Sharif Digital Repository

A new-generation equation of state, perturbed-chain statistical association fluid theory (PC-SAFT), has attracted much attention to modeling the phase behavior of fluids using molecular-based equations of state. A set of three pure component parameters is needed for non-associative compounds, conventionally determined by fitting vapor pressure and liquid density data simultaneously. Unfortunately, experimental data are scarce, and the number of pure substances is too large. Thus, it is indispensable for developing predictive methods to determine the pure component parameters. In the present paper, a new model has been developed to estimate PC-SAFT parameters for different pure components,... 

The thorough knowledge of the asphaltene aggregation phenomena and pressure/temperature related kinetics is helpful for accurate prediction/control of the asphaltene issues in all facets of petroleum production/processing. However, characterizing the asphaltene aggregation phenomena in live oils at high pressure-high temperature conditions is not well discussed in the available literature. In this work, the asphaltene aggregation phenomena as well as the kinetics of aggregation at different levels of pressure and temperature are investigated in light and heavy live oils using high pressure microscope. The results are presented and discussed in terms of asphaltene onset pressure, aggregates... 

Accurate determination of natural gas viscosity is important for successful design of production, transportation, and gas storage systems. However, most of available models/correlations suffer from complexity, robustness, and inadequate accuracy especially when wide range of pressure and temperature is applied. Present study illustrates development of two novel models for predicting natural gas viscosity for pure natural gas (CH4) as well as natural gas containing impurities. For this purpose, 6484 data points have been gathered and analyzed from the open literature covering wide range of pressure, temperature, and specific gravity levels, temperature ranges from -262.39 to 620.33 °F (109.6... 

Recently, carbon dioxide (CO2) flooding into depleted reservoirs regardless of miscible or immiscible displacement is widely investigated not only to improve oil recovery but also to reduce the greenhouse effect of this gas produced by numbers of industries in the globe. In the light of this fact, in the first stage of this investigation, the minimum miscibility pressure (MMP) of CO2 and light crude oil (API° = 35) with low asphaltene content was determined at temperatures of 30, 50 and 80 °C using vanishing interfacial tension (VIT) method. The obtained results demonstrated that the MMP of the studied system is almost linear function of temperature with slope of 0.15 MPa/K. The interesting... 

In this work, a novel multi-layer pressure-temperature swing adsorption (PTSA) process was designed for efficient simultaneous water and mercaptans removal from natural gas (NG) to less than 0.1 ppmv and 3 ppmv in a mini liquefied NG unit. The proposed multi-layer PTSA consists of a three-layer fixed bed including activated alumina, molecular sieves 4A and 13X. To gain in-depth insights about the process, a descriptive model considering mass, energy and momentum balances, along with the kinetic and equilibrium equations was developed. After validating the model with the experimental and operational data from the literature, the total energy requirement and long-term operational requirements... 

With a complete accounting of hydrodynamic forces on the translational-radial dynamics of a moving single-bubble sonoluminescence, temporal evolution of the bubble trajectory is investigated. In this paper, by using quasi-adiabatic evolution for the bubble interior, the bubble peak temperature at the bubble collapse is calculated. The peak temperature changes because of the bubble translational motion. The numerical results indicate that the strength of the bubble collapse is affected by its translational movement. At the bubble collapse, translational movement of the bubble is accelerated because of the increase in the added mass force on the bubble. It is shown that the magnitude of the... 

In this work, high-pressure microscopy technique was used to measure the size and fractal dimension of asphaltene aggregates formed in different live oil samples at elevated pressures and temperatures. It was found that the asphaltene aggregates in live oil samples are irregular fractal-like structures with pressure−temperature-dependent fractal dimensions. By monitoring the variation of the fractal dimension and size of the asphaltene aggregates with pressure and temperature, the mechanisms responsible for asphaltene aggregation process at elevated pressures and temperatures can be well predicted. The range of fractal dimension of asphaltene aggregates in live oils is similar to that... 

Petroleum industry is moving toward enhancing oil recovery methods, especially water-based methods, including low salinity and smart water flooding which water with an optimized composition is injected into the reservoir for improving oil recovery. Injection of water into the target formation is also a common operation in geothermal energy production. As the water is being injected into the reservoir, pressure and temperature change along the well column and cause scale formation. Mineral scale precipitation and deposition is a common problem for water injection wells which reduces the effective radius of the wellbore and affects the injection efficiency. In this paper, modeling scale... 

A gas turbine in combination with a nuclear heat source has been subject of study for some years. This paper describes the advantages of a gas turbine combined with an inherently safe and well-proven nuclear heat source. The design of the power conversion system is based on a regenerative, non-intercooled, closed, direct Brayton cycle with high temperature gas-cooled reactor (HTGR), as heat source and helium gas as the working fluid. The plant produces electricity and hot water for district heating (DH). Variation of specific heat, enthalpy and entropy of working fluid with pressure and temperature are included in this model. Advanced blade cooling technology is used in order to allow for a... 

Many oil reservoirs encounter asphaltene precipitation as a major problem during natural production. In spite of numerous experimental studies, the effect of temperature on asphaltene precipitation during pressure depletion at reservoir conditions is still obscure in the literature. To study their asphaltene precipitation behavior at different temperatures, two Iranian light and heavy live oil samples were selected. First, different screening criteria were applied to evaluate asphaltene instability of the selected reservoirs using pressure, volume, and temperature data. Then, a high pressure, high temperature filtration (HPHT) setup was designed to investigate the asphaltene precipitation... 

In this research, direct conversion of wet algal biomass into biodiesel using supercritical methanol was studied. In this process, microalgal lipids simultaneously was extracted and converted to biodiesel under high pressure and temperature conditions without using any catalyst. Several experiments have been performed to optimize the methanol amount and it has been revealed that the best performance was achieved by using methanol/wet biomass ratio of 8:1. The effect of using various co-solvents in increasing the efficiency of the supercritical process was investigated. It has been shown that hexane was the most effective co-solvent and its optimal ratio respect to wet biomass was 6:1. The... 

In this work, the potential for the auto-ignition of Iranian heavy oil during in situ combustion (ISC) process conditions was studied. Kinetic studies were carried out using thermal analysis techniques. Effects of oxygen partial pressure, reservoir pressure, and clay on the auto-ignition condition were investigated. Based on the experimental results obtained, a kinetic equation was derived for each of the different oil samples in the presence of different sands. The effect of partial pressure of oxygen in the injected air showed that at atmospheric pressure, low temperature combustion (LTC) was initiated at 275°C. Also, enriching the injected air by oxygen lowers the initial LTC temperature... 

With the declining energy resources and increase of pollutant emissions, a great deal of efforts has been focused on the development of alternatives for fossil fuels. One of the promising alternative fuels to gasoline in the internal combustion engine is natural gas [1-5]. The application of natural gas in current internal combustion engines is realistic due to its many benefits. The higher thermal efficiency due to the higher octane value and lower exhaust emissions including CO2 as a result of the lower carbon to hydrogen ratio of the fuel are the two important feature of using CNG as an alternative fuel. It is well known that computer simulation codes are valuable economically as a cost... 

During transient tests, both pressure and temperature are changed depending on downhole flow rate. In gas producing wells, Joule-Thomson cooling and frictional heating effects are the main dynamic factors causing flowing bottomhole temperature to differ from the static formation temperature at that depth. When a gas well is shut in, JT cooling effect is vanished and this causes a sharp increase in sandface temperature. As effect of wellbore storage ends, wellbore temperature gradually cools down due to heat conduction with near wellbore region. This paper demonstrates a new technique for using temperature transient data in gas wells in order to determine end of wellbore storage. Also, effect...