Sharif Digital Repository

A method of joining dissimilar metals in the semi solid state is presented. By this method bonding of Stainless steel and semisolid aluminum alloy took place in this research. By usage of thermomechanical treatment, dendritic microstructure of cast aluminum alloy changed to globular structure. The experimental process of bonding occurred at semisolid temperature stage of aluminum alloy in a predesigned mold by using a pressure equipment. The relationship between interfacial shear strength and solid fraction of aluminum alloy, bonding pressure and time of keeping pressure were studied by method of orthogonal experiment. By the usage of Taguchi method in designing experiments, plurality of... 

In this study AZ91 alloy reinforced by SiC particles processed by semi-solid casting was produced by using electromagnetic stirrer. In order to prevent ignition and oxidation of the melted AZ91 alloy 1 Wt.% of calcium was added to the melt. In order to surface oxidation of SiC particles, they were heat treated in 1100 ᵒC for 2 hours before adding to the melt. Different methods of adding SiC particles to the melt were investigated. Particle distribution in the matrix was studied qualitatively and quantitatively using microscopic images and image analysis, respectively. It is shown that higher amount of reinforcement particle need to be added to the melt in multi-steps. Frequency versus... 

In this research the effects of cooling slope angle and the temperature of molten steel on globular structure after holding the samples at semisolid state have been investigated. The globular structure of high speed steel in the form of rolled - annealed and as cast condition, has been investigated in the semisolid state. The results showed that the grain sizes of cooling slope samples were lower than the rolled- annealed samples after holding at semisolid temperature. On the other hand, rolled-annealed solid grains had better roundness compared with cooling slope samples. Dissolution of carbides in the austenite phase at grain boundary leads to formation of globular particles in the... 

In the last decade, magnesium alloy has been developed owing to it’s low density, high specific strength, good castability and damping property. AZ91 alloy is proved to be the most common and most important magnesium casting alloy. It is shown that, rheocasting process is a proper way which increases the mechanical properties of the products. Since 28 years, so many new methods for preparing Semi-Solid alloy slurry and rheoforming process have been suggested. Electromagnetic Stirring ( EMS ) method was used for making globular structures. In this research, the semi-solid slurry of AZ91 magnesium alloy was prepared by electromagnetic stirrer under different conditions of stirring current and... 

We demonstrated efficient direct electron transfer from the enzyme glucose oxidase to vertically aligned gold nanorods with a diameter of ~160 nm and a length of ~2 μm that are covalently linkage to a 3-dimensional network of reduced graphene oxide nanosheets. The assembly can be prepared by a 2-step electrochemical procedure. This hybrid structure holds the enzyme in a favorable position while retaining its functionality that ultimately provides enhanced performance for enzymatic sensing of glucose without utilizing mediators. The nanorod assembly was applied to the voltammetric detection of glucose. Figures of merit include an electrochemical sensitivity of 12 µA⋅mM-1⋅cm-2 (obtained from... 

Production of semi solid slurry and creating the globular alloy structure is possible in the ways of Electromagnetic stirring and Gas induced semi solid, which are used widely in industrial scale. Because of the weak magnetic field in the middle part of stirrer, this part is being emptied of melt. As a result, The porous graphite cone is used in this part in order to inject the gas bubbles.In this research, the semi solid A356 Aluminum alloy, is produced under different durations and stirring flux using a three phase Electromagnetic stirrer and injection of the Argon gas. Consequently the slurry was transferred to a mold and compacted by a drop weight. By investigating and analyzing the... 

In this study, the effects of calcium addition and T4 heat treatment at 450°C for 36 hours on the microstructure, mechanical properties, and corrosion resistance of the Mg-2.5Y alloy were comprehensively investigated. The studied alloys included the base Mg-2.5Y alloy and the Mg-2.5Y-0.2Ca alloy, which were prepared through casting. Microstructural analysis using optical microscopy, scanning electron microscopy, and X-ray diffraction revealed that the addition of 0.2 wt% calcium significantly reduced the grain size from 732±34 µm in the base alloy to 475±12 µm. After heat treatment, the dissolution of dendritic branches and secondary phases (Mg24Y5 and Mg2Ca) resulted in finer, more equiaxed... 

Several studies are already on severe plastic deformation of wrought and cast aluminum alloys. Among these studies, no evidence of applying severe plastic deformation on the structure of rheocast or rheoforgedaluminum alloy can be found. So, in this research A356 alloy with globular structure was achieved using electromagnetic stirring and rheoforging. The optimum condition of globular structure with high sphericity was achievedafter holding the produced structure in semi-solid state for 10 min. Then, the effect of severe plastic deformation on mechanical and microstructural properties of this alloy and cast alloy was studied. The results show that with applying 3 passes of multidirectional... 

The microstructure and wear performance of WC/Cu-Zn-Ni composite surface coating has been investigated using a combination of microscopy, hardness, and wear testing. The oxidation behavior of tungsten carbide hard metal in the temperature range between 600 and 900 ◦C was also researched. The oxidation mass gain of WC correlated almost directly with temperature as well as time. The particle of hard metal is surrounded by the α Cu+β Zn phase in the surface coating. The size of hard metal is almost unchanged from its original one. There exists an inter-diffusion zone at the interface of the hard metals and Cu-based matrix. The wear volume of the WC/Cu-Zn-Ni composite surface coatings increased... 

Multi-principle alloys exhibit microstructure and different properties from most conventional alloys due to their high entropy, very slow diffusion and distorted crystal structure properties. Heat treatment, thermomechanical treatment, addition of alloying elements and control of solidification process are common methods of microstructure modification and property improvement. Among the solidification parameters, undercooling and cooling rate is one of the most suitable methods to obtain semi-stable and fine-grained phases. These parameters have been less studied in multi-principle alloys, while in the case of ferrous and cobalt alloys has been much studied. The main purpose of this type of... 

Bulk metallic glasses (BMGs), in contrast to conventional crystalline materials, are defined as metals with an amorphous and disordered atomic-scale structure. Due to the absence of dislocations and grain boundaries, BMGs have considerably unique mechanical properties such as high strength and elastic strain, high wear resistance and desirable corrosion resistance. However, they generally suffer from poor plasticity caused by an inhomogeneous deformation which leads to catastrophic failure by localization of strain into narrow regions, known as shear bands. This factor has extremely restricted their application as advanced structural materials. Furthermore, the recently discovered phenomenon...