Sharif Digital Repository

Today, energy crises attracted many researchers’ attention to renewable energy technologies especially photovoltaic (PV) systems. The main challenge of PV systems is unpredictable nature of solar power generation. To overcome this challenge, a storage system is integrated which reduces demand reliance on electricity grid and uses excess energy that solar panels produce. As investment cost of the storage system is considerable, finding an optimal technology, size, and configuration are crucial. In this paper, the optimal battery system is excluded from existing PV plant installing in a commercial building located in Mashhad/Iran. Here, the sizing procedure is based on a financial evaluation... 

The fabrication of high performance, solution-processed CIGS family solar cells is based on high-temperature crystallization processes in chalcogen-containing atmosphere and/or using dangerous solvents like hydrazine. The non-hydrazine sulfurization- and selenization-free reports typically suffer from poor grain structures. We report a facile strategy to overcome grain growth limitations at very low temperature processing (250 °C). Selenium free Superstrate configuration CuInS2 (CIS) solar cells are fabricated using a nanocrystals ink which avoiding from high temperature selenization or/and sulfurization is targeted. We investigated the effect of intentional M doping (M = Sb, Zn, Cd and Sn)... 

Nowadays, fossil fuel limitations and environmental concerns push researchers to find clean and renewable energy resources. Solar hydrogen production via water splitting reactions in electrochemical and/or photo-electrochemical systems has been accepted as a promising route and efficient electrocatalysts are involved in both. Here, cobalt nanoflakes with an oxide/hydroxide surface and a conductive metallic core are grown on commercially available steel mesh modified with carbon based nanocomposites as a support layer. The portion of reduced graphene oxide sheets was changed from 0 to 100 wt% and the correlation of this concentration with the surface morphology and electro-catalytic activity... 

Thin-film solar cells based on hybrid organo-halide lead perovskites achieve over 22% power conversion efficiency (PCE). A photovoltaic technology at such high performance is no longer limited by efficiency. Instead, lifetime and reliability become the decisive criteria for commercialization. This requires a standardized and scalable architecture which does fulfill all requirements for larger area solution processing. One of the most highly demanded technologies is a low temperature and printable conductive ink to substitute evaporated metal electrodes for the top contact. Importantly, that electrode technology must have higher environmental stability than, for instance, an evaporated silver... 

Parabolic trough solar collector (PTC) is one of the most mature and widely used type of solar energy harnessing devices. Therefore, investigation of the effect of various operational conditions on the overall efficiency of these devices has been topic of substantial interest in the recent decade. Moreover, utilization of nanoparticles as a useful additive to the working fluid should be examined thoroughly to optimize the collector's outputs. To do so, in the present study, energy and exergy efficiencies of a typical PTC as a function of several involving parameters are numerically calculated. These parameters are nanoparticle volume fraction (from 0 to 5 percent), environment wind speed... 

Pulsating heat pipes (PHPs) are compact cooling equipment used for various applications. This type of heat pipes can be used in renewable energy systems, cooling electronic devices, heat recovery systems and many other applications. Since PHPs have superior thermal performance, by applying them in energy systems enhance their efficiency. In addition, PHPs are a reliable medium for cooling various devices which have high heat flux. In this study, various works conducted on the applications of PHPs are reviewed and analyzed. It is concluded that PHPs are efficient and reliable devices for utilization in various energy systems. Moreover, at very low temperatures, such as cryogenic applications,... 

All current highest efficiency perovskite solar cells (PSCs) use highly toxic, halogenated solvents, such as chlorobenzene (CB) or toluene (TLN), in an antisolvent step or as solvent for the hole transporter material (HTM). A more environmentally friendly antisolvent is highly desirable for decreasing chronic health risk. Here, the efficacy of anisole (ANS), as a greener antisolvent for highest efficiency PSCs, is investigated. The fabrication inside and outside of the glovebox showing high power conversion efficiencies of 19.9% and 15.5%, respectively. Importantly, a fully nonhalogenated solvent system is demonstrated where ANS is used as both the antisolvent and the solvent for the HTM.... 

Recent investigations on multifunctional piezoelectric semiconductors have shown their excellent potential as photovoltaic components in high-efficiency third-generation quantum nanostructure (QNS) solar cells. The current work is devoted to studying the electro-elastic behavior of high-density QNS photovoltaic semiconductors within which initial mismatch strains of arrays of quantum dots (QDs) or quantum wires (QWRs) induce coupled electro-mechanical fields. The inter-nanostructure couplings which are of great importance in high-density QNS arrays are incorporated in the presented analytical framework. In practice, QNSs with different geometries such as spherical, cuboidal, or pyramidal QDs... 

We proposed two different time-dependent modeling approaches for variation of device characteristics of perovskite solar cells under stress conditions. The first approach follows Sah-Noyce-Shockley (SNS) model based on Shockley–Read–Hall recombination/generation across the depletion width of pn junction and the second approach is based on thermionic emission model for Schottky diodes. The connecting point of these approaches to time variation is the time-dependent defect generation in depletion width (W) of the junction. We have fitted the two models with experimental data reported in the literature to perovskite solar cell and found out that each model has a superior explanation for... 

Herein, we report the impact of light scattering mechanism on photovoltaic and photoelectrochemical performance of dye-sensitized solar cell (DSC) devices composed of TiO2 nanoparticles and hollow cubes. DSCs are designed by two different light scattering modes (i.e., mode I in form of single layer electrode containing nanoparticles and hollow cubes and mode II in the form of double layer electrode comprising active and scattering layers made of nanoparticles and mixtures of nanoparticles and hollow cubes, respectively). The synthesized anatase-TiO2 hollow cubes (200–400 nm) and nanoparticles (15–30 nm) are employed to enhance the optical length and light harvesting of photoanodes,... 

In the past few years, organic–inorganic metal halide ABX3 perovskites (A = Rb, Cs, methylammonium, formamidinium (FA); B = Pb, Sn; X = Cl, Br, I) have rapidly emerged as promising materials for photovoltaic applications. Tuning the film morphology by various deposition techniques and additives is crucial to achieve solar cells with high performance and long-term stability. In this work, carbon nanoparticles (CNPs) containing functional groups are added to the perovskite precursor solution for fabrication of fluorine-doped tin oxide/TiO2/perovskite/spiro-OMeTAD/gold devices. With the addition of CNPs, the perovskite films are thermally more stable, contain larger grains, and become more... 

The solar to electric power conversion efficiency (PCE) of perovskite solar cells (PSCs) has recently reached 22.7%, exceeding that of competing thin film photovoltaics and the market leader polycrystalline silicon. Further augmentation of the PCE toward the Shockley-Queisser limit of 33.5% warrants suppression of radiationless carrier recombination by judicious engineering of the interface between the light harvesting perovskite and the charge carrier extraction layers. Here, we introduce a mesoscopic oxide double layer as electron selective contact consisting of a scaffold of TiO2 nanoparticles covered by a thin film of SnO2, either in amorphous (a-SnO2), crystalline (c-SnO2), or... 

An experimental study was conducted on a solar hybrid system to transform the waste heat of photovoltaic module (PV module) into a useful heat which could be used in a solar desalination (SD) system in order to produce freshwater (scenario 1). Then, different parameters such as the amount of the produced freshwater by condensed vapor on the glass cover and basin side walls were taken into consideration after the fabrication of the SD system. Furthermore, the effect of water depth in the tray and the effect of the presence of a fan inside the basin (scenario 3) on water yield (kg/m2hr) were evaluated. In addition, the effects of using a mirror to lead the reflected light on the PV module and... 

This paper addresses a low complexity and high efficient cooling system applicable on photovoltaic (PV) system leading to enhance electrical efficiency and provide preheated water. The developed system consists of a photovoltaic panel, a cooling water system establishing a uniform surface temperature, and a solar water heater. According to the proposed system characteristics, the setup is constructed based on a single mono-crystalline solar panel to absorb more solar radiation intensity and generate more electrical energy per area in compare to a poly-crystalline panel. The preheated water produced by absorbed heat from the photovoltaic is conducted to a solar water heater to satisfy... 

The effect of substitutional Li doping into NiOx hole transporting layer (HTL) for use in inverted perovskite solar cells was systematically studied. Li doped NiOx thin films with preferential crystal growth along the (111) plane were deposited using a simple solution-based process. Mott-Schottky analysis showed that hole carrier concentration (NA) is doubled by Li doping. Utilizing 4 % Li in NiOx improved the power conversion efficiency (PCE) of solar devices from 9.0 % to 12.6 %. Photoluminescence quenching investigations demonstrate better hole capturing properties of Li:NiOx compared to that of NiOx, leading to higher current densities by Li doping. The electrical conductivity of NiOx is... 

N-annulated perylene based materials show outstanding and tunable optical and physical properties, making them suitable to be charge transport materials for optoelectronic applications. However, this type of materials has so far not been well studied in solar cells. Here, we develop a new hole transport material (HTM), namely S5, based on perylene building block terms, for organic-inorganic hybrid perovskite solar cells (PSCs). We have systematically studied the influences of the film thickness of S5 on their photovoltaic performance, and a low concentration of S5 with a thinner HTM film is favorable for obtaining higher solar cell efficiency. S5 shows excellent energy alignment with... 

This paper reports on the synthesis of ZnO nanowires (NWs), as well asthe compound nanostructures of nanoparticles (NPs) and nanowires (NWs+NPs) with different coating layers of NPs on the top of NWs and their integration in dye-sensitized solar cells (DSSCs). In compound nanostructures, NWs offer direct electrical pathways for fast electron transfer, and the NPs of ZnOdispread and fill the interstices between the NWs of ZnO, offering a huge surface area for enough dye anchoring and promoting light harvesting. A significant photocurrent density of 2.64mA/cm2 and energy conversion efficiency of 1.43% was obtained with NWs-based DSSCs. The total solar-to-electric energy conversion efficiency... 

Photovoltaic energy is one of the clean and efficient energies which has been developing quickly in the last years. As the penetration of solar plants is increasing in the electricity network, new problems have arisen in network operation. This paper models a high penetration factor of solar energy in the electricity network and investigates the impact of solar energy growth on both the generation schedule of different power plants and in the natural gas transmission network. Fuel management of gas power plants is modeled through simulation of the natural gas transmission network. To this end, an increase in the penetration of solar energy in the electricity network inevitably leads to a... 

Global warming escalation has extended average temperature of earth beyond its safe limit. To avert this environmental-threat, solar energy has acquired substantial attention of remarkable researchers in this century. To effectively utilize solar energy by transforming into thermal and electrical energy, the involvement of nanofluids having intensified thermal, optical and magnetic properties, has become very popular. The foremost objective of this article is to provide a comprehensive review on the applications of nanofluids in solar energy systems like solar collectors, photovoltaic cells, solar stills, and thermal energy storage, which are thoroughly discussed in this paper. The effect of... 

One of the primary factors affecting the amount of worldwide energy consumption and greenhouse gas emissions is cooking. Solar cooking is an appropriate solution because it is both inexpensive and expandable. To illustrate modern advancements and the current status of solar cooking technology, this paper presents a review of recent experimental and analytical socioeconomic studies on solar cookers. The experimental studies have been divided into three categories based on different solar cooker structures: (i) box types, (ii) concentrating types, and (iii) panel types. Next, different designs are investigated according to their direct or indirect heat transfer modes and optional equipment for...