Sharif Digital Repository

The phenomenon of oil drop detachment from solid surface has great importance in many different industries, such as coating, print, membrane emulsification, detergency, and oil enhancement recovery. In our study, we tried to explore this phenomenon. Therefore, we attempted to employ Young equation as force balance for the discussed system which is comprised of n-Decane as oil droplet, aqueous solution (brine) with SDS (Sodium Dodecyl Sulfate), and glass. Also, in order to find governing factors regarding oil detachment process -such as interfacial tension, contact angle, and line friction coefficient- we used an advanced apparatus equipped with horizontal microscope and digital video camera.... 

In this experimental work terminal velocity, velocity profile and aspect ratio of bubble with 1.49 mm diameter which ascend in pure water and infected by surfactant nonionic C10DMPO and surfactant ionic SDS in regime that surface tension is dominant, have been considered. Observations showed that with respect to entering nozzle, bubbles with this diameter have two initial stable shape; spherical and extended form on surface for horizontal needle and vertical nozzle. Results are (1) Bubbles with initial spherical shape had lower terminal velocity and higher aspect ratio with respect to bubbles with initial extended form, (2) Spherical bubble had aspect ratio about 1 at whole bubble column... 

Surface phenomena is one of the fundamental branches of science that has many applications in industries related to multiphase processes. One of the most important issues of this knowledge is inter-phase transport phenomena in contacting gas - liquid and liquid – liquid systems. Multiphase systems generally include dispersions such that in many cases are associated with the relative motion between the continuous and dispersed phase. One of the most widely used inter-phase flow systems is dispersion of gas bubbles in the bulk of liquid. The overall efficiency of these systems is often determined by the characteristics of the gas phase. In order to understand the dynamic behavior of such... 

Well stimulation techniques are used to increase the productivity of oil and gas wells. One of the effective well stimulation methods, is matrix acidizing. During matrix acidizing, acidic solution is injected into the formation at pressure below the formation fracture pressure. Most of the time, acid needs to be reached to low permeability layers for more efficient damage removal. Divertors are used for diverting acid from high permeability to low permeability layers.Successful performance of a viscoelastic acid during an acid job, is highly dependent on the surfactant rheological properties. For a betaine viscoelastic surfactant, we have studied the effect of different parameters on the... 

The aim of this research is to study the effect of surfactant type and the concentration reactants on the size, shape and magnetic properties of iron-gold core-shell magnetic nanoparticles (NPs) useable for biomedical application. The reverse micelle procedure was employed to synthesize iron NPs using two surfactants of CTAB and SDS. A gold shell with a thickness in the range of 10 to 40 nm was induced by reverse micelle method in order to prevent oxidation of the iron core. The size and morphology of NPs were studied by transition electron microscopy (TEM). It was found that the size of NPs increases by the increasing the reactants concentration while the morphology of the NPs was not... 

The drop motion in fluid and the mass transfer is one of the most interesting and favorite topics that has attracted the attention of many researchers. Knowing the functions of the factors affecting the deformation and the process of mass transfer and the effects of the addition of the surfactant, improve the efficiency of the related industrial processes.In this regard, the present study examines how the shape and speed of a moving Newtonian drop in a Newtonian fluid, the mass transfer of soluble material from inside the drop to the surrounding fluid and also the study of the effect of surfactant on the dynamics of moving droplet is studied numerically. During the drop movement, the... 

There are a lot of Fractured reservoirs around the world that have large portion of oil production. These reservoirs have complex structure and fractures have important role in production but the remaining oil in matrix causes that the oil recovery decreases. One of the most important factors in these reservois are wettability. Because most of the fractured reservoirs are oil wet and water injection process in these reservoirs are not effective and chemical EOR methods such as surfactant flooding method is used. Surfactant improve oil recovery by two reasons: 1- reduction of interfacial tension between oil and water . 2-Wettability alteration of matrix. The porpose of this project is... 

During all operations in hydrocarbon reservoirs, there is a possibility of formation damage. These damages can reduce the production of fluids from reservoir. One of the major damages that can seriously affect the performance of a reservoir is the damage caused by drilling fluid. The main purpose of this research is to study the main mechanisms of formation damages when using oil-based drilling fluids and fixing or preventing these damages. Once the mechanisms are identified, it is tried to cure the damages but without acid-washing. The alternative method is surfactant-washing which is a surfactant-brine injection. This injection has been done for the first time. This study helps to industry... 

The success of matrix acid production operations and its proper efficiency is one of the main challenges for oil and gas companies. The heterogeneity of the reservoir formation (especially the permeability difference) in the area around the well due to the presence of different reservoir layers results in the non-uniform distribution of acid among them and adds acidizing challenges. In order to improve production conditions, stimulation fluid transfer to the low permeability layer, which is the main target of acidizing. In this study, a new generation of chemical diverter, called Viscoelastic Surfactant, has been used. These materials have two components of elastic and viscous behavior, and... 

Chemical flooding has great potential to recover significant fractions of remaining oil for medium to heavy oil reservoirs not applicable for thermal recovery techniques. Nowadays, with gradual crude oil price increase the chemical process is receiving renewed attention, however, illustration of the possibility of various chemical injection scenarios for medium to heavy oil reservoirs has not been clearly reported and these kinds of reservoirs require more investigation for the applicability of these techniques in the fields. The interfacial active molecules are responsible for providing low IFT range and water/oil emulsions which in many cases could improve the oil displacement efficiency.... 

Acidizing efficiency depends on various factors such as formation properties, reservoir and stimulation fluid types and injection scenario. Among these factors, heterogeneity of reservoir’s formation (layered reservoirs and permeability variation versus depth) strongly affect acidizing performance. Accordingly, applying a reliable technique that distribute stimulation fluid uniformly is essential. The aim of carbonate matrix acidizing is to improve fluid flow specially in low permeability zones. Stimulation fluid cannot enter into the low permeability layer due to existence of high permeability layers which are in contact with low permeability ones. So, the stimulation fluid should be... 

Imbibition process is known to be an important recovery mechanism in naturally fractured reservoirs with water-wet matrix blocks that are imposed to water influx from an active aquifer or water flooding. Matrix blocks which are subjected to water flooding or water invasion from active aquifers do not become immersed in water at once, but they experience gradual rising of water in fracture. But most of imbibition studies are performed under conditions of totally immersed cores in static aqueous phase. Surfactants are known to reduce residual oil saturation by decreasing interfacial tension (IFT) between oil and water. On the other hand, considerable reduction of IFT due to surfactant... 

Many of oil reservoirs in Iran that are fractured, do not have high Recovery Factor (RF), therefor Enhanced Oil Recovery (EOR) methods are exerted in them. In fractured reservoirs, due to high capillary pressure in matrix and low amount of it in fracture, the wetting phase tends to imbibe to the matrix from the fracture. Altering the wettability of reservoir rock from Oil-Wet (OW) to Water-Wet (WW) enables the injected water to imbibe to matrix and sweep its oil. Also reducing oil/water IFT turns oil to small droplets, helps them to pass narrow pores and be produced. In one of the new EOR methods called chemical EOR, chemical additives are injected to the reservoirs along with water to... 

Naturally fractured oil reservoirs represent over 20% of the world's oil reserves, while over 60% of the world’s remaining oil lies trapped in fractured reservoirs. However, relatively little success has been achieved in increasing oil production from these complex reservoirs. Water flooding process leaves much oil in the reservoir, especially in fractured reservoirs. Surfactant flooding is known to lower the interfacial tension and hence, reduces capillary forces responsible for trapping oil and increasing recovery. However, fundamental understanding how the fracture geometrical properties affect the oil recovery efficiency during surfactant flooding remains a topic of debate in the... 

In many cases, oil and gas extraction from reservoirs due to damage and permeability reduction near wellbore is lower than optimum level and reduces the flow of oil into the well. In fact, formation damage is the collapse of natural condition of reservoirs, In addition to delaying production and increasing costs, it causes early desertification of wells. Well stimulation methods are used to solve this problem and increase production. One of the most effective ways to increase the production of wells is well acidizing. In this study, the acid performance of the fractured carbonate reservoirs has been investigated. In this type of reservoirs, due to the existence of high permeable paths of the... 

Given the decreasing trend of light petroleum reserves and the necessity to produce heavy and extra-heavy oil resources, the challenge of dealing with existing asphaltene related problems, which is the heaviest and the most complex component of crude oil, has become increasingly tangible. Asphaltene precipitates and deposits due to pressure, temperature or composition alterations which leads to obstruction of porous media and production facilities. Set the costly methods aside, one of the available approaches to prevent asphaltene precipitation, is to apply an electric field upon the suspected zone, which is cheap and uncomplicated. Besides, utilizing nano-particles while applying electric... 

Matrix acidizing operation is one of the popular methods of well stimulation in the oil and gas industry which is used to remove near wellbore damage, increase the permeability, hence improve the production rate from the formation. Hydrochloric acid is used in the carbonate reservoirs to remove formation damage and create wormhole deep in the rock. It has been shown that with the proper operating design, significant improvement in the production rate can be obtained. A successful acid operations involves the proper selection of the candidate wells, identify the type of formation damage, stimulation method selection, correct design acidizing scenario, implementation of the technique and... 

In this research, the characteristics of non-Newtonian, shear-thinning drop formation containing surfactant from a needle are investigated experimentally. The ambient fluid is air and all experiments have been conducted in a constant flow rate of drop phase fluid. Images of forming drop are taken using a high-speed camera and by processing them, important parameters in drop formation such as length of drop, minimum neck thickness, formation time and the size of satellite drops have been studied. Three non-Newtonian and three Newtonian fluids are considered in a way that the initial viscosity of non-Newtonian fluids would be equal to the viscosity of their corresponding Newtonian fluids.... 

Application of nanotechnology in the field of heat transfer has increased recently. The need to increase heat transfer rate yet decrease the size of cooling equipment, brought about lots of attention to thermal properties of Nanofluids. Nanofluid is the suspension of nanometer-sized solid particles in base liquid. Research on convective heat transfer of nanofluids which is only two decades old, shows great potential in increasing heat transfer rate. Although there is a remarkable research on thermal conductivity of Nanofluids, negligible research was conducted on combined Nanofluids . Developed Theory for thermal conductivity of combined nanofluid can be used to modeling the thermal... 

Fractured carbonate reservoirs are mostly oil-wet to intermediate-wet. Due to the negative capillary pressure of the matrix poor spontaneous imbibition of reservoir brine occurs in such reservoirs, and water flooding leads into early break through due to the high conductivity of the fracture network. Some surfactants have the ability to change the wettability of rock matrix toward water-wet state by adsorbing onto the rock surface. The phenomenon can result in spontaneous imbibition improvement and thereby increasing water flooding efficiency and recovery from fractured carbonate reservoirs. In this thesis the effect of some surfactants on the wettability of Iranian carbonate reservoir rocks...