Sharif Digital Repository

Spontaneous imbibition of water into the matrix blocks because of capillary forces is an important recovery mechanism for oil recovery from naturally fractured reservoirs. In modeling this process, it has been assumed classically that local equilibrium is reached and, therefore, capillary pressure and relative permeability functions are only a function of water saturation, resulting in the appearance of the self-similarity condition. In some works published in the last 2 decades, it has, however, been claimed that local equilibrium is not reached in porous media, and therefore, opposite the classical local-equilibrium/self-similar approach, non-equilibrium effects should be taken into... 

Spontaneous imbibition of water into the matrix blocks because of capillary forces is an important recovery mechanism for oil recovery from naturally fractured reservoirs. In modeling this process, it has been assumed classically that local equilibrium is reached and, therefore, capillary pressure and relative permeability functions are only a function of water saturation, resulting in the appearance of the self-similarity condition. In some works published in the last 2 decades, it has, however, been claimed that local equilibrium is not reached in porous media, and therefore, opposite the classical local-equilibrium/self-similar approach, non-equilibrium effects should be taken into... 

Spontaneous imbibition, defined as the displacement of nonwetting phase by wetting phase in porous media by action of capillary forces, is important in many applications within earth sciences and in particular in naturally fractured oil and gas reservoirs. Hence, it is critical to investigate the various aspects of this process to correctly model the fractured reservoir behavior. In this study, twenty four experiments were conducted to study the effect of rock properties, lithology of porous medium, brine viscosity and boundary conditions on displacement rate and final recovery by cocurrent spontaneous imbibition (COCSI) in brine-oil systems. The results can be extended to brine-gas systems,... 

A large amount of the discovered oil reserves are reserved in carbonate formations, which are mostly naturally fractured oil-wet. Wettability alteration towards more water-wet state reduces the capillary barrier, hence improving the oil recovery efficiency in such reservoirs. In this study, wettability alteration towards favorable wetting state was investigated by combining modified low salinity brine with surfactant during water flooding. The diluted brine was modified by increasing the concentration of Mg2+ and SO4 2−, individually as well as both ions in combination. Different brine formulations were tested experimentally through the observations of contact angle measurements and... 

Recently, wettability alteration has been much attended by researchers for studying well productivity improvement in gas condensate reservoirs. Previous studies in this area only utilized water/alcohol based chemicals for this purpose. While, hydrocarbon nature of the blocked condensate in retrograde gas reservoirs, may motivate application of hydrocarbon based chemical agents. In this study, a new hydrocarbon based wettability modifier is introduced to alter wettability of carbonate and sandstone rocks to preferentially gas wetting condition. Static and dynamic contact angle measurements, spontaneous imbibition and core flooding tests were conducted to investigate the effect of proposed... 

Spontaneous imbibition is well-known to be one of the most effective processes of oil recovery in fractured reservoirs. However, the detailed pore-scale mechanisms of the counter-current imbibition process and the effects of different fluid/rock parameters on this phenomenon have not yet been deeply addressed. Thiswork presents the results of a newpore-level numerical study of counter-current spontaneous imbibition, using coupled Cahn-Hilliard phase field and Navier-Stokes equations, solved by a finite element method. A 2D fractured medium was constructed consisting of a nonhomogeneous porous matrix, in which the grains were represented by an equilateral triangular array of circles with... 

Condensate and water banking around gas condensate wells result in vital well deliverability issues. Wettability alteration of near wellbore region to gas wetting condition is known to be the most novel and the only permanent method, to improve condensate well productivity. In this work, a water based nanofluid is used to change the wettability of sandstone reservoir rocks from strongly liquid wetting to intermediate gas wetting condition. Static contact angle measurements demonstrated significant increase of liquid phase contact angle as a result of chemical treatment with SurfaPore M nanofluid. The characteristics of SurfaPore M adsorption on sandstone rock are quantified through kinetic... 

In order to understand the potential role of divalent ions involved in smart water, fluid-fluid and rock-fluid interactions are studied through contact angle and interfacial tension (IFT) measurements. Then, the suitable brines in changing contact angle and IFT are brought into measurement with spontaneous imbibition experiments to evaluate the co-impact of fluid-fluid and rock-fluid interactions. The results show the importance of SO42− ions during smart water injection as removing them from the injection water leads to a sharp drop in ultimate oil recovery. Accordingly, when the concentration of SO42− within the injection water increases four times, 10% ultimate oil recovery is recovered.... 

There are increasing evidences that adjusting the chemistry of the injecting water improves the oil recovery efficiency. However, the underlying mechanisms for this technique which is referred to as "smart waterflood" have not yet been thoroughly understood. It is needed to explore the role of individual ions through set of different tests, to find the right mechanisms behind "smart waterflood". This study is focused on the fluid/solid (carbonate) interactions through systematic wettability measurement. Contact angle measurements accompanied by spontaneous imbibition tests were employed to determine the role of individual monovalent and divalent ions in wettability alteration process by... 

A Green Element numerical formulation is used to solve the time-dependent nonlinear one-dimensional counter-current spontaneous imbibition diffusion equation in which water enters a water wet rock spontaneously while oil escapes by flowing in the opposite direction. The Green Element Method (GEM) is an element by element approach of the boundary element method. In this new method, by generating large sparse global matrices and yet taking advantage of properties of Green's function, solution of more complicated physical problem is achievable while at the same time much less computational effort is needed rather than boundary element method (BEM). By discretizing both the boundary and problem... 

Including gravity and wettability effects, a full analytical solution for the frontal flow period for 1D counter-current spontaneous imbibition of a wetting phase into a porous medium saturated initially with non-wetting phase at initial wetting phase saturation is presented. The analytical solution applicable for liquid-liquid and liquid-gas systems is essentially valid for the cases when the gravity forces are relatively large and before the wetting phase front hits the no-flow boundary in the capillary-dominated regime. The new analytical solution free of any arbitrary parameters can also be utilized for predicting non-wetting phase recovery by spontaneous imbibition. In addition, a new...