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Total 233 records

    Investigation of Asphaltene Electro-deposition In Presence of Addetives

    , M.Sc. Thesis Sharif University of Technology Moradpour, Nikoo (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Dehghani, Farzaneh ($item.subfieldsMap.e)
    Abstract
    Given the decreasing trend of light petroleum reserves and the necessity to produce heavy and extra-heavy oil resources, the challenge of dealing with existing asphaltene related problems, which is the heaviest and the most complex component of crude oil, has become increasingly tangible. Asphaltene precipitates and deposits due to pressure, temperature or composition alterations which leads to obstruction of porous media and production facilities. Set the costly methods aside, one of the available approaches to prevent asphaltene precipitation, is to apply an electric field upon the suspected zone, which is cheap and uncomplicated. Besides, utilizing nano-particles while applying electric... 

    Modeling of Wettability Alteration During Enhanced Oil Recovery by Surfactants

    , M.Sc. Thesis Sharif University of Technology Aliabadian, Ehsan (Author) ; Ghazanfari, Mohammad Hossein (Supervisor) ; Ayatollahi, Shahaboddin (Supervisor)
    Abstract
    There are considerable investigations on wettability alteration in carbonate reservoirs in recent years. The presence of ions including Ca, Si, Al etc in natural carbonate rocks and also the presence of various fatty acids, resins, asphaltenes etc in crude oil makes it difficult to understand the complex mechanism of wettability alteration by using surfactants. Furthermore there is still a conspicuous lack of dynamic wettability alteration model to demonstrate the dynamic behavior of cationic surfactants during wettability alteration. It is also widely accepted that cationic surfactants have substantial impact on changing the wettability of strongly oil-wet matrixes to a more water-wet... 

    CFD Modeling of Reactive Flow During Matrix Acidizing

    , M.Sc. Thesis Sharif University of Technology Hashemi Khoramabad, Mohammad (Author) ; Bazarga, Mohammad (Supervisor) ; Masihi, Mohsen (Co-Supervisor)
    Abstract
    Heterogeneity is the major cause of the uneven acid distribution in carbonate acidizing. Traditional acidizing involves the injection of mineral acids, such as hydrochloric acid into the formation, which the bulk of the acidic solution permeates into the high-permeable layers and the low-permeability layers remain unreacted. So far, many chemical and mechanical techniques have been used to avoid the uneven distribution of acid. Using surfactant-based viscoelastic acids is one of the effective chemical method to divert acid to low-permeable zones. The unique feature of these acids is increasing viscosity of acidic solution as the pH increases. In this study, a two-scale continuum model... 

    Characterization of Formation Damage Induced by Oil-Based Drilling Fluid and Proposing its Optimized Remedy

    , M.Sc. Thesis Sharif University of Technology Ahmadi, Amir (Author) ; Masihi, Mohsen (Supervisor) ; Tahmasbi, Koroush (Supervisor) ; Kalhor, Mojtaba (Co-Supervisor)
    Abstract
    During all operations in hydrocarbon reservoirs, there is a possibility of formation damage. These damages can reduce the production of fluids from reservoir. One of the major damages that can seriously affect the performance of a reservoir is the damage caused by drilling fluid. The main purpose of this research is to study the main mechanisms of formation damages when using oil-based drilling fluids and fixing or preventing these damages. Once the mechanisms are identified, it is tried to cure the damages but without acid-washing. The alternative method is surfactant-washing which is a surfactant-brine injection. This injection has been done for the first time. This study helps to industry... 

    Foam stability and foam-oil interactions

    , Article Petroleum Science and Technology ; Vol. 32, issue. 15 , May , 2014 , p. 1843-1850 ; ISSN: 10916466 Rashed Rohani, M ; Ghotbi, C ; Badakhshan, A ; Sharif University of Technology
    Abstract
    Gas injection into reservoirs can be used to increase oil recovery. However, reservoir heterogeneity and high gas mobility reduce sweep efficiency and decrease recovery. Using foam can reduce gas mobility and therefore increase sweep efficiency. Foam is thermodynamically unstable, so it is important to predict the foam stability. In order to understand the influence of oil presence on foam stability, static experiments performed on foam by varying the type and amount of added oil and molecular weight of added alkane. Also static foam properties have been investigated by varying the surfactant concentration, ionic strength, composition of different salts in the sample, and addition of polymer... 

    Investigation of effects of salinity, temperature, pressure, and crude oil type on the dynamic interfacial tensions

    , Article Chemical Engineering Research and Design ; Volume 115 , 2016 , Pages 53-65 ; 02638762 (ISSN) Lashkarbolooki, M ; Riazi, M ; Ayatollahi, S ; Sharif University of Technology
    Institution of Chemical Engineers  2016
    Abstract
    The main objectives of this study are to determine the influence of crude oil type, salinity, temperature and pressure on the dynamic interfacial tension (DIFT) of crude oil based on the experiments and modeling approaches. DIFT is also modeled using dynamic adsorption models, mono-exponential decay model as well as empirical equations. The results showed that when temperature increases, unlike deionized water which inversion phase temperature was observed, the equilibrium IFT of crude oils/sea water increases due to reduction of surface excess concentration of natural surfactants at the fluid/fluid interface as a dominant mechanism  

    Effect of asphaltene and resin on interfacial tension of acidic crude oil/ sulfate aqueous solution: Experimental study

    , Article Fluid Phase Equilibria ; Volume 414 , 2016 , Pages 149-155 ; 03783812 (ISSN) Lashkarbolooki, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier  2016
    Abstract
    Although the capability of using sulfate anion as a wettability modiffier is well established, no systematic investigation on the effect of sulfate ions and natural surfactants in the crude oil including asphaltene and resin on the interfacial tension (IFT) of acidic crude oil (ACO)/sulfate were performed. In this regards, the fluid/fluid interactions are tested through the IFT measurements for ACO, asphaltene and resin extracted from ACO in the presence of sulfate salts including Na2SO4, MgSO4 and CaSO4 while the concentration of each salt ranges between 0 and 45000 ppm. The obtained results demonstrate that the capability of asphaltene molecules is higher for IFT reduction compared with... 

    Preparation of sorbitan stearate

    , Article 2nd International Multi-Conference on Engineering and Technological Innovation, IMETI 2009, Orlando, FL, 10 July 2009 through 13 July 2009 ; Volume 1 , 2009 , Pages 81-85 ; 193427268X (ISBN); 9781934272688 (ISBN) Amin Mahalati, A. R ; Alemzadeh, I ; Vossoughi, M ; Inter-American Organization for Higher Education (IOHE); International Institute of Informatics and Systemics (IIIS); Journal of Systemics, Informatics and Cybernetics (JSCI) ; Sharif University of Technology
    International Institute of Informatics and Cybernetics, IIIC  2009
    Abstract
    The present paper relates to an improved method for making surfactant esters, especially sorbitan monostearate and tristearate. Sorbitan esters of fatty acid, stéarate are derived from a reaction between sorbitan and fatty acid. Method of sorbitan ester production needs addition of catalyst. Sorbitan stéarate production was studied using chemical catalyst. Two steps process leading sorbitan production under atmospheric and vacuum pressure with acid catalyst resulted dehydrated product at optimal residence time of 195 min at 180°C for atmospheric conditions and optimalresidence time of 150 min at the same temperature respectively. Sorbitan stearate production was studied by utilizing sorbitan... 

    The effects of bubble detachment shape on rising bubble hydrodynamics

    , Article Scientia Iranica ; Volume 26, Issue 3 C , 2019 , Pages 1546-1554 ; 10263098 (ISSN) Fayzi, P ; Bastani, D ; Lotfi, M ; Ghamangiz Khararoodi, M ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    Local velocities and aspect ratios of rising bubbles were measured to investigate the effects of bubble detachment shape on rising bubble hydrodynamics. Two types of capillary were employed to generate bubbles of identical volume: one glassy nozzle aligned vertically and the other stainless steel needle aligned horizontally. Horizontally injected bubbles have a spherical initial shape, and their values of aspect ratio slightly fluctuate around unity. However, vertically injected bubbles have a surface-stretched initial shape, and their values of aspect ratios decrease sharply from 1.1 to 0.65. There is a notable correspondence between the variation of local velocities and aspect ratios that... 

    Experimental investigation of the effects of surfactants on the mass transfer in liquid-liquid extraction equipment

    , Article 2007 5th Joint ASME/JSME Fluids Engineering Summer Conference, FEDSM 2007, San Diego, CA, 30 July 2007 through 2 August 2007 ; Volume 2 FORA, Issue PART A , 2007 , Pages 239-244 ; 0791842886 (ISBN); 9780791842881 (ISBN) Haghdoost, A ; Shah Alami, M ; Mansouri, H ; Sharif University of Technology
    2007
    Abstract
    Mass transfer rates to the drops in liquid-liquid extraction equipment are often likely to be reduced by the presence of surface active contaminants. This reduction in mass transfer is said to be due to a reduction in terminal velocity, and to changes in pattern of internal circulation. A single-drop extraction apparatus was used to investigate the dependency of mass transfer coefficient on the amount of surfactant added in a system of n-butanol/succinic acid/water. Three types of surfactants, SDS, DTMAC and Triton X-100, were used to study their effects on the inhibition of mass transfer in liquid-liquid extraction. The effect of surfactants concentration on extraction percentage, overall... 

    Study and optimization of Amino Acid Extraction by emulsion Liquid Membrane

    , Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) Mohagheghe, E ; Vosoughi, M ; Alemzadeh, I ; Hexion Specialty Chemicals; Mitsubishi Chemical Corporation; CS Cabot; Zentiva; BorsodChem MCHZ ; Sharif University of Technology
    2006
    Abstract
    A batch extraction of an essential amino acid, Phenylalanine, from an aqueous solution of different concentrations by an Emulsion Liquid Membrane (ELM) was developed using D2EHPA as a cationic carrier, Span 80 as the surfactant, paraffin and kerosene as the diluents, and HCl as the internal electrolyte. All effective parameters such as pH of initial aqueous external phase, electrolyte concentration in aqueous internal phase, carrier and surfactant concentration in emulsion, volume ratio of the organic to aqueous internal phase (Roi), volume ratio of the W/O emulsion to aqueous external phase (Rew) and time were examined and optimized using Taguchi method which was the first time of... 

    Influence of surface-modified nanoparticles on the hydrodynamics of rising bubbles

    , Article Chemical Engineering and Technology ; Volume 44, Issue 3 , 2021 , Pages 513-520 ; 09307516 (ISSN) Fayzi, P ; Bastani, D ; Lotfi, M ; Miller, R ; Sharif University of Technology
    Wiley-VCH Verlag  2021
    Abstract
    Local velocities of bubbles rising in four different nanosilica solutions were investigated experimentally. Also, the density, viscosity, and surface tension of fumed nanosilica and modified nanosilica solutions were measured. Heat treatment and chemical functionalization were used to modify the properties of silica nanoparticles. It was found that the addition of nanosilica affected the hydrodynamics of the rising bubble by increasing the drag friction at the interface. However, environmentally responsive nanosilica particles behaved like surfactant molecules, due to the interfacial activity of hydrophilic and hydrophobic chains. Silica nanoparticles coated with both hydrophilic and... 

    Quantitative determination of linear alkylbenzene sulfonate (LAS) concentration and simultaneous power generation in a microbial fuel cell-based biosensor

    , Article Journal of Cleaner Production ; Volume 294 , 2021 ; 09596526 (ISSN) Askari, A ; Vahabzadeh, F ; Mardanpour, M. M ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Linear alkylbenzene sulfonate (LAS), one of the most widely used synthetic surfactants in laundry detergent industry, is considered a hazardous contaminant in wastewater. In the present study, a microbial fuel cell (MFC) based biosensor is developed to quantitively determine the LAS concentration in wastewater. To do so, the developed MFC is fed with LAS concentration of 60 mg l−1. Finally, a sustained biofilm is formed after almost 34 days and the highest open circuit potential of 425 mV is recorded. The maximum power and current densities of 75 mW m−3 and 663 mA m−3 are obtained, respectively; and the internal resistance of the MFC-based biosensor is calculated to be about 1 kΩ. After 98... 

    Multiple linear regression modeling of the critical micelle concentration of alkyltrimethylammonium and alkylpyridinium salts

    , Article Journal of Surfactants and Detergents ; Volume 6, Issue 1 , 2003 , Pages 25-30 ; 10973958 (ISSN) Jalali Heravi, M ; Konouz, E ; Sharif University of Technology
    American Oil Chemists Society  2003
    Abstract
    The critical micelle concentration (CMC) of a set of 30 alkyltrimethylammonium [RN+(R′)3X-] and alkylpyridinium salts [RN+φX-] was related to topological, electronic, and molecular structure parameters using a stepwise regression method. Among different models obtained, two equations were selected as the best and their specifications are given. The statistics for these models together with the crossvalidation results indicate the capability of both models to predict the CMC of cationic surfactants. The results obtained for alkyltrimethylammonium salts indicate that geometric characteristics such as volume of the tail of the molecule, maximum distance between the atoms, and surface area play... 

    Dissolution and remobilization of NAPL in surfactant-enhanced aquifer remediation from microscopic scale simulations

    , Article Chemosphere ; Volume 289 , 2022 ; 00456535 (ISSN) Ramezanzadeh, M ; Aminnaji, M ; Rezanezhad, F ; Ghazanfari, M. H ; Babaei, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    In this paper, the dissolution and mobilization of non-aqueous phase liquid (NAPL) blobs in the Surfactant-Enhanced Aquifer Remediation (SEAR) process were upscaled using dynamic pore network modeling (PNM) of three-dimensional and unstructured networks. We considered corner flow and micro-flow mechanisms including snap-off and piston-like movement for two-phase flow. Moreover, NAPL entrapment and remobilization were evaluated using force analysis to develop the capillary desaturation curve (CDC) and predict the onset of remobilization. The corner diffusion mechanism was also applied in the modeling of interphase mass transfer to represent NAPL dissolution as the dominant mass transfer... 

    Experimental Investigation of Rock Wettability Effect on Carbonate Reservoir Matrix Acidizing

    , M.Sc. Thesis Sharif University of Technology Karimi, Masoud (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Matrix acidizing operation is one of the popular methods of well stimulation in the oil and gas industry which is used to remove near wellbore damage, increase the permeability, hence improve the production rate from the formation. Hydrochloric acid is used in the carbonate reservoirs to remove formation damage and create wormhole deep in the rock. It has been shown that with the proper operating design, significant improvement in the production rate can be obtained. A successful acid operations involves the proper selection of the candidate wells, identify the type of formation damage, stimulation method selection, correct design acidizing scenario, implementation of the technique and... 

    Simultaneous/sequential alkaline-surfactant-polymer flooding in fractured/non-fractured carbonate reservoirs

    , Article Canadian Journal of Chemical Engineering ; Vol. 92, issue. 5 , May , 2014 , p. 918-927 ; ISSN: 00084034 Sedaghat, M. H ; Ghazanfari, M. H ; Masihi, M ; Sharif University of Technology
    Abstract
    Alkaline-Surfactant-Polymer flooding is one of the most novel chemical enhanced oil recovery methods in the petroleum industry. This method has attracted interest due to its remarkable advantages. In this work, a series of ASP floods are conducted on fractured/non-fractured carbonate rocks. The performance of the tests was investigated by various ASP floods consisting of five types of polymers, two surfactants and one common alkaline. ASP was flooded simultaneously and sequentially in four defined scenarios after water flooding. The results showed that although using hydrolysed polymers increases the recovery factor in the fractured medium, sulfonated polymers increase oil recovery even more... 

    Bubble in flow field: A new experimental protocol for investigating dynamic adsorption layers by using capillary pressure tensiometry

    , Article Colloids and Surfaces A: Physicochemical and Engineering Aspects ; Vol. 460, issue , 2014 , p. 369-376 Lotfi, M ; Bastani, D ; Ulaganathan, V ; Miller, R ; Javadi, A ; Sharif University of Technology
    Abstract
    For many years the model of a dynamic adsorption layer (DAL) is well established as explanation for the behavior of rising bubbles in surfactant solutions. This model explains the velocity profile and the evolution of the shape of a rising bubble based on the hypothesis of the balance between the drag force and the structure of the adsorbed layer governed by Marangoni convection. However, direct measurements of interfacial properties of the bubble during rising are a real challenge. Here we present a new experimental protocol called "bubble in flow field" suitable for direct measurements of dynamic interfacial properties of a bubble surface using the capillary pressure tensiometry under... 

    Application of biosurfactants to wettability alteration and IFT reduction in enhanced oil recovery from oil-wet carbonates

    , Article Petroleum Science and Technology ; Volume 31, Issue 12 , Jul , 2013 , Pages 1259-1267 ; 10916466 (ISSN) Biria, D ; Maghsoudi, E ; Roostaazad, R ; Sharif University of Technology
    2013
    Abstract
    To obtain potentially applicable microorganisms to an effective in situ microbial enhanced oil recovery operation, bacteria that were compatible with the harsh conditions of a petroleum reservoir were isolated from a crude oil sample. The application of an oil spreading technique showed that all of the isolates were capable of producing biosurfactants from both the glucose and crude oil as carbon sources. The secreted biosurfactants could at least reduce the surface tension 20 mN/m and for one of the isolates; the surface tension value dropped below 40 mN/m. In addition, the contact angle measurements revealed that the produced biosurfactants could effectively alter the wettability of the... 

    Phase behavior and interfacial tension evaluation of a newly designed surfactant on heavy oil displacement efficiency; effects of salinity, wettability, and capillary pressure

    , Article Fluid Phase Equilibria ; Volume 396 , 2015 , Pages 20-27 ; 03783812 (ISSN) Dehghan, A. A ; Masihi, M ; Ayatollahi, S ; Sharif University of Technology
    Elsevier  2015
    Abstract
    This work aims to discuss the results of wide ranges of laboratory investigations to evaluate the performance of a newly-formulated surfactant for heavy oil reservoirs in order to improve the microscopic sweep efficiency after water flooding processes. In the first part, the specific behavior of the formulated surfactant including its salinity tolerance, interfacial tension, and optimum performance window was determined. Then, the application of surfactant solutions in real sandstone reservoir rocks was assessed for both oil-wet and water-wet cases. Besides, the effect of changing the capillary and viscous forces and interfacial tension on the residual phase saturations were characterized....