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    Design and Construct of Nd:YAG Laser and Using it in the Laser Ablation Process of Silver, Titanium and Zinc Element

    , M.Sc. Thesis Sharif University of Technology Gohari kamel, Nasser (Author) ; Sadighi Bonabi, Rasoul (Supervisor)
    Abstract
    The purpose of this project is to investigate the production of nano-micro metallic particles—of different elements—with different characteristics in size and optical property by employing a pulsed laser ablation processes in liquid medium. In this study, the means by which we build the laser, the experimental arrangement of the pulsed laser ablation process, the measurement of the absorption spectrum of generated nano-micro particles as well as the size of the particles are discussed.
    To satiate this aim, we have expressed the manner of constructing the Nd:YAG laser, the power supply circuits, along with its optics. This laser has some advantages such as high energy ~700mj, good... 

    The 2D SEM: A novel high-performance and low-power mesh-based topology for networks-on-chip

    , Article International Journal of Parallel, Emergent and Distributed Systems ; Vol. 25, issue. 4 , 2010 , p. 331-344 ; ISSN: 17445760 Sabbaghi-Nadooshan, R ; Modarressi, M ; Sarbazi-Azad, H ; Sharif University of Technology
    Abstract
    In this paper, a 2D shuffle-exchange based mesh topology, or 2D shuffle-exchange mesh (SEM) for short, is presented for network-on-chips. The proposed 2D topology applies the conventional well-known shuffle-exchange structure in each row and each column of the network. Compared to an equal sized mesh which is the most common topology in on-chip networks, the proposed shuffle-exchange based mesh network has smaller diameter but for an equal cost. Finally for better performance cross-shuffle is proposed. Simulation results show that the 2D SEM and 2D cross-shuffle effectively reduce the power consumption and improve performance metrics of the on-chip networks compared to the conventional mesh... 

    Investigation of asphaltene adsorption in sandstone core sample during CO2 injection: Experimental and modified modeling

    , Article Fuel ; Vol. 133 , 2014 , Pages 63-72 ; ISSN: 00162361 Jafari Behbahani, T ; Ghotbi, C ; Taghikhani, V ; Shahrabadi, A ; Sharif University of Technology
    Abstract
    In this work, asphaltene adsorption in a sandstone core sample under dynamic conditions and during miscible CO2 injection was studied using live oil sample which is close to real conditions in petroleum reservoirs. In order to investigate of damage in sandstone core sample by the deposited material such as asphaltene, the morphology analysis of sandstone core sample using scanning electron microscopic method was studied. Also analyses of the adsorbed material in sandstone core sample by Soxhlet extraction using an azeotrope mixture and with SARA method were performed. The experimental results show that by increasing the flow rate of injected CO2, the amount of asphaltene in retained material... 

    A novel approach for preparation of CL-20 nanoparticles by microemulsion method

    , Article Journal of Molecular Liquids ; Vol. 193, issue , May , 2014 , pp. 83-86 Bayat, Y ; Zarandi, M ; Zarei, M. A ; Soleyman, R ; Zeynali, V ; Sharif University of Technology
    Abstract
    2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) as one of the high energy cage nitramines has been used in various propellants and explosive formulations. The performance of energetic materials depends on its particle size and shape. Therefore, in this research, microemulsion method has been applied for the preparation of CL-20 nanoparticles via oil in water (O/W) microemulsions. The optimized formulation contains water 45%, n-butyl acetate 20.5%, sodium dodecyl sulfate (SDS, as anionic surfactant) 6.5% and 2-propanol (as co-surfactant) 26.5%. CL-20 nanoparticles that were obtained by microemulsion method are spherical with an average diameter of 25 nm, based on TEM image.... 

    Effect of carbon nanotube incorporation in polyvinyl alcohol on structure and morphology of derived electrospun carbon nanofibers in presence of iodine and cadmium salt

    , Article Materials Chemistry and Physics ; April , 2014 ; SSN: 02540584 Azami Ghadikolaei, M ; Faghihi-Sani, M. A ; Shabani, K ; Baniasadi, A ; Sharif University of Technology
    Abstract
    This research focused on fabrication of various carbon nanofibers (CNFs) from electrospun Polyvinyl alcohol (PVA) by utilization of iodine (I2) and cadmium acetate dihydrate (Cd) as stabilizers. Moreover, the influence of carbon nanotube (CNT) incorporation on structure and morphology of CNFs was investigated. In this regard, PVA and PVA-Cd solutions were individually prepared and electrospun. The resulting nanofibers were treated in I2 vapor and then carbonized. In the case of CNT incorporation, oxidized CNTs were first scattered in PVA and PVA-Cd solutions and then electrospun, iodinated and carbonized in the same conditions as mentioned above. It was found that the I2, Cd and their... 

    Influence of tool geometry and contact condition on friction stir welding of Al-Cu laminated composites

    , Article Advanced Materials Research ; Vol. 856 , 2014 , pp. 16-21 ; ISSN: 10226680 Beygi, R ; Kazeminezhad, M ; Kokabi, A. H ; Alvani, S. M. J ; Verdera, D ; Loureiro, A ; Sharif University of Technology
    Abstract
    In this study friction stir welding of Al-Cu laminated composites were carried out by two different tool geometries. Welding procedure was carried out from both sides of Al and Cu. Analyzing cross section of welds showed that different contact conditions between shoulder and material, offers different material flow behavior which is dependent on the tool geometry. SEM analyses showed that mixing of materials in nugget region is more pronounced in the advancing side. Also XRD results indicated that welding from Cu side, leads to intermetallic formation in mixed regions  

    Metallography and microstructure interpretation of some archaeological tin bronze vessels from Iran

    , Article Materials Characterization ; Vol. 97 , November , 2014 , pp. 74-82 Oudbashi, O ; Davami, P ; Sharif University of Technology
    Abstract
    Archaeological excavations in western Iran have recently revealed a significant Luristan Bronzes collection from Sangtarashan archaeological site. The site and its bronze collection are dated to Iron Age II/III of western Iran (10th-7th century BC) according to archaeological research. Alloy composition, microstructure and manufacturing technique of some sheet metal vessels are determined to reveal metallurgical processes in western Iran in the first millennium BC. Experimental analyses were carried out using Scanning Electron Microscopy-Energy Dispersive X-ray Spectroscopy and Optical Microscopy/Metallography methods. The results allowed reconstructing the manufacturing process of bronze... 

    Synthesis and properties of MWCNT-HAP composites via sol-gel technique

    , Article Iranian Journal of Materials Science and Engineering ; Volume 10, Issue 2 , 2013 , Pages 57-63 ; 17350808 (ISSN) Jafaripour Maybody, J ; Nemati, A ; Salahi, E ; Sharif University of Technology
    2013
    Abstract
    In the present study, bioceramic composites based hydroxyapatite (HAp) reinforced with carbon nanotubes (CNTs) was synthesized via sol-gel technique. The dried gels were individually heated at a rate of 5°C/min up to 600°C for 2 h in a muffle furnace in order to obtain HAp-MWCNTs mixed powder. Composites were characterized by XRD, FT-IR, SEM, TEM/SAED/EDX and Raman spectroscopy techniques. Results showed the synthesis of HAp particles in the MWCNTs sol which was prepared in advance, leads to an excellent dispersion of MWCNTs in HAp matrix. Apparent average size of crystallites increased by increasing the percentage of MWCNTs. The average crystallite size of samples (at 600°C), estimated by... 

    Micro-stratigraphical investigation on corrosion layers in ancient Bronze artefacts by scanning electron microscopy energy dispersive spectrometry and optical microscopy

    , Article Heritage Science ; Volume 1, Issue 1 , 2013 ; 20507445 (ISSN) Oudbashi, O ; Emami, S. M ; Ahmadi, H ; Davami, P ; Sharif University of Technology
    2013
    Abstract
    Background: Archaeological metallic artefacts buried in soils deteriorate by means of various environmental as well as internal factors and mechanisms over time such as change in composition and microstructure of metal and corrosive factors due to long-term burial environment. Corrosion in metals occurs in different morphologies and results in different types of corrosion products based on soil composition. Identification of corrosion mechanisms and morphology in archaeological metals can help conservators to characterize deterioration occurred in metals and make decisions to protect artefacts about preventing further deterioration. In archaeological bronzes, different layers may form on the... 

    Pressureless sintering of Ta0.8Hf0.2C UHTC in the presence of MoSi2

    , Article Ceramics International ; Volume 39, Issue 2 , 2013 , Pages 1985-1989 ; 02728842 (ISSN) Ghaffari, S. A ; Faghihi Sani, M. A ; Golestani Fard, F ; Ebrahimi, S ; Sharif University of Technology
    2013
    Abstract
    Ta0.8Hf0.2C ceramic has the highest melting point among the known materials (4000 °C). However, this high melting point makes the ceramic difficult to be sintered at temperatures lower than 2300 °C, pressurelessly. The purpose of this study is to consolidate Ta 0.8Hf0.2C UHTC by pressureless sintering at 2000 °C using MoSi2 as sintering aid. In this regard, effect of different amounts of MoSi2 on sintering behavior of Ta0.8Hf 0.2 UHTC was investigated. It was observed that condensation of the UHTC after sintering at 2000 °C was enhanced by increasing MoSi2 content and the highest relative density of 95% was obtained in the presence of 24 vol.% MoSi2. XRD pattern of the sintered UHTC... 

    Controlled microwave-assisted synthesis of ZnFe 2 O 4 nanoparticles and their catalytic activity for O-acylation of alcohol and phenol in acetic anhydride

    , Article Scientia Iranica ; Volume 19, Issue 6 , December , 2012 , Pages 1597-1600 ; 10263098 (ISSN) Matloubi Moghaddam, F ; Doulabi, M ; Saeidian, H ; Sharif University of Technology
    2012
    Abstract
    ZnFe2O4 nanoparticles have been successfully prepared through a controlled microwave-assisted co-precipitation. X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and Vibrating Sample Magnetometer (VSM) were used for the structural, morphological and magnetic investigation of the product. SEM micrographs of ZnFe2O4 nanopowder also reveal that nanoparticles have spherical shape. Average particle size was obtained as 12 nm from XRD. Catalytic activity of ZnFe2O4 nanopowder for O-acylation of alcohol and phenol has been investigated. A trace amount of ZnFe2O4 has been effectively used as a nanocatalyst for the acylation of alcohol and... 

    Electrophoretic deposition of bioactive glass coating on 316L stainless steel and electrochemical behavior study

    , Article Applied Surface Science ; Volume 258, Issue 24 , 2012 , Pages 9832-9839 ; 01694332 (ISSN) Mehdipour, M ; Afshar, A ; Mohebali, M ; Sharif University of Technology
    Elsevier  2012
    Abstract
    In this research, submicron bioactive glass (BG) particles were synthesized by a sol-gel process and were then coated on a 316L stainless steel substrate using an electrophoretic deposition (EPD) technique. Stable suspension of bioactive glass powders in ethanol solvent was prepared by addition of triethanol amine (TEA), which increased zeta potential from 16.5 ± 1.6 to 20.3 ± 1.4 (mv). Thickness, structure and electrochemical behavior of the coating were characterized. SEM studies showed that increasing EPD voltage leads to a coating with more agglomerated particles, augmented porosity and micro cracks. The results of Fourier transformed infrared (FTIR) spectroscopy revealed the adsorption... 

    Theoretical model for evaluating the threshold reduction in roll bonding of Al/Al 2O 3/Al laminations

    , Article Metals and Materials International ; Volume 18, Issue 5 , 2012 , Pages 827-832 ; 15989623 (ISSN) Rezayat, M ; Akbarzadeh, A ; Sharif University of Technology
    Springer  2012
    Abstract
    Roll bonding is the most important stage of the accumulative roll bonding process, which is used to produce high strength composites. The presence of a particle layer at the interface alters the bonding condition and increases the threshold reduction for the commencement of bonding. In this study, the bonding mechanism in presence of powder at the interface is analyzed and a theoretical model is proposed to predict the required threshold reduction in warm roll bonding of commercially pure aluminum sheets as a function of amount of alumina particles at the interface. The model considers the rolling parameters and the effect of amount and size of particles by defining some constants, which are... 

    Fabrication of biocompatible titanium scaffolds using space holder technique

    , Article Journal of Materials Science: Materials in Medicine ; Volume 23, Issue 10 , 2012 , Pages 2483-2488 ; 09574530 (ISSN) Dezfuli, S. N ; Sadrnezhaad, S. K ; Shokrgozar, M. A ; Bonakdar, S ; Sharif University of Technology
    Springer  2012
    Abstract
    Open-pore titanium scaffolds were fabricated by sintering of compressed mixtures of TiH1.924 and urea. Spherical and irregular shaped space holders were used to investigate the effect of pore shape on cellular behavior. After removal of the space holder, the shape of the spacers was replicated to the pores. Average diameter of the pores was in the range of 300-600 lm. SEM images showed that titanium hydride resulted in higher surface roughness and larger micro porosities than pure titanium. In vitro evaluationswere carried out by using MTT assay, measuring alkaline phosphatase activity and alizarin red staining in flow perfusion bioreactor for cell culture. Observations revealed excellent... 

    Effect of NaOH on the structure and corrosion performance of alumina and silica PEO coatings on aluminum

    , Article Journal of Materials Engineering and Performance ; Volume 21, Issue 10 , October , 2012 , Pages 2195-2202 ; 10599495 (ISSN) Salehi Doolabi, D ; Ehteshamzadeh, M ; Mirhosseini, S. M. M ; Sharif University of Technology
    Springer  2012
    Abstract
    The effect of NaOH content of electrolyte on the properties of ceramic coatings, produced in silicate solution, was studied. Morphology, chemical analysis, phase composition, and cross-section of the ceramic coatings were investigated by SEM, EDS, XRD, and OM, respectively. The corrosion resistance and corrosion mechanism were also studied using potentiodynamic polarization and electrochemical impedance spectroscopy in a 3.5% NaCl solution. To study the surface roughness, a brightness SEM image analysis method was used. Results suggested that increasing the NaOH concentration of sediment production size causes thickness and coating roughness to decrease. The lowest corrosion rate belonged to... 

    Effect of synthesis conditions on performance of a hydrogen selective nano-composite ceramic membrane

    , Article International Journal of Hydrogen Energy ; Volume 37, Issue 20 , October , 2012 , Pages 15359-15366 ; 03603199 (ISSN) Amanipour, M ; Safekordi, A ; Ganji Babakhani, E ; Zamaniyan, A ; Heidari, M ; Sharif University of Technology
    Elsevier  2012
    Abstract
    A hydrogen-selective nano-composite ceramic membrane was prepared by depositing a dense layer composed of SiO2 and Al2O 3 on top of a graded multilayer substrate using co-current chemical vapor deposition (CVD) method. The multilayer substrate was made by dip-coating a macroporous α-alumina tubular support by a series of boehmite solutions to get a graded structure. Using DLS analysis, it was concluded that decreasing hydrolysis time and increasing acid concentration lead to smaller particle size of boehmite sols. XRD analysis was carried out to investigate the structure of intermediate layer and an optimized calcination temperature of 973 K was obtained. SEM images indicated the formation... 

    Effects of hydrogen and oxides on tensile properties of Al-Si-Mg cast alloys

    , Article Materials Science and Engineering A ; Volume 552 , 2012 , Pages 36-47 ; 09215093 (ISSN) Eisaabadi B., G ; Davami, P ; Kim, S. K ; Varahram, N ; Sharif University of Technology
    Abstract
    Gas porosities and entrapped double oxide film (hereafter: oxides) are known to be the most detrimental defects in cast Al-Si-Mg alloys. This study investigated the effects of dissolved hydrogen (hereafter: H) and oxides on reproducibility of tensile properties in Al-7Si-0.35 Mg alloys. Also the effects of H and oxides content on the morphology of defects were studied. Four different casting conditions (low oxide-low H, low oxide-high H, high oxide-low H, high oxide-high H) were tested using tensile test bars that were cast in a metallic mold. Results of tensile test that were obtained for each casting condition were analyzed using Weibull two-parameter analysis. Microstructure and fracture... 

    Corrosion behavior of aluminum 6061 alloy joined by friction stir welding and gas tungsten arc welding methods

    , Article Materials and Design ; Volume 39 , 2012 , Pages 329-333 ; 02641275 (ISSN) Fahimpour, V ; Sadrnezhaad, S. K ; Karimzadeh, F ; Sharif University of Technology
    Abstract
    Wrought aluminum sheets with thickness of 13. mm were square butt-welded by friction stir welding (FSW) and gas tungsten arc welding (GTAW) methods. Corrosion behavior of the welding zone was probed by Tafel polarization curve. Optical metallography (OM) and scanning electron microscopy together with energy dispersive spectroscopy (SEM-EDS) were used to determine morphology and semi-quantitative analysis of the welded zone. FSW resulted in equiaxed grains of about 1-2 μm, while GTAW caused dendritic structure of the welded region. Resistance to corrosion was greater for the FSW grains than the GTAW structure. In both cases, susceptibility to corrosion attack was greater in the welded region... 

    Failure analysis of a cracked gasoline engine cylinder head

    , Article Journal of Failure Analysis and Prevention ; Volume 12, Issue 3 , 2012 , Pages 286-294 ; 15477029 (ISSN) Azadi, M ; Mafi, A ; Roozban, M ; Moghaddam, F ; Sharif University of Technology
    2012
    Abstract
    This article presents a failure analysis on a gasoline engine cylinder head made of aluminum alloy, which has been used in passenger cars. During an endurance test, a crack initiated from the interior wall of a hole in the center of the cylinder head and then propagated through the thickness of the cylinder head. The metallurgical examinations are conducted in the crack origin zone. The results show that there are many casting pores due to poor quality of casting in the failed cylinder head which has certainly played a crucial role in initiating the crack. Finite element analysis of the cylinder head is performed to identify the stress components. Modeling of a bolt for the hole shows that... 

    The effects of SiO 2 and K 2O on glass forming ability and structure of CaOTiO 2P 2O 5 glass system

    , Article Ceramics International ; Volume 38, Issue 4 , 2012 , Pages 3281-3290 ; 02728842 (ISSN) Ahmadi Mooghari, H. R ; Nemati, A ; Eftekhari Yekta, B ; Hamnabard, Z ; Sharif University of Technology
    2012
    Abstract
    The effects of SiO 2 and K 2O were investigated on the glass forming ability (GFA) and structural characteristics of CaOTiO 2P 2O 5 system. Differential thermal analyzer (DTA), X-ray diffraction (XRD), scanning electron microscopy (SEM), FT-IR and 31P magic angle spinning NMR methods were applied for characterizations of the system. Unwanted crystallization in the initial three components base glass composition was observed by adding SiO 2 and crystalline phases such as TiP 2O 7, rutile (TiO 2) and cristobalite (SiO 2) were formed in it. The results showed that K 2O prevents crystallization of glasses and promotes the formation of glass. FT-IR and X-ray diffraction showed that the addition...