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Numerical investigation of effects of uniform magnetic field on heat transfer around a sphere
, Article International Journal of Heat and Mass Transfer ; Volume 114 , 2017 , Pages 703-714 ; 00179310 (ISSN) ; Molaei Dehkordi, A ; Abbasi, F ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
In this article, ferrohydrodynamic forced-convection heat transfer from a heated sphere embedded in a ferrofluid in the presence of the uniform external magnetic field has been studied numerically for the first time over a wide range of Reynolds number value, nanoparticle diameter, particle volume fraction, and magnetic field intensity. Despite the uniform external magnetic field applied, the internal magnetic field near the sphere could be nonuniform due to the considerable difference between the relative magnetic permeability of the sphere and the surrounding medium. Kelvin body force arises from this nonuniformity and induces vortexes near the sphere. These vortexes disturb the boundary...
A method for simulation of vapour cloud explosions based on computational fluid dynamics (CFD)
, Article Journal of Loss Prevention in the Process Industries ; Volume 24, Issue 5 , 2011 , Pages 638-647 ; 09504230 (ISSN) ; Rashtchian, D ; Abbasi, T ; Abbasi, S.A ; Sharif University of Technology
2011
Abstract
The effectiveness of the application of CFD to vapour cloud explosion (VCE) modelling depends on the accuracy with which geometrical details of the obstacles likely to be encountered by the vapour cloud are represented and the correctness with which turbulence is predicted. This is because the severity of a VCE strongly depends on the types of obstacles encountered by the cloud undergoing combustion; the turbulence generated by the obstacles influences flame speed and feeds the process of explosion through enhanced mixing of fuel and oxidant. In this paper a CFD-based method is proposed on the basis of the author's finding that among the various models available for assessing turbulence, the...
Thin film graphene oxide membrane: challenges and gas separation potential
, Article Korean Journal of Chemical Engineering ; Volume 35, Issue 5 , May , 2018 , Pages 1174-1184 ; 02561115 (ISSN) ; Karimi Sabet, J ; Ghotbi, C ; Abbasi, Z ; Sharif University of Technology
Springer New York LLC
2018
Abstract
Graphene oxide membranes were prepared by vacuum and pressurized ultrafiltration methods on the 12% modified Polyacrylonitrile (12mPAN) substrate to specify challenges, salient features, future directions, and potential of GO membrane for separation fields using characterization techniques and gas separation test (studied gases are CO2, He and N2), which is an efficient tool for better understanding of GO membrane behavior. GO membrane structure was examined over a wide range of parameters, such as pore size range of substrate and its surface properties, pH of GO dispersion, GO content, synthesis pressure, operating pressure and temperature. The results show that the GO content does not hold...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; Volume 16, Issue 7 , 2022 , Pages 1139-1148 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2022
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Improved method for increasing accessible pores of MIL-101(Cr) by encapsulation and removal of Phosphotungstic acid (PTA): Pd/PTA-MIL-101(Cr) as an effective catalyst for CO oxidation
, Article Journal of Cleaner Production ; Volume 347 , 2022 ; 09596526 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
This study forwards a novel and simple approach for encapsulation of Phosphotungstic acid (PTA) into MIL-101(Cr) cavities to develop PTA-MIL-101(Cr) with a high surface area. In this method, the resulting surface area of PTA-MIL-101(Cr) (3563 m2/g) is 1.72 times that of MIL-101(Cr) due to the existence of more accessible pores which are formed by leaching of PTAs incorporated inside MIL-101(Cr) pores during the intense washing. Catalysts are investigated in CO oxidation under atmospheric pressure and feed composition of 1%CO, 20%O2, and 79%He. 3%Pd/PTA-MIL-101(Cr) shows 100%CO conversion at T = 145 °C and outperforms PTA, PTA-MIL-101(Cr), Pd/PTA, 1–3%Pd/MIL-101(Cr), Pd-PTA/MIL-101(Cr), and...
Investigation into the effects of weld zone and geometric discontinuity on the formability reduction of tailor welded blanks
, Article Computational Materials Science ; Volume 59 , 2012 , Pages 158-164 ; 09270256 (ISSN) ; Ketabchi, M ; Ramazani, A ; Abbasi, M ; Prahl, U ; Sharif University of Technology
2012
Abstract
Numerous advantages of application of tailor welded blanks (TWBs) in automobile industry, namely reduction of weight, fuel consumption and air pollution, have made the manufacturers eager to investigate in this field. On the other hand, while experiments generally provide valuable information in regard with mechanical behaviors, but utilization of simulation methods has extended vastly due to time and cost saving issues. One challenging issue in numerically analyzing the forming behavior of transversely welded TWBs, welded by laser welding methods, has been the presence of weld zone. While some researchers believe that during simulation, the weld zone can be neglected due to its minority and...
Fabrication of Graphene-WO3 Nanocomposites as Photocatalyst in the Visible Light Region
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
WO3 is known as a photocatalyst in the visible light region, but with lower efficiency compared to more interesting semiconductor photocatalysts such as TiO2 and ZnO. Many attempts have been done to increase the efficiency of this photocatalyst by incorporating metal and metal oxide nanoparticles or recently carbon nanotubes.On the other hand, application of graphene, as an unrolled carbon nanotube, for increasing the photocatalytic activity of TiO2 and ZnO has shown positive results. Furthermore, it was reported that such semiconductor photocatalysts (and very recently WO3) can photocatalytically reduce the chemically exfoliated graphene oxide sheets under UV-vis irradiation.
In this...
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Synthesize of Graphene Nanoribbons with a Non-Zero Energy Band Gap for Inactivation of Alive Cells Using Infrared Irradiation
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene is a one layer atom thickness and zero energy gap so for using it in nano electronic and transistors baised on graphene it's energy gap should be opened.one of the methods for opening graphene band gap is creating nano scale boundaries or synthesize graphene nanoribbons. One of the new methods for graphene nanoribbon synthesize is longitudinal opening of carbon nanotube. In this thesis graphene nanoribbons synthesize with this method and analyze with AFM and Raman spectroscopy. Carbon nanotubes also have energy gap and IR absorption recently they used for living cell destruction. In this thesis we synthesize graphene nanoribbons and analyzing their optical absorption and use it for...
Fabrication of Graphene/TiO2 Nanowalls as Visible Lights Photocatalysts
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
TiO2 is known as a photocatalyst in near UV-Visible light region with better efficiency compared to other semiconductor photocatalysts. Many attempts have been done to increase the efficiency of this photocatalyst. also, application of 2D carbon nanostructures namely graphene for increasing the photocatalytic activity of TiO2 has shown positive results.
In this research, we first synthesized Graphene Oxide (GO) suspension by exfolation of graphite oxide suspension. then we fabricated TiO2 thin films on glass substrates by so-called sol-gel method. finally we fabricate Graphene Oxide/TiO2 nanowalls composite films as a photocatalyst in visible light. X-ray photoelectron spectroscopy...
In this research, we first synthesized Graphene Oxide (GO) suspension by exfolation of graphite oxide suspension. then we fabricated TiO2 thin films on glass substrates by so-called sol-gel method. finally we fabricate Graphene Oxide/TiO2 nanowalls composite films as a photocatalyst in visible light. X-ray photoelectron spectroscopy...
Synthesis of Graphene Nanosheets for Stem Cells Applications
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene nanogrids fabricated by graphene nanoribbons obtained through oxidative unzipping of multi-walled carbon nanotubes, used as two-dimensional selective templates for accelerated differentiation of human mesenchymal stem cells (hMSCs), isolated from umbilical cord blood, into osteogenic lineage. The biocompatible and hydrophilic graphene nanogrids showed high actin cytoskeleton proliferations that coinciding with patterns of the nanogrids. The amounts of proliferations found are slightly better than proliferation on hydrophilic graphene oxide (GO) sheets, and significantly higher than non-uniform proliferations on hydrophobic reduced graphene oxide (rGO) sheets and polydimethylsiloxane...
Synthesis of Graphene from Waste by Chemical Exfoliation and Study of It’s Physical Characteristics
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
One atom thick layer of pure carbon in bonded and hexagonal lattice is named graphene. graphene has unique mechanical, optical, thermal and electrical properties and because of these properties has grabbed attention. graphene has been made from high pure graphite by different methods such as CVD(chemical vapor deposition) , chemical exfoliation , micromechanical cleavage and colloidal suspension. through these methods, green methods for synthesis of graphene, using eco-friendly reductants during synthesis of graphene instead of hydrazine and recently using waste(not graphite) are attractive for synthesis of graphene. Following this idea , a group has produced graphene from wastes such as...
Synthesis of Graphene Oxide and Study of its Fluorescence Properties
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene oxide is a single sheet of Carbon atoms which has been arranged on a two-dimensional honeycomb lattice. Functional groups such as epoxy, carboxyl and carbonyl are located on basal plane and at the edges of graphene oxide and they localize electrons on the surface of graphene oxide and open band gap in its band structure. Pure graphene has zero band gap, so existence of fluorescence properties is unlikely; but graphene oxide has fluorescence properties due to band gap in its band structure. Fluorescence properties of graphene have been used in live cell imaging and drug delivery, so study and increasing of fluorescence properties is significantly important. The purpose of this...
The Use of Hydrogen Rich Water for Synthesis of Hydrogenized Graphene and Investigation of Its Properties
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Graphene is a two dimensional lattice which is created from carbon atoms. Having special feature, it has such various medical usage, for example in diagnosing and treating cancer. Adding a particular factor to graphene could improve their efficiency. In comparis on with graphene itself, graphene oxide and reduced graphene oxide are much more successful in diagnosing and treating than others because of their higher hygroscopic. Recent studies state that hydrogenized combinations including hydrogenized graphene show desired results. Due to its higher hygroscopic and the possibility of adherence to the cells, hydrogenized graphene could be very effective in diagnosing and treating the sarcomas....
A Meta Heuristic Approach for Design of a Network System in Mass Customization
, M.Sc. Thesis Sharif University of Technology ; Fattahi, Omid (Supervisor)
Abstract
This study discusses about mass customization and optimization of supply network in which both goal considering to set the flow of raw material and final product to satisfy the customer demand. The mass customization is more important concept in this study, so that this goal is placed to the first objective. In this research, the model which contained both goal is presented. The model focus on mass customization and try to satisfy various products demand, which constitute 3 kind of speed demands. Each product can satisfy in 3 way: fast, normal, slow.In the first model the new approach present in which the speed affects all of supplying, manufacturing and distributing system. The system try...
Identifying the risks of Iranian Knowledge BasedFirms Using Fault Tree Analysis (FTA)
, M.Sc. Thesis Sharif University of Technology ; Fattahi, Omid (Supervisor)
Abstract
Knowledge Based Firms are considered to be important for the economic development of a country in regards to both employment growth and innovative activity. The latter is believed to contribute significantly to the increase in productivity and therefore the competitiveness of Iran’s economy. This study contributes to the above literature by investigating the factors that are believed to treat the growth of such firms in Iran. The purpose of this study is to identify functional risks of vital signs monitors via Fault Tree Analysis (FTA) method to use as a guide for manufacturers to identify and control hazards. Therefore, 30 knowledge based firms were selected as sample. Then, based on a...
A Novel Reliability Model for Information Technology Web services
, M.Sc. Thesis Sharif University of Technology ; Fatahi Valilai, Omid (Supervisor)
Abstract
The Internet is often used for communication-based applications such as online banking, stock trading, and shopping where service interruption is unacceptable. Thus, analysis of the impact of the failures of hardware, software, and related services’ performance quality of the service provided to users is of importance to designers and managers in these functions. In this study, we developed a strategy to the design of a dynamic combination of file servers with the aim of providing reliability and SLA. At first, we examine the reasons for the violation of service level in file host services and datacenters, and then we introduce the criteria to measure the violation of service level on the...
A neural network applied to estimate process capability of non-normal processes
, Article Expert Systems with Applications ; Volume 36, Issue 2 PART 2 , 2009 , Pages 3093-3100 ; 09574174 (ISSN) ; Sharif University of Technology
2009
Abstract
It is always crucial to estimate process capability index (PCI) when the quality characteristic does not follow normal distribution, however skewed distributions come about in many processes. The classical method to estimate process capability is not applicable for non-normal processes. In the existing methods for non-normal processes, probability density function (pdf) of the process or an estimate of it is required. Estimating pdf of the process is a hard work and resulted PCI by estimated pdf may be far from real value of it. In this paper an artificial neural network is proposed to estimate PCI for right skewed distributions without appeal to pdf of the process. The proposed neural...
Application of the GTN model to predict the forming limit diagram of IF-Steel
, Article Journal of Mechanical Science and Technology ; Volume 26, Issue 2 , February , 2012 , Pages 345-352 ; 1738494X (ISSN) ; Shafaat, M. A ; Ketabchi, M ; Haghshenas, D. F ; Abbasi, M ; Sharif University of Technology
2012
Abstract
Forming limit diagrams (FLDs) are extensively used in industries, particularly the auto industry. The establishment of these diagrams using a predictive approach can lead to reduction in both cost and time. In the present work, Gurson-Tvergaard-Needleman (GTN), a porosity-based model, was used to predict the FLD of an interstitial-free steel via finite element simulation. Optimum values of the GTN model were obtained by applying a response surface methodology (RSM) based on central composite design. Results show that RSM is a good method for an appropriate determination of the GTN model parameters, such as initial void volume fraction, effective void volume fraction, critical void volume...