Sharif Digital Repository

Nickel and nickel-copper alloy modified glassy carbon electrodes (GC/Ni and GC/NiCu) prepared by galvanostatic deposition were examined for their redox process and electrocatalytic activities towards the oxidation of methanol in alkaline solutions. The methods of cyclic voltammetery (CV) and chronoamperometry (CA) were employed. The cyclic voltammogram of NiCu alloy demonstrates the formation of β/β crystallographic forms of the nickel oxyhydroxide under prolonged repetitive potential cycling in alkaline solution. In CV studies, in the presence of methanol NiCu alloy modified electrode shows a significantly higher response for methanol oxidation. The peak current of the oxidation of nickel... 

LLC resonant converter has been used widely as dc-dc converter for achieving constant dc voltage. In this paper, an LLC resonant converter, by adding an inductance to its conventional topology and considering the rectifying stage stray inductances, is proposed for an adjustable wide range regulated current source (20-200 A dc) for using as ion implanter's filament power supply. The additional inductor increases output current adjustment range and efficiency, especially at light loads. Transformer's leakage inductances and rectifying stage stray inductances have been considered. Because of these inductances, the rectifier stage always works in continuous conduction mode, and its conduction... 

Differential pulse polarography (DPP) was applied for the determination of the herbicide Tribenuron-methyl (TBM). This is a first study for various parameters affecting the reduction peak current were simultaneously optimized using experimental design and these results are different from other reports. The effect of factors such as voltage step, voltage step time, pulse amplitude, pulse time, sample pH, concentration of the supporting electrolyte and the mercury drop size were assessed by means of a (27-2) fractional factorial design. It was found that the effects and interactions of four out of seven factors were significant. Consequently, a central composite design (CCD) with four factors,...