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Investigation of Cathodic Parameters on the Performance of Microbial Electrolysis Cell
, M.Sc. Thesis Sharif University of Technology ; Kariminia, Hamid-Reza (Supervisor)
Abstract
Microbial electrolysis cell is a novel technology for hydrogen production. The biggest challenges for this new technology are low rate of hydrogen production and high investment cost.
In this research, catholite condition was investigated for increasing the rate of hydrogen production. Low price stainless steel was used as cathode electrod. The microbial electrolysis cell operated applying 1.3 v external voltage. Basic pH was found to be the best condition for maximum rate of hydrogen production, where the average rate of hydrogen production was 100.006 1.866 L/m3.d. However, the hydrogen production rate for the acidic and neutral cathodic condition, were 92.89 1.13 and 91.845 1.485...
In this research, catholite condition was investigated for increasing the rate of hydrogen production. Low price stainless steel was used as cathode electrod. The microbial electrolysis cell operated applying 1.3 v external voltage. Basic pH was found to be the best condition for maximum rate of hydrogen production, where the average rate of hydrogen production was 100.006 1.866 L/m3.d. However, the hydrogen production rate for the acidic and neutral cathodic condition, were 92.89 1.13 and 91.845 1.485...
Numerical Study of Spray Impingement to Solid Wall
, M.Sc. Thesis Sharif University of Technology ; Morad, Mohammad Reza (Supervisor) ; Jahannama, Mohammad Reza (Co-Supervisor)
Abstract
Spray-wall impingement is one of the phenomenon that associated in different subject such as spray cooling, combustion chamber and gas turbine. With the impingement of spray to the wall, liquid film begins to form. Wall film characteristics is still an important subject to study. Due to the various stages of liquid film formation from injection of spray till spray-wall impingement, the investigation of this phenomenon is far more complicated. This paper is meant to provide detailed data on spray-wall impingement and wall film formation physics with the help of computational analysis of OpenFOAM . A Lagrangian-Eulerian method based on discrete phase model (DPM) was employed to model...
A Novel Context-Aware Model to Improve Quality of Recommender Systems
, M.Sc. Thesis Sharif University of Technology ; Rabiei, Hamid Reza (Supervisor) ; Jalili, Mahdi (Co-Advisor)
Abstract
As the amount of data on the Internet grows, users face diverse options while searching for their desired information and items. Therefore, accessing what one is looking for, is usually time consuming and even impossible in some cases. In order to solve this issue, the goal of recommender systems is to offer recommendations which are compatible with users’ needs and preferences. One of the most important challenges of recommender systems is to improve the quality of recommendations. Recommender systems’ quality can be assessed using different metrics including precision, novelty and coverage. However, these metrics are inconsistent in some applications and improving one will cause a decline...
Spectrophotometric Determination of Copper Ions and Pamidronate Disodium Based on Changing the Surface Plasmon Resonance Band of Au Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Hormozi-Nezhad, Mohammad Reza (Supervisor)
Abstract
In recent years, metallic nanoparticles, specially gold and silver nanoparticles, have received great attention for biological and metal ions analysis, due to the surface plasmon resonance phenomena. Gold nanoparticles (AuNPs) have recently gained much interest in colorimetric probe based on aggregation or anti-aggregation of AuNPs, due to their simplicity and having high order of magnitude extinction coefficients, in addition to the dependence of surface plasmon resonance wavelength and intensity on the interparticles distances. In the first part of this thesis, a highly sensitive colorimetric method for detection of copper ions based on anti-aggregation of citrate capped AuNPs was...
Numerical investigation of effects of uniform magnetic field on heat transfer around a sphere
, Article International Journal of Heat and Mass Transfer ; Volume 114 , 2017 , Pages 703-714 ; 00179310 (ISSN) ; Molaei Dehkordi, A ; Abbasi, F ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
In this article, ferrohydrodynamic forced-convection heat transfer from a heated sphere embedded in a ferrofluid in the presence of the uniform external magnetic field has been studied numerically for the first time over a wide range of Reynolds number value, nanoparticle diameter, particle volume fraction, and magnetic field intensity. Despite the uniform external magnetic field applied, the internal magnetic field near the sphere could be nonuniform due to the considerable difference between the relative magnetic permeability of the sphere and the surrounding medium. Kelvin body force arises from this nonuniformity and induces vortexes near the sphere. These vortexes disturb the boundary...
A method for simulation of vapour cloud explosions based on computational fluid dynamics (CFD)
, Article Journal of Loss Prevention in the Process Industries ; Volume 24, Issue 5 , 2011 , Pages 638-647 ; 09504230 (ISSN) ; Rashtchian, D ; Abbasi, T ; Abbasi, S.A ; Sharif University of Technology
2011
Abstract
The effectiveness of the application of CFD to vapour cloud explosion (VCE) modelling depends on the accuracy with which geometrical details of the obstacles likely to be encountered by the vapour cloud are represented and the correctness with which turbulence is predicted. This is because the severity of a VCE strongly depends on the types of obstacles encountered by the cloud undergoing combustion; the turbulence generated by the obstacles influences flame speed and feeds the process of explosion through enhanced mixing of fuel and oxidant. In this paper a CFD-based method is proposed on the basis of the author's finding that among the various models available for assessing turbulence, the...
Thin film graphene oxide membrane: challenges and gas separation potential
, Article Korean Journal of Chemical Engineering ; Volume 35, Issue 5 , May , 2018 , Pages 1174-1184 ; 02561115 (ISSN) ; Karimi Sabet, J ; Ghotbi, C ; Abbasi, Z ; Sharif University of Technology
Springer New York LLC
2018
Abstract
Graphene oxide membranes were prepared by vacuum and pressurized ultrafiltration methods on the 12% modified Polyacrylonitrile (12mPAN) substrate to specify challenges, salient features, future directions, and potential of GO membrane for separation fields using characterization techniques and gas separation test (studied gases are CO2, He and N2), which is an efficient tool for better understanding of GO membrane behavior. GO membrane structure was examined over a wide range of parameters, such as pore size range of substrate and its surface properties, pH of GO dispersion, GO content, synthesis pressure, operating pressure and temperature. The results show that the GO content does not hold...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; Volume 16, Issue 7 , 2022 , Pages 1139-1148 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2022
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Improved method for increasing accessible pores of MIL-101(Cr) by encapsulation and removal of Phosphotungstic acid (PTA): Pd/PTA-MIL-101(Cr) as an effective catalyst for CO oxidation
, Article Journal of Cleaner Production ; Volume 347 , 2022 ; 09596526 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
This study forwards a novel and simple approach for encapsulation of Phosphotungstic acid (PTA) into MIL-101(Cr) cavities to develop PTA-MIL-101(Cr) with a high surface area. In this method, the resulting surface area of PTA-MIL-101(Cr) (3563 m2/g) is 1.72 times that of MIL-101(Cr) due to the existence of more accessible pores which are formed by leaching of PTAs incorporated inside MIL-101(Cr) pores during the intense washing. Catalysts are investigated in CO oxidation under atmospheric pressure and feed composition of 1%CO, 20%O2, and 79%He. 3%Pd/PTA-MIL-101(Cr) shows 100%CO conversion at T = 145 °C and outperforms PTA, PTA-MIL-101(Cr), Pd/PTA, 1–3%Pd/MIL-101(Cr), Pd-PTA/MIL-101(Cr), and...
Investigation into the effects of weld zone and geometric discontinuity on the formability reduction of tailor welded blanks
, Article Computational Materials Science ; Volume 59 , 2012 , Pages 158-164 ; 09270256 (ISSN) ; Ketabchi, M ; Ramazani, A ; Abbasi, M ; Prahl, U ; Sharif University of Technology
2012
Abstract
Numerous advantages of application of tailor welded blanks (TWBs) in automobile industry, namely reduction of weight, fuel consumption and air pollution, have made the manufacturers eager to investigate in this field. On the other hand, while experiments generally provide valuable information in regard with mechanical behaviors, but utilization of simulation methods has extended vastly due to time and cost saving issues. One challenging issue in numerically analyzing the forming behavior of transversely welded TWBs, welded by laser welding methods, has been the presence of weld zone. While some researchers believe that during simulation, the weld zone can be neglected due to its minority and...
Developments of Fluorescence Sensor Arrays Using Nanostructured Sensor Elments and Nanocellulose Substrate for Identification and Discrimination of Biomolecules and Environmental pollutants
, Ph.D. Dissertation Sharif University of Technology ; Hormozi-Nezhad, Mohammad Reza (Supervisor) ; Golmohammadi Ghaneh, Hamed (Co-Supervisor)
Abstract
In the first part of this research, a ratiometric fluorescent sensor array has been developed on nanocellulose platform towards chemical discrimination applications. Bacterial nanocellulose (BC) was utilized for the first time as a novel, flexible and transparent substrate in optical sensor arrays for developing portable and high performance sensor array.. To fabricate this platform, the hydrophobic walls on BC nanopaper substrates were successfully created using laser printing technology. In addition, we have used the properties of immobilized ratiometric fluorescence sensor elements (Carbon Dots- Rhodamine B (CDs-RhB) nanohybrids) on nanopaper platform to improve the visual...
A neural network applied to estimate process capability of non-normal processes
, Article Expert Systems with Applications ; Volume 36, Issue 2 PART 2 , 2009 , Pages 3093-3100 ; 09574174 (ISSN) ; Sharif University of Technology
2009
Abstract
It is always crucial to estimate process capability index (PCI) when the quality characteristic does not follow normal distribution, however skewed distributions come about in many processes. The classical method to estimate process capability is not applicable for non-normal processes. In the existing methods for non-normal processes, probability density function (pdf) of the process or an estimate of it is required. Estimating pdf of the process is a hard work and resulted PCI by estimated pdf may be far from real value of it. In this paper an artificial neural network is proposed to estimate PCI for right skewed distributions without appeal to pdf of the process. The proposed neural...
Application of the GTN model to predict the forming limit diagram of IF-Steel
, Article Journal of Mechanical Science and Technology ; Volume 26, Issue 2 , February , 2012 , Pages 345-352 ; 1738494X (ISSN) ; Shafaat, M. A ; Ketabchi, M ; Haghshenas, D. F ; Abbasi, M ; Sharif University of Technology
2012
Abstract
Forming limit diagrams (FLDs) are extensively used in industries, particularly the auto industry. The establishment of these diagrams using a predictive approach can lead to reduction in both cost and time. In the present work, Gurson-Tvergaard-Needleman (GTN), a porosity-based model, was used to predict the FLD of an interstitial-free steel via finite element simulation. Optimum values of the GTN model were obtained by applying a response surface methodology (RSM) based on central composite design. Results show that RSM is a good method for an appropriate determination of the GTN model parameters, such as initial void volume fraction, effective void volume fraction, critical void volume...
Experimental Studies on Biodiesel Production Using Waste Frying Oil in a Hetergogeneous Catalytic Reaction
, M.Sc. Thesis Sharif University of Technology ; Kariminia, Hamid Reza (Supervisor) ; Shaygan Salek, Jalaloddin (Supervisor) ; Pazouki, Mohammad (Co-Advisor)
Abstract
Biodiesel can be a good alternative for fossil diesel since it isrenewable, biodegradable and non-toxic. Also, in comparison with fossil fuels, it emits less air pollutants and greenhouse gases.Findacost effective and environmentally friendly wayforcontinuousproductionofbiodieselcanaddressmany of our environmental concerns. In this study, we applied heterogeneous alkali-catalyzed transesterification as method and used waste frying oil as a low cost feedstock for biodiesel production. The project was performed in two phases. First, experiments were conducted in astirred reactor to finda suitable catalyst which was strontium carbonate calcinated for 3:24 hours in 975̊C.
RPB(rotating...
RPB(rotating...
Improving response surface methodology by using artificial neural network and simulated annealing
, Article Expert Systems with Applications ; Volume 39, Issue 3 , February , 2012 , Pages 3461-3468 ; 09574174 (ISSN) ; Mahlooji, H ; Sharif University of Technology
2012
Abstract
Response surface methodology (RSM) explores the relationships between several explanatory variables and one or more response variables. The main idea of RSM is to use a set of designed experiments to obtain an optimal response. RSM tries to simplify the original problem through some polynomial estimation over small sections of the feasible area, elaborating on optimum provision through a well known optimization technique, say Gradient Method. As the real world problems are usually very complicated, polynomial estimation may not perform well in providing a good representation of the objective function. Also, the main problem of the Gradient Method, getting trapped in local minimum (maximum),...
Moving quark in a viscous fluid
, Article Journal of High Energy Physics ; Volume 2012, Issue 6 , 2012 ; 11266708 (ISSN) ; Davody, A ; Sharif University of Technology
Springer
2012
Abstract
To study the rate of energy and momentum loss of a heavy quark in QGP, specifically in the hydrodynamic regime, we use fluid/gravity duality and construct a perturbative procedure to find the string solution in gravity side. We show that by this construction, the position of the world-sheet horizon and thereby the drag force exerted on the quark can be computed perturbatively, order by order in a boundary derivative expansion, for a wide range of quark velocities. At ideal order, our result is just the localized expression of the drag force exerted on a moving quark in thermal plasma, while for a quark whose velocity does not belong to the mentioned range, we predict a nonlocal drag force....
Moving quark in a general fluid dynamical flow
, Article Journal of High Energy Physics ; Volume 2013, Issue 12 , December , 2013 ; 11266708 (ISSN) ; Davody, A ; Sharif University of Technology
Springer Heidelberg
2013
Abstract
We determine the most general form of the covariant drag force exerted on a quark moving through a fluid dynamical flow. Up to first order in derivative expansion, our general formula requires the specification of seven coefficient functions. We use the perturbative method introduced in arXiv:1202.2737 and find all these coefficients in the hydrodynamic regime of a N = 4 SYM plasma. Having this general formula, we can obtain the rate of the energy and momentum loss of a quark, namely the drag force, in a general flow. This result makes it possible to perturbatively study the motion of heavy quarks moving through the Bjorken flow up to first order in derivative expansion
Production planning and performance optimization of reconfigurable manufacturing systems using genetic algorithm
, Article International Journal of Advanced Manufacturing Technology ; Volume 54, Issue 1-4 , 2011 , Pages 373-392 ; 02683768 (ISSN) ; Houshmand, M ; Sharif University of Technology
2011
Abstract
To stay competitive in the new dynamic market having large fluctuations in product demand, manufacturing companies must use systems that not only produce their goods with high productivity but also allow for rapid response to market changes. Reconfigurable manufacturing system (RMS) is a new paradigm that enables manufacturing systems to respond quickly and cost effectively to market demand. In other words, RMS is a system designed from the outset, for rapid changes in both hardware and software components, in order to quickly adjust its production capacity to fluctuations in market demand and adapt its functionality to new products. The effectiveness of an RMS depends on implementing its...