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    Cobalt based metal organic framework/graphene nanocomposite as high performance battery-type electrode materials for asymmetric supercapacitors

    , Article Journal of Energy Storage ; Volume 33 , 2021 ; 2352152X (ISSN) Azadfalah, M ; Sedghi, A ; Hosseini, H ; Kashani, H ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Recently, development of advanced materials of metal-organic frameworks (MOFs) has attracted attention for the fabrication of supercapacitors (SCs) because of their high surface area and high level of porosity. However, poor electrical conductivity and weak mechanical properties of the MOFs have restricted their applications in the field. In this study, a one-step, in-situ synthesis of Cobalt-based MOF with graphene (CoMG nanocomposite) was employed to overcome the poor properties of MOFs. Accordingly, when the nanocomposite (CoMG5) was use as a supercapacitor electrode material, a specific capacitance (CS) of 549.96 F g−1 was observed in a three-electrode system with 6 M KOH electrolyte... 

    Nickel molybdate nanorods supported on three-dimensional, porous nickel film coated on copper wire as an advanced binder-free electrode for flexible wire-type asymmetric micro-supercapacitors with enhanced electrochemical performances

    , Article Journal of Colloid and Interface Science ; Volume 542 , 2019 , Pages 325-338 ; 00219797 (ISSN) Naderi, L ; Shahrokhian, S ; Sharif University of Technology
    Academic Press Inc  2019
    Abstract
    Wire-shaped micro-supercapacitors attracted extensive attentions in next-generation portable and wearable electronics, due to advantages of miniature size, lightweight and flexibility. Herein, NiMoO 4 nanorods supported on Ni film coated Cu wire are successfully fabricated thorough direct deposition of Ni film onto Cu wire as the conductive substrate, followed by growth of the NiMoO 4 nanorods on Ni film coated Cu wire substrate by means a hydrothermal annealing process. The prepared 3D, porous electrode demonstrates extremely high areal specific capacitance of 12.03F cm −2 at the current density of 4 mA cm −2 and retained capacitance of 8.23 F cm −2 at a much higher current density of 80... 

    Energy Savings in the Urban Electrified Railway using Onboard Storage Systems Energy Savings in the Urban Electrified Railway Using Onboard Storage Systems

    , M.Sc. Thesis Sharif University of Technology Hanifi, Mahmood (Author) ; Zolghadri, Mohammad Reza (Supervisor)
    Abstract
    Given the high rate of energy dissipation in electric urban rail lines, methods of saving energy in these systems have become a topic of interest. The use of energy saving equipment to save the energy wasted in braking (Because of the diode rectifier, thermal energy is usually wasted and is not reversible) can play an important role in reducing the energy loss. The role of energy storage equipment, from other aspects such as voltage regulation and increasing the system reliability is also remarkable. In this thesis, the various possible methods for saving energy in the Metro system are expressed.
    The various types of storage devices with increased reuse of braking energy which is the... 

    Control of Multi Inverter Microgrid Considering Hybrid Distributed Generation Systems and Renewable Energy Sources in Island Mode

    , M.Sc. Thesis Sharif University of Technology Ghazanfari, Amin (Author) ; Mokhtari, Hossein (Supervisor)
    Abstract
    Nowdays, distributed generation (DG) systems based on renewable energy sources have significantly increased around the world as an alternative solution to enhance the power quality and reliability and reduce the need for extensive transmission system as well. An evolved recent concept called microgrid is developed by grouping a cluster of loads and DG units in a common local area which increases the integaration of sustainable energy generation systems. This thesis presents control of a medium voltage (MV) microgrid considering multi-hybrid distributed generation systems (MHGS) and renewable energy resources in island mode. The first part is focused on the development a control strategy for... 

    Preparation of Nanocomposites from Carbon Nanostructures and Transtion Metal Oxides and their use in Preparation of Hybrid Electrochemical Capacitors

    , M.Sc. Thesis Sharif University of Technology Rahimi, Sajad (Author) ; Shahrokhian, Saeed (Supervisor)
    Abstract
    In the first part, we report a new and simple procedure for preparing reduced graphene oxide /nickel, cobalt hydroxide composite (Ni,Co-OH/rGO/NF via a fast and simple two-step electrochemical method including potentiostatic routes in the presence of Cetyl trimethyl ammonium bromide )CTAB( as a cationic surfactant. In the first step, a piece of nickel foam (NF) is sonicated in a suspension of graphene oxide (GO, 6 mg/L) after dried in an oven, reduced by electrochemically. After that, Ni, Co LDH were co-deposited on the surface of rGO/NF. The resulting modified electrode afforded extremely high specific capacitance of 2133.3 F/g at a current density of 4 A g-1. FE-SEM results showed that... 

    Fabrication and Investigation of Co3O4 Sponged Shape Nanostructured Supercapacitor Layer Electrodes Modified by Graphene

    , Ph.D. Dissertation Sharif University of Technology Qorbani, Mohammad (Author) ; Moshegh, Alireza (Supervisor) ; Naseri, Naima (Supervisor)
    Abstract
    Recently, Supercapacitors, as one of the most important energy storage devices, have attracted attensions by the scientists. Supercapcitor devices with appoporate design can store energy by two different mechanisms: i) physical (like conventional capacitors, i.e. by using polarization of the electrolyte, and ii) formation of electric double layer) and chemical mechanisms (like batteries, with reversible faradic reactions). These energy storage mechanisms allow these devices not only store high energy density but also they can provide high power density. In this project, two Co3O4/Co(OH)2 and Co3O4@Sponge-like rGO electrodes are made with chemical and electrochemical methods. To characterize... 

    Preparation and Characterization of Supercapacitor Nanocomposites Based on Polyaniline and Hybrid of Nano Metal/Metal Oxide Particles

    , M.Sc. Thesis Sharif University of Technology Mirzaei, Kamyar (Author) ; Shojaei, Akbar (Supervisor)
    Abstract
    Supercapacitors are one of the most important energy storage devices that have been researched with respect to the development of hybrid cars. Polymer composites have received much attention due to the electrochemical properties of conductive polymers and the synergistic effects of the composite components. In the present Thesis, in order to investigate the synergistic effect of gold nanoparticles with MnO2 nanorods as a metal oxide and polyaniline as a conductive polymer and graphene as a carbon material, two groups of composites were synthesized in the presence and absence of graphene. Characterization of the electrode material is carried out by XRD, FT-IR and FE-SEM tests. The... 

    Synthesis of MXene/Polyaniline Composite as an Electrode Material for Supercapacitors

    , M.Sc. Thesis Sharif University of Technology Borzou, Mohadeseh (Author) ; Khachatourian, Adrineh Malek (Supervisor) ; Bagheri, Reza (Supervisor) ; Esfandiar, Ali (Co-Supervisor)
    Abstract
    Titanium carbide MXene (Ti_3 C_2 T_x) has attracted significant research interest because of its extraordinary advantages as advanced electrode material for energy storage. In this study, 4-aminodiphenylamine functionalized Ti_3 C_2 T_x/polyaniline composite synthesized by in situ growth of PANI on 4-aminodiphenylamine functionalized Ti_3 C_2 T_x nanosheets. First, Ti_3 C_2 T_x MXene nanosheets was prepared according to the minimally intensive layer delamination (MILD) method followed by sonication. Ti_3 C_2 T_x nanosheets were modified with 4-aminodiphenylamine diazonium salt. The FTIR، FE-SEM and EDS analysis were used to characterize modified Ti_3 C_2 T_x. Finally, the Ti_3 C_2 T_x... 

    Comparison of the Performance of Nanostructured Metal Oxides and Metal Sulfides as Electrode Active Materials in the Construction of Supercapacitors

    , M.Sc. Thesis Sharif University of Technology Molaei Zarandi, Zeynab (Author) ; Ghotbi, Cyrus (Supervisor) ; Khorasheh, Farhad (Supervisor) ; Asgharinezhad, Ali Akbar (Supervisor) ; larimi, Afsaneh Sadat (Supervisor)
    Abstract
    High-capacity electrode materials are crucial for enhancing the performance of supercapacitors. Transition metal sulfides are considered promising materials for supercapacitor applications due to their high theoretical capacity and good electrical conductivity. Additionally, cerium oxide improves the performance of supercapacitors due to stable reversible oxidation states and greatly supported the faradaic redox reaction. In this study, ceria nanosheets incorporated with MCoS (M=Mn, Zn, Cu) were synthesized successfully through a facile hydrothermal method by sulfidation of MCo LDH/CeO2. The structural and morphological characteristics were analyzed using X-ray diffraction, scanning electron... 

    Theoretical analysis of the performance of a model supercapacitor consisting of metal oxide nano-particles

    , Article Journal of Solid State Electrochemistry ; Volume 11, Issue 8 , 2007 , Pages 1085-1092 ; 14328488 (ISSN) Farsi, H ; Gobal, F ; Sharif University of Technology
    2007
    Abstract
    The factors influencing the electrochemical behaviour of a supercapacitor have been partly examined in this work. The effects of so-called intrinsic parameters, i.e. exchange current density, unit cell length and double layer (DL) capacitance; as well as the so-called application parameters, i.e. cell current, on the cell potential discharge time have been considered. The contributions of each type of capacitors, DL capacitor and faradaic supercapacitor under various states of operation and material have been analyzed, and the competing (compensating) effects of the two types of capacitors as regards to the discharge and power characteristics manifested by current-potential and energy-power... 

    MnO2/ordered mesoporous carbon nanocomposite for electrochemical supercapacitor

    , Article Journal of Solid State Electrochemistry ; Vol. 18, issue. 4 , 2014 , pp. 1117-1125 Kiani, M. A ; Khani, H ; Mohammadi, N ; Sharif University of Technology
    Abstract
    The preparation of composite manganese dioxide (MnO2) nanoparticles in an ordered mesoporous carbon (CMK-3) matrix and its use for constructing a new wide-potential-window supercapacitor is reported. CMK-3 is prepared using mesoporous silica as a hard template and sucrose as carbon source. The different ratios of MnO2/CMK-3 composite is synthesized by impregnating CMK-3 with a Mn(NO3)2·4H 2O solution followed by annealing in nitrogen. Physical properties, morphology, and specific surface area were characterized by X-ray diffraction, transmission electron microscopy, and nitrogen sorption measurements, respectively. The electrochemical properties of the composite were studied by cyclic... 

    Fabrication of nanoporous nickel oxide by de-zincification of Zn-Ni/(TiO2-nanotubes) for use in electrochemical supercapacitors

    , Article Electrochimica Acta ; Volume 100 , 2013 , Pages 133-139 ; 00134686 (ISSN) Gobal, F ; Faraji, M ; Sharif University of Technology
    2013
    Abstract
    NiO-ZnO/TiO2NTs electrodes were synthesized by the electrodeposition of Zn-Ni onto TiO2 nanotubes, dealloying in a concentrated alkaline solution and finally calcination of the resulting Zn(OH)2-Ni(OH)2/TiO2NTs at 300 C. Morphology of the electrodeposited nanostructures was studied using scanning electron microscopy (SEM) while their electrochemical characterizations were carried out using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge procedures. The SEM analysis revealed the nanoporous/cracked structures of the NiO-ZnO/TiO2NTs obtained at the electroplating time of 20 min. The EIS studies showed that nanoporous/cracked structures of... 

    Electrodeposited polyaniline on Pd-loaded TiO2 nanotubes as active material for electrochemical supercapacitor

    , Article Journal of Electroanalytical Chemistry ; Volume 691 , 2013 , Pages 51-56 ; 15726657 (ISSN) Gobal, F ; Faraji, M ; Sharif University of Technology
    2013
    Abstract
    PANI/Pd/TiO2NTs electrodes with highly porous structures and good capacitive characteristics were prepared by electrodeposition of polyaniline on palladium nanoparticles loaded TiO2 nanotubes. The loading of small palladium nanoparticles was carried out by sonochemical reduction of Pd+2 onto TiO2NTs and affected the ordered growth of PANI, reducing the charge transfer resistance and increasing surface area of PANI. The specific capacitance and the stability of electrode showed improvements. The results illustrated that the specific capacitance of these electrodes was around 1060 F g-1 in 1.0 M H2SO4 electrolyte as measured at a constant current of 2.0 A g-1, whereas it was 210 F g-1 for the... 

    A comparative study of sequentially layer-deposited and co-deposited Co-Mn oxides as potential redox capacitors

    , Article Journal of Solid State Electrochemistry ; Volume 16, Issue 4 , April , 2012 , Pages 1561-1569 ; 14328488 (ISSN) Gobal, F ; Jafarzadeh, S ; Sharif University of Technology
    2012
    Abstract
    Layers of cobalt and manganese oxides were co-deposited or deposited on top of each other or next to each other by potentiostatic method onto stainless steel substrate. Deposition potentials of 1 and -1 V for the anodic and cathodic depositions were employed. Specific capacitance values in the range of 38.5-78 F g -1 were found with cobalt oxide on top of manganese oxide having the lowest and manganese oxide on top of cobalt oxide having the highest capacitances. The usefulness of the electrodes was characterized by cyclic voltammetry, charge-discharge cycling, and electrochemical impedance spectroscopy in 2 M NaOH electrolyte for redox supercapacitor applications. The latter presented the... 

    Hierarchical Co3O4/Co(OH)2 nanoflakes as a supercapacitor electrode: experimental and semi-empirical model

    , Article ACS Applied Materials and Interfaces ; Volume 7, Issue 21 , 2015 , Pages 11172-11179 ; 19448244 (ISSN) Qorbani, M ; Naseri, N ; Moshfegh, A. Z ; Sharif University of Technology
    American Chemical Society  2015
    Abstract
    In this research, facile and low cost synthesis methods, electrodeposition at constant current density and anodization at various applied voltages, were used to produce hierarchical cobalt oxide/hydroxide nanoflakes on top of porous anodized cobalt layer. The maximum electrochemical capacitance of 601 mF cm-2 at scan rate of 2 mV s-1 was achieved for 30 V optimized anodization applied voltage with high stability. Morphology and surface chemical composition were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analysis. The size, thickness, and density of nanoflakes, as well as length of the porous anodized Co layer were measured about 460 ± 45 nm,... 

    A high performance supercapacitor based on graphene/polypyrrole/Cu2O-Cu(OH)2 ternary nanocomposite coated on nickel foam

    , Article Journal of Physical Chemistry C ; Volume 121, Issue 12 , 2017 , Pages 6508-6519 ; 19327447 (ISSN) Asen, P ; Shahrokhian, S ; Sharif University of Technology
    Abstract
    A simple and low-cost electrochemical deposition method is used to prepare reduced graphene oxide/polypyrrole/Cu2O-Cu(OH)2 (RGO/PPy/Cu2O-Cu(OH)2) ternary nanocomposites as the electrode material for supercapacitor application. First, graphene oxide-polypyrrole (GO/PPy) nanocomposite is electrochemically synthesized on Ni foam by electro-oxidation of pyrrole monomer in an aqueous solution containing GO and Tiron. Subsequently, the GO/PPy film is converted to the corresponding reduced form (RGO/PPy) by an effective and eco-friendly electrochemical reduction method. Then, a thin layer of Cu2O-Cu(OH)2 is formed on RGO/PPy film by chronoamperometry. The RGO/PPy/Cu2O-Cu(OH)2 nanocomposite is... 

    Silver fiber fabric as the current collector for preparation of graphene- based supercapacitors

    , Article Electrochimica Acta ; Volume 227 , 2017 , Pages 246-254 ; 00134686 (ISSN) Mehrabi Matin, B ; Shahrokhian, S ; Iraji zad, A ; Sharif University of Technology
    Elsevier Ltd  2017
    Abstract
    During the past few years, a considerable attention has been devoted to the development of textile- based energy storage devices and wearable electronics applications. In this paper, for the first time, we report a flexible high performance graphene-based supercapacitor using silver fiber fabric as the current collector. The silver fiber fabric offers remarkable advantages such as light weight, mechanical flexibility and ease of integration with electronic textiles, which well-suited for wearable energy storage devices. A new hybrid material of graphene-silver fiber fabric (rGO/SFF) was prepared through a facile electrophoretic deposition of graphene and being used as a binder-free flexible... 

    Ternary nanostructures of Cr2O3/graphene oxide/conducting polymers for supercapacitor application

    , Article Journal of Electroanalytical Chemistry ; Volume 823 , 2018 , Pages 505-516 ; 15726657 (ISSN) Asen, P ; Shahrokhian, S ; Iraji Zad, A ; Sharif University of Technology
    Abstract
    In this work, nanostructured composites of Cr2O3-graphene oxide (Cr2O3/GO) with conducting polymers; polyaniline (PANI) and polypyrrole (PPy) with the shape of cauliflower were synthesized via s simple and low cost one-step chronoamperometry method. The structures and morphologies of the resulting ternary nanocomposites were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The electrochemical capacitive properties of the prepared nanocomposites were evaluated by using cycle voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The... 

    Iron‑vanadium oxysulfide nanostructures as novel electrode materials for supercapacitor applications

    , Article Journal of Electroanalytical Chemistry ; Volume 818 , 2018 , Pages 157-167 ; 15726657 (ISSN) Asen, P ; Shahrokhian, S ; Iraji Zad, Azam ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    Iron‑vanadium oxysulfide (Fe-VO-S) nanostructures with different Fe:VO atomic ratios are synthesized by a facile and low cost electrochemical deposition method. The synthesis of the various samples is confirmed by the physicochemical characterizations such as Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and atomic force microscopy (AFM). For different Fe-VO-S nanostructures, the correlation between the physicochemical and the electrochemical properties is investigated. It is found that the Fe:VO atomic ratio has an important effect on the structure and size of the resulted particles.... 

    Ti-rich TiO2 tubular nanolettuces by electrochemical anodization for all-solid-state high-rate supercapacitor devices

    , Article ChemSusChem ; Volume 12, Issue 17 , 2019 , Pages 4064-4073 ; 18645631 (ISSN) Qorbani, M ; Khajehdehi, O ; Sabbah, A ; Naseri, N ; Sharif University of Technology
    Wiley-VCH Verlag  2019
    Abstract
    Supercapacitors store charge by ion adsorption or fast redox reactions on the surface of porous materials. One of the bottlenecks in this field is the development of biocompatible and high-rate supercapacitor devices by scalable fabrication processes. Herein, a Ti-rich anatase TiO2 material that addresses the above-mentioned challenges is reported. Tubular nanolettuces were fabricated by a cost-effective and fast anodization process of Ti foil. They attained a large potential window of 2.5 V in a neutral electrolyte owing to the high activation energy for water splitting of the (1 0 1) facet. Aqueous and all-solid-state devices showed diffusion time constants of 46 and 1700 ms, as well as...