Sharif Digital Repository

In this paper, a new configuration of a solar combined cooling, heating, and power (CCHP) system is proposed to recover the waste thermal energy of a steam power plant, which provides the cooling and heating needs of an apartment complex located in Tehran. The required energy of the system is supplied by the parabolic trough solar collectors (PTCs) and, if necessary, an auxiliary heater is also used. An ejector refrigeration cycle (ERC) and a steam Rankine cycle are used for cooling and power generation, respectively. The cycle is dynamically modeled over a year using a TRNSYS-EES co-simulator. It is found that the highest Rankine cycle efficiency is obtained in the cold months (January)... 

One of the main issues of wastewater treatment is the silica deposition in steam turbines. Evaporation of silica with the steam in adequate concentration is one of the main sources of scale formation in steam turbines. In this study, the authors introduce the utilization of a genetic-based approach—gene expression programming (GEP)—for solubility prognostication of the silica in superheated steam of boilers with respect to water silica content and pressure. The result of GEP mathematical approach is a new algebraic formula to achieve our goals. Developed model predicts the silica solubility in the range of 0.8–22.1 MPa and 1–500 mg/kg for pressure and boiler water silica content,... 

The production of reducing gas is usually a bottleneck to capacity increase in direct reduction plants. Modelling and simulation of reducing gas production result in better design and operation of these plants. In the present work, a mathematical model is discussed that relates to a Midrex reformer, which is different from conventional steam reformers in some respects. Both process side and furnace side have been included in an integrated model. Simulation results have been tested against available data from an actual plant. The model predictions have been found to be reasonably accurate. The effects of three process variables, feed gas temperature, feed gas pressure and excess air, on... 

In this paper, a novel method of retrofit design in total site cogeneration systems based on constructal theory is presented. In this regard, the total site cogeneration system is decomposed into three constructs: turbines, turbine arrays, and steam generators. The objective function to be minimised is the total annual cost of existing total site. Using constructal theory simplifies the optimisation procedure of total site in addition to reaching better conceptual design especially in more sophisticated systems. A case study from literatures has been taken up to examine the applicability of the algorithm and excellent agreement has been observed. Copyright  

Mechanical alloying and hot extrusion techniques were employed to produce in-situ fully dens Al-Ti composites without applying any heat treatment. The focus of this study is the investigation of fracture toughness in produced composites in order to improve it and to explain the mechanisms responsible for the fracture. The morphology of milled powders was studied by Scanning Electron Microscopy (SEM). The microstructure of the extruded composites was examined by Optical Microscopy (OM) and Field Emission Scanning Electron Microscopy (FESEM). Moreover, the density and hardness of samples were investigated. Three point bending test of the single edge notched beam (SENB) samples was applied to... 

This paper deals with the development of a qualified thermal-hydraulic nodalization for modeling Station Black-Out (SBO) accident in PSB-VVER Integral Test Facility (ITF). This study has been performed in the framework of a research project, aiming to develop an appropriate accident management support tool for Bushehr nuclear power plant. In this regard, a nodalization has been developed for thermal-hydraulic modeling of the PSB-VVER ITF by MELCOR integrated code. The nodalization is qualitatively and quantitatively qualified at both steady-state and transient levels. The accuracy of the MELCOR predictions is quantified in the transient level using the Fast Fourier Transform Base Method... 

In this study, lamination as extrinsic mechanism was considered to enhance damage tolerance of three-layer Al6061-5%vol. SiCp/Al1050/Al6061-5%vol. SiCp composites. To fabricate laminates of dissimilar interfacial adhesion, different rolling strains were applied during hot roll-bonding. The discrepancy in interfacial strength of laminates was examined by shear test while toughness values were studied using three-point bending test. It was revealed that both interfacial adhesion and damage tolerance were influenced by rolling strain. Interfacial bonding played the major role in the energy absorption during fracture which was quantified as initiation, propagation and total toughness. The... 

For the purposes of lowering environmental emission cost and increasing economic profit, energy efficient combined heat and power (CHP) units can be integrated with conventional separate heat and power production units to meet heat and power demands. The goal of this study is to develop and examine a novel heuristic and deterministic optimization algorithm for solving the profit-based unit commitment (PBUC) problem for a generation company with integrated CHP-thermal-heat only system for (i) satisfying demands for heat and power, (ii) selling spinning reserve for power, (iii) reducing environmental CO2 emission cost, and (iv) accounting for valve-point effects for steam turbines. For... 

The main function of a fired heater in a petrochemical site is to produce supersaturated steam. Due to extremely difficult working conditions and high temperatures, there is a very high probability of failures in different parts of a fired heater. In the fired heater under study, tube guides are frequently damaged due to malfunctions and fractures in bolt connections. To investigate the nature of such fractures, Computational Fluid Dynamics (CFD), Finite Element (FE) method, Charpy impact test and fractography were used. To obtain the temperature of various components of the fired heater, a CFD analysis was carried out by considering the combustion process and modeling the central and side... 

Injection of Emergency Core Cooling System (ECCS) water into the primary loops of the Pressurized Water Reactors (PWRs) leads to rapid cooling of Reactor Pressure Vessel (RPV) inside wall after Loss Of Coolant Accident (LOCA). This condition, known as Pressurized Thermal Shock (PTS) intensifies the propagation of the RPV structural defects and would be considered as an ageing mechanism. For structural and fracture analysis of RPV wall, thermal-hydraulic analysis of PTS should be accomplished to obtain the steam/water flow characteristics in the downcomer. For this purpose, simulation of steam/water stratified flow (due to density difference) after the injection point should be done by... 

This work proposes a novel configuration for steam methane reformers (SMR) in order to improve their syngas stoichiometric ratio (SR). This is a decisive element for methanol producers to increase their production tonnage. While the optimum theoretical SR value is around 2, many conventional SMRs operate far beyond this value due to thermodynamic equilibrium limitations. In the new SMR design CO2, which could be an industrial off gas, is injected into the reactor in multiple stages. The corresponding CO2 injection flow rate is determined by a multi-objective optimization method. The optimum flow rate at each stage is chosen to minimise abs (SR-2) while maintaining the CH4 conversion at its... 

Supportless Ni-Pd-0.1CNT foamy nanocatalyst with specific surface area of 611.3 m2/g was produced by electroless deposition of nickel, palladium and multiwall carbon nanotube (MWCNT) on interim polyurethane substrate. Application of temperature programmed reduction (TPR) and temperature programmed oxidation (TPO) data into Kissinger (Redhead) kinetic model showed lessening of their activation energies due to Pd and CNT addition. Presence of foamy Ni/SiC caused 8% higher steam reforming of methane; while Ni-Pd-0.1CNT presence resulted in 22% higher methane conversion. The catalytic behavior of the samples was described by morphological and compositional studies which were carried out by... 

Glycerol might be converted into hydrogen through a catalytic reforming process. In order to design an effective route, the choice of reaction conditions and in particular its medium considered yet a crucial issue still needing further investigations. In this research, a mathematical model of reforming processes in vapor (i.e., steam reforming (SR) and liquid phase (i.e.; aqueous phase reforming (APR)) were developed. This was performed in terms of understudying effects of parameters including the reactor diameter, catalyst morphology (i.e., particle size) and mass flow rate on the glycerol conversion. Then, a superior reaction medium in terms of these variables was determined. For data... 

The effect of strain rate on the ductility of a La-based bulk metallic glass (BMG) over a wide temperature range, and the correlation between ductility and relaxation processes within this alloy are investigated in the present work. The three point bending test and dynamic mechanical analysis are employed to study these phenomena. It is found that the activation energies of the nearly constant loss (NCL) relaxation and intermediate temperature brittleness are almost identical. This observation reveals that the NCL relaxation, as a locally confined or caged dynamics, contributes as the main source of intermediate temperature brittleness in La-based BMGs. © 2018 Elsevier B.V  

This article presents a two-dimensional simulation of the coal gasification in tapered fluidized bed gasifier. The effects of tapered angle, gasifier temperature, velocity of gasifying agent, and steam-to-air ratio on the gas compositions, lower heating value (LHV), and higher heating value (HHV) were examined. In order to find the appropriate operating conditions of coal gasification, carbon conversion efficiency (CCE) and cold gas efficiency (CGE) were also explored. It was found that with an increase of the gasifier temperature, CCE and CGE of the tapered gasifier diminishes. Increasing tapered angle results in a decrease of the LHV and HHV of the gas products, whereas the CCE of... 

In this research, a series of NiO-xMgO-SiO2 catalysts with various MgO/SiO2 molar ratios were prepared via precipitation method followed by a hydrothermal treatment in the presence of PVP as surfactant. The synergic effect between MgO and SiO2 leading to the various characteristic and catalytic performance during propane steam reforming was investigated in detail. The results showed that 15 wt% NiO-0.5MgO–SiO2 catalyst possessed the highest catalytic activity (68.9% conversion for C3H8 at 550 °C) with a negligible amount of carbon formation after 20 h of reaction duration. This superior catalytic performance can be attributed to the enhanced basicity strength along with strong metal-support... 

In this research, the propane steam reforming (PSR) as a promising alternative route over a mesoporous NiO–MgO–SiO2 catalyst to produce syngas (SG) was undertaken. This catalyst was prepared using a co-precipitation method followed by hydrothermal treatment. The influence of such catalyst preparation factors as the hydrothermal time and temperature, pH and calcination temperature on the physicochemical characteristics of the prepared samples were examined. Next, these materials were characterized through the BET-BJH, XRD, TPR, and FTIR analyses. The thermal stability of this catalyst was tested through the TGA and DTA techniques. Furthermore, the deactivation of the calcined catalysts at... 

In this paper, a comparative techno-economic evaluation of hydrogen production by glycerol reforming in aqueous and gaseous phases are presented. To accomplish the techno-economic evaluation, firstly the process modeling and design are presented. Based on the equipment purchased costs, with 80 kg/h hydrogen production, the total cost of hydrogen production is estimated 3.65 and 3.55 $/kgH2 for steam reforming and aqueous phase reforming plants, respectively. Regarding the installation factor in the equipment costs, the total cost of hydrogen production is estimated 7.49 and 7.45 $/kgH2 for steam reforming and aqueous phase reforming plants, respectively. To investigate the impact of... 

The paper presents a comparison of steam methane reforming (SMR), sorption enhanced steam methane reforming (SE-SMR), auto-thermal reforming (ATR), and sorption enhanced auto-thermal reforming (SE-ATR) in a fixed bed reformer for hydrogen production. A one-dimensional, unsteady-state heterogeneous reactor model for each process which includes mass and thermal dispersion in the direction of flow and axial pressure distribution, has been simulated using gPROMS® 4.0.1 model builder, while CEA and Aspen Plus® have been employed to analyze the equilibrium performance and simulate the process flowsheets of individual process respectively. The performance of the individual hydrogen production... 

In the present study, due to various advantages of process miniaturization, the integrated design and operation of a mobile power generation system consisting of a microreactor reformer and a proton exchange membrane fuel cell (PEMFC) are investigated. The hydrogen fuel is supplied through autothermal steam-reforming of methanol in a microreactor leading to a safer, as well as more efficient, and economical operation. A high-temperature polymer membrane fuel cell with external accessories is applied for power generation. Then, simulation-optimization programming is applied for simultaneously optimizing the process design and operation at the same level. The result shows that the implemented...