Sharif Digital Repository

In this study, a series of heteroatoms including nitrogen, oxygen, and sulfur were added to different positions of the model asphaltene structure to study the effect of the heteroatom presence in the self-aggregation of the model asphaltenes. Molecular Dynamics was used to calculate Solubility Parameters, Radial Distribution Function, and Relative Solubility Parameters. Additionally, Reactivity Parameters, Electrostatic Potential, Reduced Density Gradient, and Independent Gradient Model were calculated using the Density Functional Theory to further investigate the Molecular Dynamics results. This study indicated that heteroatoms' diversity and their positions in the model asphaltene... 

A film composed of carbon nanoparticles and poly(diallyldimethylammonium chloride) or CNP-PDDAC is formed in a layer-by-layer deposition process at tin-doped indium oxide (ITO) substrates. Excess positive binding sites within this film in aqueous phosphate buffer at pH 9.5 are quantified by adsorption of iron(III)phthalocyanine tetrasulfonate and indigo carmine. Both anionic redox systems bind with Langmuirian characteristics (K ≈ 105 mol-1 dm3) and show electrochemical reactivity throughout the film at different thicknesses. Therefore, the electrical conductivity in CNP-PDDAC films is good and the positive binding sites are approximately 140 pmol cm-2 per layer. Structural instability of... 

In this study, collagen/chitosan membrane used for guided bone regeneration (GBR) was modified. Collagen and chitosan are routinely used in GBR membrane fabrication. In addition advanced platelet rich fibrin (A-PRF) is a promising substitution for fabricating membrane in dental surgery. Herein, acid soluble collagen from calf skin was extracted and characterized. The combination of A-PRF with collagen/chitosan membrane was investigated in this study. FTIR analysis revealed that chemical crosslinking using EDC/NHS was occurred. The morphology of collagen/chitosan membrane in a gradient manner of chitosan was assessed via SEM images. Response surface methodology (RSM) was used to... 

Citric acid was polymerized onto the surface of functionalized multiwall carbon nanotubes (MWCNTCOOH) and MWCNT-graft-poly(citric acid) (MWCNTg-PCA) hybrid materials were obtained. Due to the grafted poly(citric acid) branches, MWCNT-g-PCA hybrid materials not only were soluble in water but also were able to trap water soluble metal ions. Reduction of trapped metal ions in the polymeric shell of MWCNT-g-PCA hybrid materials by reducing agents such as sodium borohydride led to encapsulated metal nanoparticles on the surface of MWCNT. Herein palladium nanoparticles were encapsulated and transported by MWCNT-g-PCA hybrid materials (MWCNT-g-PCA-EPN) and their application as nanocatalyst toward... 

In the present study, an aqueous root-extract of Acanthophyllum laxiusculum (AREAL) was evaluated for phenanthrene removal from two samples of contaminated soil. AREAL showed a linear solubilization enhancement for phenanthrene with a weight solubilization ratio of 0.05. Batch soil washing experiments caused the removal of phenanthrene with efficiencies of 96.7% and 78% from soils with 0.78% and 2.73% organic carbon, respectively. Desorption kinetics of phenanthrene exhibited a twophase pattern, namely, a rapid release as the initial phase and a slower removal as a subsequent phase. A two-compartment exponential model could adequately represent the two phases of the kinetic pattern of... 

In this study, degradation of trichloroethylene (TCE), a chlorinated hydrocarbon, using starch supported Fe/Ni nanoparticles was investigated. The scanning electron microscope images showed applying water soluble starch as a stabilizer for the Fe/Ni nanoparticles tended to reduce agglomeration and discrete particle. Also the mean particle diameter reduced from about 70 nm (unsupported Fe/Ni nanoparticle) to about 30 nm. Effects of three key independent operating parameters including initial TCE concentration (10.0-300.0 mg L-1), initial pH (4.00-10.00) and Fe0 dosage (0.10-2.00) g L-1 on TCE dechlorination efficiency in 1 hour were analysed by employing response surface methodology (RSM).... 

Interfacial tension (IFT) as one of the main properties for efficient CO2 flooding planning in oil reservoirs depends strongly on pressure, temperature, and composition of the reservoir fluids. Therefore, it is important to measure this property at real reservoir conditions for successful field development plan. In this study, an axisymmetric drop shape analysis (ADSA) has been utilized to measure the equilibrium IFTs between crude oil and CO2 at different temperatures and pressures. Moreover, minimum miscibility pressures (MMP) and first-contact miscibility pressures (P max) of crude oil/CO2 systems at different temperatures are determined by applying the vanishing interfacial tension (VIT)... 

Minimum Miscibility Pressure (MMP) is regarded as one of the foremost parameters required to be measured in a CO2 injection process. Therefore, a reasonable approximation of the MMP can be useful for better development of injection conditions as well as planning surface facilities. In this study, the impact of asphaltene content ranging from 3.84 % to 16 % on CO2/heavy oil MMP is evaluated. In this respect, slim tube miscibility and Vanishing Interfacial Tension (VIT) tests are used. Regarding the VIT test, the Interfacial Tension (IFT) is measured by means of two methods including pendant drop and capillary apparatuses, and thereafter the MMP measurement error between slim tube and VIT... 

The requirement of reliable relative permeability data is more intensified when the miscibility condition approaches. In this work the relative permeability of CO2 and oil has been measured at different miscibility conditions using conventional methods. Fractured dolomite and sandstone core plugs samples were used in the experiments. Due to some errorful assumptions of conventional methods such as immiscible, incompressible displacement, inverse modeling was used for predicting the reliable relative permeability of oil and gas phases at near miscible condition from measured oil production and pressure drop data. The initial guesses of relative permeabilities were provided from conventional... 

Practical designs of non-aqueous phase liquids (NAPLs) remediation strategies require reliable modeling of interphase mass transfer to predict the retraction of NAPL during processes such as dissolution. In this work, the dissolution process of NAPL during two-phase flow in heterogeneous porous media is studied using pore-network modeling and micromodel experiments. A new physical-experimental approach is proposed to enhance the prediction of the dissolution process during modeling of interphase mass transfer. In this regard, the normalized average resident solute concentration is evaluated for describing the dissolution process at pore-level. To incorporate the effect of medium... 

In this research, organic solvent composed of hexane and methanol was used for lipid extraction from dry and wet biomass of Chlorella vulgaris. The results indicated that lipid and fatty acid extraction yield was decreased by increasing the moisture content of biomass. However, the maximum extraction efficiency was attained by applying equivolume mixture of hexane and methanol for both dry and wet biomass. Thermodynamic modeling was employed to estimate the effect of hexane/methanol ratio and moisture content on fatty acid extraction yield. Hansen solubility parameter was used in adjusting the interaction parameters of the model, which led to decrease the number of tuning parameters from 6... 

Objective(s): Bioresorbable scaffolds have been advocated as the new generation in interventional cardiology because they could provide temporary scaffolds and then disappear with resorption. Although, the available stents in clinical trials exhibited biosafety, efficacy, no death, and no apparent thrombosis, Mg-substrate degradation on drug release has not been investigated. Materials and Methods: Therefore, more research has been needed to legitimize the replacement of current stents with Mg-based stents. UV-Vis spectrophotometer, scanning electron microscope (SEM), X-ray diffraction (XRD), pH measurement, H2 evolution, and corrosion tests determined the change in hybrid properties and... 

This investigation aims at understanding the underlying fundamentals of the isothermal solidification phenomenon during the transient liquid phase (TLP) bonding process. The isothermal solidification is governed by solid-state diffusion of the melting point depressant (MPD) into the base material, which, in turn, is controlled by both kinetic and thermodynamic parameters; however, the latter factor is generally ignored. In this work, the competition between kinetics and thermodynamics of diffusion were considered in TLP bonding of a nickel alloy, Monel 400, using two distinct filler metals including pure copper (Cu) and Ni-Si-B filler metal. The joint generated by Ni-Si-B filler metal... 

In this paper, the effect of ozone on membrane fouling of membrane bioreactor (MBR) systems was investigated. Sludge specification such as soluble microbial product (SMP), extracellular polymeric substance (EPS), viscosity, particle size distribution (PSD), microscopic observations and sludge volume index (SVI) in presence of ozone were determined. Further, EPS, Fourier-transform infrared (FTIR) analysis, excitation-emission matrix (EEM) fluorescence spectroscopy, and gel permission chromatography (GPC) are considered to determine cake layer characteristics. The results indicated COD removal did not show significant difference with ozonation. Ozone also increases the particle size and... 

Reliable relative permeability curves of oil-gas systems are important for successful simulation and modeling of gas injection, especially when the miscibility condition approaches. In this work, the relative permeability of a CO2-light oil system has been measured under different conditions, using the Civan and Donaldson (1989) [13] method. Dolomite and sandstone core samples were used in the experiments. The minimum miscibility pressure was calculated using an empirical correlation, as well as slim-tube simulation. Due to some controversial assumptions of the Civan and Donaldson method, such as immiscible and incompressible displacement, history matching was used for predicting the... 

In this research, low density polyethylene (LDPE) and poly(ethylene-co-vinyl acetate) (EVA) were used as polymeric materials. The methods used to produce LDPE and EVA was film blowing and thermal-dry phase inversion. The amount of permeability, diffusivity and solubility of O2 and CO2 through above polymers were obtained and also the effect of temperature, pressure and film thickness for LDPE was measured. To study film cross-section morphology in EVA, scanning electron microscopy (SEM) was applied. The results showed that the amount of permeability and solubility were decreased by increasing film thickness but diffusivity was increased. However, by increasing temperature, permeability,... 

In this research, low density polyethylene (LDPE) and poly ethylene-co-vinyl acetate (EVA) were used as polymeric materials. The methods used to produce LDPE and EVA was Film Blowing and ThermalDry Phase Inversion. The amount of permeability, diffusivity and solubility of O2 and CO2 through above polymers were obtained and also the effect of temperature, pressure and film thickness for LDPE was measured. The Barometric method was considered and measurements were based on ASTM standard. To study film cross-section morphology in EVA, Scanning Electron Microscopy (SEM) was applied. From results we considered that the amount of permeability and solubility were decreased by increasing film... 

Comprehensive structural/molecular simulations have been undertaken to study the poly(benzimidazoles) (PBI) membrane combined with four different nano-oxide materials (ZnO, Al2O3, SiO2 and TiO2) for purification and production of hydrogen from natural gases. Composite membranes were built with different amounts of nano-oxide materials to investigate the influence of nano-oxide content on the PBI membrane performance. Several structural characterizations such as FFV, WAXD and also a thermal one (glass transition temperature) were done to study the structural properties of all simulated membrane cells. Moreover, MSD and adsorption isotherms tasks were used to estimate the diffusivity and... 

In this work, a novel carrier based-on modified graphene oxide was designed for co-delivery of hydrophobic and hydrophilic anticancer drugs (curcumin (Cur) and doxorubicin (DOX) as the model of drugs). The hydroxyl groups at the edges of graphene oxide (GO) sheets were used as the initiation sites for growing poly(epichlorohydrin) (PCH) chains. Then, hyperbranched polyglycerol (HPG) was grafted on the hydroxyl end groups of PCH (PCH-g-HPG). Pendant chlorines in the main chain of GO-PCH-g-HPG were replaced with hydrazine. The modification of GO sheets with oxygen-rich polymers increased water solubility of graphene oxide. Doxorubicin was loaded onto the nanocarrier by covalent bonding with... 

In this study, the potential of using MIL-100(Fe) metal–organic framework (MOF) for loading and controlling the release of dacarbazine (DTIC) was evaluated for in vitro treatment of melanoma. The drug loading was performed during the green synthesis of MIL-100(Fe) in an aqueous media without using any harmful solvents, to obtain MIL-DTIC. The surface of this structure was then coated with polyethylene glycol (PEG) in the same aqueous solution to synthesize MIL-DTIC-PEG. The synthesized samples were characterized using various methods. Their release profile was studied in phosphate-buffered saline (PBS) and simulated cutaneous medium (SCM). The cytotoxicity of DTIC and its nano-MOF...