Sharif Digital Repository

In manufacturing amorphous silicon solar cells, thin films are deposited at high temperatures (200-400 °C) on a thick substrate using sputtering and plasma enhanced chemical vapor deposition (PECVD) methods. Since the thin films and substrate have different thermal expansion coefficients, cooling the system from deposition temperature to room temperature induces thermal residual stresses in both the films and substrate. In addition, these stresses, especially those having been induced in the amorphous silicon layer can change the carrier mobility and band gap energy of the silicon and consequently affect the solar cell efficiency. In this paper, a 2D finite element model is proposed to... 

Challenging problems in the design and analysis of photovoltaic (PV) systems stem from the nonlinear current–voltage (I–V) characteristics of solar cells. This paper presents an analytical analysis based on a describing function method to investigate the transient and steady-state characteristics of a three-phase single-stage grid-connected PV system. In this study, the nonlinear I–V characteristic of the PV array is linearized around the operating point. The nonlinear dynamic of the maximum power point tracking controller is divided into two parts of continuous and discrete. For the continuous part, the common small-signal linearization is applied, while for the discontinuous part, a... 

Dielectric scattering particles have widely been used as embedded scattering elements in dye-sensitized solar cells (DSCs) to improve the optical absorption of the device. Here we systematically study rodlike and spherical core-shell silica@Ag particles as more effective alternatives to the dielectric scattering particles. The wavelength-scale silica@Ag particles with sufficiently thin Ag shell support hybrid plasmonic-photonic resonance modes that have low parasitic absorption losses and a broadband optical response. Both of these features lead to their successful deployment in light trapping in high-efficiency DSCs. Optimized rodlike silica@Ag@silica particles improve the power conversion... 

Solar energy will make a valuable contribution for power generation in the future. However the intermittency of solar energy has become an important issue in the utilization of PV system, especially small scale distributed solar energy conversion systems. The issue can be addressed through the management of production and storage of the energy in the form of hydrogen. The hydrogen can be produced by solar photovoltaic (PV) powered electrolysis of water. The amount of transferred energy to an electrolyzer from a PV module is a function of the distance between maximum power points (MPP) of PV module and the electrolyzer operating points. The distance can be minimized by optimizing the number... 

Energy and environment crises motivated scientists to develop sustainable, renewable, and clean energy resources mainly based on solar hydrogen. For this purpose, one main challenge is the low cost flexible substrates for designing earth abundant efficient cocatalysts to reduce required water oxidation overpotential. Here, a systematic morphological and electrochemical study has been reported for cobalt oxide/hydroxide nanoflakes simply electrodeposited on four different commercially available substrates, titanium, copper sheet, steel mesh, and nickel foam. Remarkable dependence between the used substrate, morphology, and electrocatalytic properties of nanoflakes introduced flexible porous... 

Herein, we report a double-layer photoanode electrode composed of TiO2 nanoparticles active layer and a mixture of nanoparticles and newly proposed skein-like nanotubes (NTs) top layer. Such structure performs well in solar light harvesting due to first, the top layer exhibits superior light scattering and second, the active layer with high dye-loading can make better use of the back-scattered light. The results reveal that 30-40 nm nanoparticles have anatase structure, whereas 5-7 μm skein-like NTs show a mixture of anatase and rutile phases. Photovoltaic measurements demonstrate that by tuning mass ratio between nanoparticles and skein-like NTs, the cells based on single-layer photoanode... 

In the present work, effects of height, length, and width of a single-slope basin-type solar still on its distillate production was investigated. For this purpose, a radiation model was developed which accounts for the influences of all walls on quantities of received solar radiation by the base and saline water of the still. Moreover, in this radiation model, the side walls of the still were considered as the trapezoid and the diffuse as well as beam components of solar irradiance were separately taken into account for the first time. Abilities of the present model were compared with earlier ones. Furthermore, the predictions of the current model were compared with the present experimental... 

In common solar stills, a portion of the produced vapor undesirably condenses on the sidewalls and runs down to be mixed with saline water in the basin. This results in lower distillate output of the system. The aim of this study was to improve the condensation process of a solar still without complicating its structure to collect the water condensed on sidewalls. The proposed solar still was made of two containers nested one inside the other such that the smaller container, containing saline water, fitted easily into the larger container. There was a thin gap between the two in which condensed liquid on sidewalls, ran down and was collected from the bottom of the larger container. The... 

Enhancing stability against photocorrosion and improving photocurrent response are the main challenges toward the development of cupric oxide (CuO) based photocathodes for solar-driven hydrogen production. In this paper, stable and efficient CuO-photocathodes have been developed using in situ materials engineering and through gold-palladium (Au-Pd) nanoparticles deposition on the CuO surface. The CuO photocathode exhibits a photocurrent generation of ∼3 mA/cm2 at 0 V v/s RHE. Time-of-flight secondary ion mass spectrometry (TOF-SIMS) analysis and X-ray spectroscopy (XPS) confirm the formation of oxygen-rich (O-rich) CuO film which demonstrates a highly stable photocathode with retained... 

Today’s the technology based on dye-sensitized solar cells (DSSCs) has an important role in all photovoltaic system technologies. DSSCs can generate electricity with various degrees of transparency; this makes it suitable for use in various industries, especially in construction industry as smart windows. In fact DSSC can produce electricity and having natural light, simultaneously. It is obvious that DSSCs need to absorb solar radiation as much as possible. Since, the effective use of all incident lights leads to an increase in cell efficiency and this increase in efficiency is related to the amount of dye adsorbed on the surface of nanostructured electrode, so higher amount of dye for... 

Modern sensors consist of arrays of detectors specially arranged to enhance precision, capabilities, and field of view (FOV). Sensor arrays can have multiple functionalities, such as the simultaneous detection of position and motion. We use a linear sensor model and develop an optimization method to design an array of photodiodes. Our objective function minimizes bias and variance estimations. We introduce a maximum likelihood technique to approximate and determine the bias caused by measurement errors, and verify our theory by statistically complete simulations. We apply our theory to design an optimal sun sensor. The sensor has a predefined conical FOV, and its accuracy is controlled by a... 

The techno-economic and environmental performance of hybrid solar hydrogen energy systems was investigated to provide combined cooling, heating and power (CCHP) demands of a standalone greenhouse in Iran to achieve sustainable agriculture based on an optimization procedure. From the environmental point of view, by deploying hybrid energy systems, 83%, to 100% of emissions can be avoided. Also a sensitivity analysis was performed on the hybrid energy systems in order to study the effect of major parameter variation on the systems justification. It was concluded that hybrid solar systems are economically competitive with conventional systems, for high solar intensity locations with high diesel... 

In this study, the optimal sizing and performance analysis of a standalone integrated solar power system equipped with different storage scenarios to supply the power demand of a household is presented. One of the main purposes when applying solar energy resource is to face the increasing environmental pollutions resulting from fossil fuel based electricity sector. To this end, and to compare and examine two energy storage technologies (battery and hydrogen storage technology), three storage scenarios including battery only, hydrogen storage technology only and hybrid storage options are evaluated. An optimization framework based on Energy Hub concept is used to determine the optimum sizes... 

Distributed generation (DG) units are often interfaced to the main grid using power electronic converters including voltage-source converters (VSCs). A VSC offers dc/ac power conversion, high controllability, and fast dynamic response. Because of nonlinearities, uncertainties, and system parameters’ changes involved in the nature of a grid-connected renewable DG system, conventional linear control methods cannot completely and efficiently address all control objectives. In this paper, a nonlinear adaptive control scheme based on adaptive backstepping strategy is presented to control the operation of a grid-connected renewable DG unit. As compared to the popular vector control technique, the... 

In this study, a novel idea of storing the latent heat of condensing vapor in solar stills by means of phase change materials (PCMs) as a thermal storage is experimentally investigated. During the daytime, the generated water vapor by the solar energy, is conducted to an external condenser filled with PCM to be condensed. The wasted latent heat is absorbed by PCM and thereby stored. It is worth noting that there is no direct contact between the saline water and the PCM, therefore, the solar energy is not directly stored in the PCM. In the evening, the energy stored in the PCM is transferred as heat to the saline water by heat pipes and enables the desalination process to continue. Several... 

Providing solar hydrogen as a clean energy resource is one of the human challenges for future. Controlling oxygen vacancies as well as surface morphology in metal oxide semiconductors enables developing PEC H2production in some understood ways. Here, the influence of simple change in annealing atmosphere, air and pure oxygen, on photoresponse of nanocrystalline WO3has been studied completely. Results revealed that such slight change in annealing procedure increases effective surface interface and donor density by 77 and 72%, respectively. These effects and also retarding recombination of photogenerated electro-hole pair resulted in photocurrent enhancement under solar like illumination more... 

Today, energy crises attracted many researchers’ attention to renewable energy technologies especially photovoltaic (PV) systems. The main challenge of PV systems is unpredictable nature of solar power generation. To overcome this challenge, a storage system is integrated which reduces demand reliance on electricity grid and uses excess energy that solar panels produce. As investment cost of the storage system is considerable, finding an optimal technology, size, and configuration are crucial. In this paper, the optimal battery system is excluded from existing PV plant installing in a commercial building located in Mashhad/Iran. Here, the sizing procedure is based on a financial evaluation... 

The use of solar energy concentration systems for achieving performance enhancements in the Photovoltaic/thermal hybrid solar systems and reduction of initial costs is an idea that has been studied for years. In this article a new structure for parabolic trough photovoltaic/thermal collector is proposed and its thermal and electrical performances are experimentally investigated. The receiver of this concentrator contains a triangular channel with an outer surface covered with photovoltaic cells and thermoelectric modules with a specific arrangement so that in addition to absorbing heat, a larger portion of the solar radiation is directly converted to electricity. Hence, the performance of... 

In this paper, a new control strategy and power management for a stand-alone PV/battery hybrid power system has been suggested. The solar cell arrays provide energy in the steady-state and the battery provides energy in transient states. Here, a charge controller system based on the MPP tracking technology, suitable for using in the islanded micro grid that contains a solar panel and a battery is designed. The charge controller includes a unidirectional DC-DC converter as an interface circuit between the solar panel and the DC bus, a bidirectional DC-DC converter as an interface circuit between the battery and the DC bus with a control system and power management in different states of... 

We investigate short-term non-linearity of solar irradiance fluctuations using the multifractal detrended fluctuation analysis (MFDFA). The MFDFA shows that time series of solar irradiance have a long range correlation function with a multifractal behavior. We apply this method to solar irradiance time series from several regions around the world with resolutions of seconds and minutes. The obtained generalized Hurst and Renyi exponents h(q) and τ(q) suggest the non-linear and non-stationary essence of measured irradiance time series. Also, we analyze shuffled, random phase, and rank-wised surrogated data to reveal the nature of the multifractality and conclude that linear and non-linear...