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abbasi-kamran--ehsan
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Synthesis, and Characterization of Binuclear Platinum (IV)with Coinage Metals
, M.Sc. Thesis Sharif University of Technology ; Jamali, Sirous (Supervisor)
Abstract
In this research binuclear platinum(IV) complexes with coinage metals have been synthesized and characterized. the trimethyl platinum(IV) complex [PtMe3(phthalazine)3]+X- has been prepared by the reaction of [PtMe3(THF)]4 with 3 equiv. phthalazine and used as initial material. The first complex, [PtMe3(µ-(phthalazine)2Cl)PtMe3], synthesized via reaction of 2 equiv. [Pt(Me)3(Phthalazine)3] with 1 equiv. [AuClSMe2]. The second complex, [PtMe3(µ-phthalazine)3Ag][BF4], synthesized by reaction of one equiv. of each compound [Ag(CH3CN)4]BF4 and [Pt(Me)3(Phthalazine)3] And the third complex, [PtMe3(µ-phthalazine)3Cu][PF6], synthesized like second one via reaction of [Cu(CH3CN)4]PF6 and...
Numerical investigation of effects of uniform magnetic field on heat transfer around a sphere
, Article International Journal of Heat and Mass Transfer ; Volume 114 , 2017 , Pages 703-714 ; 00179310 (ISSN) ; Molaei Dehkordi, A ; Abbasi, F ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
In this article, ferrohydrodynamic forced-convection heat transfer from a heated sphere embedded in a ferrofluid in the presence of the uniform external magnetic field has been studied numerically for the first time over a wide range of Reynolds number value, nanoparticle diameter, particle volume fraction, and magnetic field intensity. Despite the uniform external magnetic field applied, the internal magnetic field near the sphere could be nonuniform due to the considerable difference between the relative magnetic permeability of the sphere and the surrounding medium. Kelvin body force arises from this nonuniformity and induces vortexes near the sphere. These vortexes disturb the boundary...
Dark silicon and the history of computing
, Article Advances in Computers ; Volume 110 , 2018 , Pages 1-33 ; 00652458 (ISSN); 9780128153581 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2018
Abstract
For many years, computer designers benefitted from Moore's law and Dennard scaling to significantly improve the speed of single-core processors. The failure of Dennard scaling pushed the computer industry toward homogenous multicore processors for the performance improvement to continue without significant increase in power consumption. Unfortunately, even homogeneous multicore processors cannot offer the level of energy efficiency required to operate all the cores at the same time in today's and especially tomorrow's technologies. As a result of lack of energy efficiency, not all the cores in a multicore processor can be functional at the same time. This phenomenon is referred to as dark...
Temporal prefetching
, Article Advances in Computers ; 2021 ; 00652458 (ISSN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2021
Abstract
Many applications, including big-data server applications, frequently encounter data misses. Consequently, they lose significant performance potential. Fortunately, data accesses of many of these applications follow temporal correlations, which means data accesses repeat over time. Temporal correlations occur because applications usually consist of loops, and hence, the sequence of instructions that constitute the body of a loop repeats many times, leading to data access repetition. Temporal data prefetchers take advantage of temporal correlation to predict and prefetch future memory accesses. In this chapter, we introduce the concept of temporal prefetching and present two instances of...
Spatial prefetching
, Article Advances in Computers ; 2021 ; 00652458 (ISSN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2021
Abstract
Many applications extensively use data objects with a regular and fixed layout, which leads to the recurrence of access patterns over memory regions. Spatial data prefetching techniques exploit this phenomenon to prefetch future memory references and hide their long latency. Spatial prefetchers are particularly of interest because they usually only need a small storage budget. In this chapter, we introduce the concept of spatial prefetching and present two instances of spatial data prefetchers, SMS and VLDP. © 2021 Elsevier Inc
Preface
, Article Advances in Computers ; Volume 125 , 2022 , Pages ix-x ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Temporal prefetching
, Article Advances in Computers ; Volume 125 , 2022 , Pages 31-41 ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Abstract
Many applications, including big-data server applications, frequently encounter data misses. Consequently, they lose significant performance potential. Fortunately, data accesses of many of these applications follow temporal correlations, which means data accesses repeat over time. Temporal correlations occur because applications usually consist of loops, and hence, the sequence of instructions that constitute the body of a loop repeats many times, leading to data access repetition. Temporal data prefetchers take advantage of temporal correlation to predict and prefetch future memory accesses. In this chapter, we introduce the concept of temporal prefetching and present two instances of...
Spatial prefetching
, Article Advances in Computers ; Volume 125 , 2022 , Pages 19-29 ; 00652458 (ISSN); 9780323851190 (ISBN) ; Sarbazi Azad, H ; Sharif University of Technology
Academic Press Inc
2022
Abstract
Many applications extensively use data objects with a regular and fixed layout, which leads to the recurrence of access patterns over memory regions. Spatial data prefetching techniques exploit this phenomenon to prefetch future memory references and hide their long latency. Spatial prefetchers are particularly of interest because they usually only need a small storage budget. In this chapter, we introduce the concept of spatial prefetching and present two instances of spatial data prefetchers, SMS and VLDP. © 2022 Elsevier Inc
A method for simulation of vapour cloud explosions based on computational fluid dynamics (CFD)
, Article Journal of Loss Prevention in the Process Industries ; Volume 24, Issue 5 , 2011 , Pages 638-647 ; 09504230 (ISSN) ; Rashtchian, D ; Abbasi, T ; Abbasi, S.A ; Sharif University of Technology
2011
Abstract
The effectiveness of the application of CFD to vapour cloud explosion (VCE) modelling depends on the accuracy with which geometrical details of the obstacles likely to be encountered by the vapour cloud are represented and the correctness with which turbulence is predicted. This is because the severity of a VCE strongly depends on the types of obstacles encountered by the cloud undergoing combustion; the turbulence generated by the obstacles influences flame speed and feeds the process of explosion through enhanced mixing of fuel and oxidant. In this paper a CFD-based method is proposed on the basis of the author's finding that among the various models available for assessing turbulence, the...
Thin film graphene oxide membrane: challenges and gas separation potential
, Article Korean Journal of Chemical Engineering ; Volume 35, Issue 5 , May , 2018 , Pages 1174-1184 ; 02561115 (ISSN) ; Karimi Sabet, J ; Ghotbi, C ; Abbasi, Z ; Sharif University of Technology
Springer New York LLC
2018
Abstract
Graphene oxide membranes were prepared by vacuum and pressurized ultrafiltration methods on the 12% modified Polyacrylonitrile (12mPAN) substrate to specify challenges, salient features, future directions, and potential of GO membrane for separation fields using characterization techniques and gas separation test (studied gases are CO2, He and N2), which is an efficient tool for better understanding of GO membrane behavior. GO membrane structure was examined over a wide range of parameters, such as pore size range of substrate and its surface properties, pH of GO dispersion, GO content, synthesis pressure, operating pressure and temperature. The results show that the GO content does not hold...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; 2021 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2021
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Conversion of CO into CO2 by high active and stable PdNi nanoparticles supported on a metal-organic framework
, Article Frontiers of Chemical Science and Engineering ; Volume 16, Issue 7 , 2022 , Pages 1139-1148 ; 20950179 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Higher Education Press Limited Company
2022
Abstract
The solubility of Pd(NO3)2 in water is moderate whereas it is completely soluble in diluted HNO3 solution. Pd/MIL-101(Cr) and Pd/MIL-101-NH2(Cr) were synthesized by aqueous solution of Pd(NO3)2 and Pd(NO3)2 solution in dilute HNO3 and used for CO oxidation reaction. The catalysts synthesized with Pd(NO3)2 solution in dilute HNO3 showed lower activity. The aqueous solution of Pd(NO3)2 was used for synthesis of mono-metal Ni, Pd and bimetallic PdNi nanoparticles with various molar ratios supported on MOF. Pd70Ni30/MIL-101(Cr) catalyst showed higher activity than monometallic counterparts and Pd + Ni physical mixture due to the strong synergistic effect of PdNi nanoparticles, high distribution...
Improved method for increasing accessible pores of MIL-101(Cr) by encapsulation and removal of Phosphotungstic acid (PTA): Pd/PTA-MIL-101(Cr) as an effective catalyst for CO oxidation
, Article Journal of Cleaner Production ; Volume 347 , 2022 ; 09596526 (ISSN) ; Karimi Sabet, J ; Abbasi, Z ; Ghotbi, C ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
This study forwards a novel and simple approach for encapsulation of Phosphotungstic acid (PTA) into MIL-101(Cr) cavities to develop PTA-MIL-101(Cr) with a high surface area. In this method, the resulting surface area of PTA-MIL-101(Cr) (3563 m2/g) is 1.72 times that of MIL-101(Cr) due to the existence of more accessible pores which are formed by leaching of PTAs incorporated inside MIL-101(Cr) pores during the intense washing. Catalysts are investigated in CO oxidation under atmospheric pressure and feed composition of 1%CO, 20%O2, and 79%He. 3%Pd/PTA-MIL-101(Cr) shows 100%CO conversion at T = 145 °C and outperforms PTA, PTA-MIL-101(Cr), Pd/PTA, 1–3%Pd/MIL-101(Cr), Pd-PTA/MIL-101(Cr), and...
Investigation into the effects of weld zone and geometric discontinuity on the formability reduction of tailor welded blanks
, Article Computational Materials Science ; Volume 59 , 2012 , Pages 158-164 ; 09270256 (ISSN) ; Ketabchi, M ; Ramazani, A ; Abbasi, M ; Prahl, U ; Sharif University of Technology
2012
Abstract
Numerous advantages of application of tailor welded blanks (TWBs) in automobile industry, namely reduction of weight, fuel consumption and air pollution, have made the manufacturers eager to investigate in this field. On the other hand, while experiments generally provide valuable information in regard with mechanical behaviors, but utilization of simulation methods has extended vastly due to time and cost saving issues. One challenging issue in numerically analyzing the forming behavior of transversely welded TWBs, welded by laser welding methods, has been the presence of weld zone. While some researchers believe that during simulation, the weld zone can be neglected due to its minority and...
Processing Thin Magnesium Tubes by TCAP Process with Trapezoidal Geometry and Fabrication of Magnesium Microtubes with a Novel Method
, M.Sc. Thesis Sharif University of Technology ; Assempour, Ahmad (Supervisor)
Abstract
Due to compability of Magnesium with the body, it is a suitable material for making biodegradable stents, Althogh, its mechanical properties are not desirable for stent application. Accordingly, lately, magnesium’s microstructure and mechanical properties have been improved using various methods, including the process of severe plastic deformation (SPD). Many severe plastic deformation methods have been introduced for the fabrication of ultrafine grain tubes till now, which the process of tubular channel angular pressing (TCAP) is the most effective one. In the first part of the research, Magnesium tubes with a thickness of 1 mm were processed using the TCAP with a trapezoidal channel, and...
A neural network applied to estimate process capability of non-normal processes
, Article Expert Systems with Applications ; Volume 36, Issue 2 PART 2 , 2009 , Pages 3093-3100 ; 09574174 (ISSN) ; Sharif University of Technology
2009
Abstract
It is always crucial to estimate process capability index (PCI) when the quality characteristic does not follow normal distribution, however skewed distributions come about in many processes. The classical method to estimate process capability is not applicable for non-normal processes. In the existing methods for non-normal processes, probability density function (pdf) of the process or an estimate of it is required. Estimating pdf of the process is a hard work and resulted PCI by estimated pdf may be far from real value of it. In this paper an artificial neural network is proposed to estimate PCI for right skewed distributions without appeal to pdf of the process. The proposed neural...
Distributed Generation Planning in Deregulated Electric Industry Using Multi-objective Optimization
, M.Sc. Thesis Sharif University of Technology ; Ehsan, Mehdi (Supervisor)Methods of Clearing Reactive Power Market and Cost Allocation in Pool Structure
, M.Sc. Thesis Sharif University of Technology ; Ehsan, Mehdi (Supervisor)
Abstract
Restructuring and privatization in power system such as any industry leads to better market operation and more social welfare. Since two decade the power system in many countries have changed from monopoly to free market. In a restructured network the technical and economical aspects should be considered together. Ancillary services are needed for any power system to be operated in an optimal and secure manner. Reactive power and voltage regulation is one of the most important ancillary services in the network. this service should be supplied by its providers through a competitive market and system operator determines the optimal dispatch among different bids. The cost of purchasing reactive...
Dynamic Security Assessment in Restructured Power Systems
, Ph.D. Dissertation Sharif University of Technology ; Ehsan, Mahdi (Supervisor)
Abstract
This thesis addresses the problem of dynamic security assessment in power sys-tems with an emphasis on its application in restructured power systems and issues arising in its applications. The new electric utility environment has an immedi-ate consequence of emphasis on reliability and secure operation of power systems. This requires faster and more precise methods to assess the dynamic aspect of se-curity. On the other hand, this issue is becoming challenging when the determined dispatch might not be accommodated due to violation of the limits.This thesis addresses the problem of dynamic security assessment in power sys-tems with an emphasis on its application in restructured power systems...