Search for: reproducibility
Total 166 records
Immersed single-drop microextraction-electrothermal vaporization atomic absorption spectroscopy for the trace determination of mercury in water samples, Article Journal of Hazardous Materials ; Volume 165, Issue 1-3 , 2009 , Pages 353-358 ; 03043894 (ISSN) ; Naderi, M ; Sharif University of Technology
Generic extraction medium: From highly polar to non-polar simultaneous determination, Article Analytica Chimica Acta ; Volume 1066 , 2019 , Pages 1-12 ; 00032670 (ISSN) ; Khalilzadeh, M ; Bagheri, H ; Sharif University of Technology
Elsevier B.V 2019
Sample preparation for non-target analysis is challenging due to the difficulty in the extraction of polar and non-polar analytes simultaneously. Most commercial solid sorbents lack the proper comprehensiveness for extraction of analytes with different physiochemical properties. A possible key is the combination of hydrophobic polymer and hydrophilic surface functional groups in solid based extraction methods in order to generate the susceptibility for retaining both polar and non-polar analytes. To pursue this goal, in this study, four polar groups including [sbnd]NH 2 , [sbnd]NO 2 , [sbnd]COOH, and [sbnd]COCH 3 were chemically bound to Amberlite XAD-4 substrate in order to prepare a...
Roles of metal, ligand and post synthetic modification on metal organic frameworks to extend their hydrophobicity and applicability toward ultra–trace determination of priority organic pollutants, Article Analytica Chimica Acta ; Volume 1125 , 2020 , Pages 231-246 ; Abbasi, A ; Bagheri, H ; Sharif University of Technology
Elsevier B.V 2020
Implementation of metal organic frameworks (MOFs) in the separation science has attracted many researchers attention. In this study, the role of metal, ligand, the reaction condition and modification on the extraction efficiency of some MOFs was investigated. Among the prevalent reported MOFs, some members of the MIL and MOF–5 families were chosen, and eleven MOF–based sorbents were prepared by changing the metal and ligand type, reaction condition, and/or functionality through post synthetic modification (PSM). MIL–101 and MIL–101–NH2 based structures were initially synthesized based on the chromium and iron salts. Also, three zinc–based structures including MOF–5, [NH2(CH3)2]2...
Efficient one-pot four-component synthesis and X-ray crystallographic structure of 2-pyridone derivatives, Article Journal of Heterocyclic Chemistry ; Volume 50, Issue 6 , 2013 , Pages 1272-1280 ; 0022152X (ISSN) ; Hashemi, M. M ; Khezri, S. H ; Rominger, F ; Ghabraie, E ; Oeser, T ; Sharif University of Technology
A series of 3-cyano-2-pyridone derivatives were synthesized by one-pot four-component condensation reaction involving a benzaldehyde derivative, alkyl cyanoacetate, acyclic or cyclic ketones, and ammonium acetate in reflux condition. The X-ray structure of the products 5a and 5d confirm symmetric dimers via hydrogen bonding interactions between individual pyridine molecules showing, in addition, also π-π stacking interactions
Reinforced polydiphenylamine nanocomposite for microextraction in packed syringe of various pesticides, Article Journal of Chromatography A ; Volume 1222 , January , 2012 , Pages 13-21 ; 00219673 (ISSN) ; Ayazi, Z ; Es'haghi, A ; Aghakhani, A ; Sharif University of Technology
Reinforced polydiphenylamine (PDPA) nanocomposite was synthesized by oxidation of diphenylamine in 4molL-1 sulfuric acid solution containing a fixed amount of carbon nanotubes (CNTs) in the presence of cetyltrimethylammonium bromide (CTAB). The surface characteristic of PDPA and PDPA/CNT nanocomposites was investigated using scanning electron microscopy (SEM). The prepared PDPA/CNT nanocomposite was used as an extraction medium for microextraction in packed syringe (MEPS) of selected pesticides from aquatic environment. The effect of CNT doping level and the presence of surfactant on the extraction capability of nanocomposite was investigated and it was revealed that when 4% (w/w) of CNT in...
Design and fabrication of an electrochemical aptasensor using Au nanoparticles/carbon nanoparticles/cellulose nanofibers nanocomposite for rapid and sensitive detection of Staphylococcus aureus, Article Bioelectrochemistry ; Volume 123 , 2018 , Pages 70-76 ; 15675394 (ISSN) ; Shahrokhian, S ; Sharif University of Technology
Elsevier B.V 2018
Since that pathogenic bacteria are major threats to human health, this paper describes the fabrication of an effective and durable sensing platform based on gold nanoparticles/carbon nanoparticles/cellulose nanofibers nanocomposite (AuNPs/CNPs/CNFs) at the surface of glassy carbon electrode for sensitive and selective detection of Staphylococcus aureus (S. aureus). The AuNPs/CNPs/CNFs nanocomposite with the high surface area, excellent conductivity, and good biocompatibility was used for self-assembled of the thiolated specific S. aureus aptamer as a sensing element. The surface morphology of AuNPs/CNPs/CNFs nanocomposite was characterized with field emission scanning electron microscopy...