth of the palladium particles in these crakes. However, removing the microporous layer by KOH solution with an ultrasonically assisted process makes the growth of rather uniform palladium particles on the surface in electroless plating. Variation of the electrical resistance in the presence of diluted hydrogen at room temperature revealed that the best samples have the ability to... 

This article presents the research results on production and performance of palladium-only catalytic converters. Monolith is used as catalyst carrier and gamma alumina as substrate. Dipping method is used for monolith washcoating. Palladium as the active metal is impregnated on gamma alumina using wet impregnation to produce catalyst samples. The effects of factors such as percent solid in slurry, milling time, calcination time and temperature, pH and existence of Al(NO3)3 on wash-coat characteristics were studied experimentally. SEM, XRD, and BET tests were carried out on the samples. Catalyst performance was tested in an experimental reactor that was designed for this research. The results... 

Porous silicon samples obtained from p+-type silicon wafers were impregnated with Pd by electroless process in different conditions. Scanning electron microscopy was used to study the change in the features of the surface after palladium plating. Results showed how the factors like Pd-salt concentration, HCl concentration, temperature of the electroless solution and the time of process affect on the growth and nucleation of Pd particles. Observations demonstrated that illumination-assisted process and pre-oxidation of the surface before process have drastic effect on the growth of palladium. Variation of the electrical resistance in the presence of diluted hydrogen at room temperature... 

Porous poly-silicon (PPS) samples, obtained by electrochemical anodization of p-type poly-silicon wafers, were doped with Pd by the electroless process. Rutherford backscattering spectroscopy shows that Pd has diffused a few micrometres into the PPS layer. Scanning electron microscopy and energy dispersive x-ray analysis results demonstrate the presence of Pd as dispersed clusters on the surface. The variation of the electrical resistance in the presence of dry air diluted with hydrogen at room temperature shows that Pd/PPS samples have the ability to sense hydrogen at levels down to several thousands of ppm. This value is far below the flammability limit of hydrogen gas. It was found that... 

The novel unsymmetrical tetradentate Schiff base complexes of Co(II) and Pd(II) with the general formula M(SaI.Phen.Acac.) and M(Sal.Phen. Naph.), have been synthesised by template and non-template method