Sharif Digital Repository

Hand in hand with the flourish of the biodiesel industry, glycerol (GLY) as an inconvenient by-product has generated environmental and sustainability concerns. Devising measures for efficient transformation of GLY into value-added products is a promising solution. In this contribution, the transformation of GLY to lactic acid (LA) as a valuable chemical was investigated in a continuous process for industrial applications. In this regard, a catalytic method using heterogeneous Cu nanoparticles in NaOH solution was studied in a microreactor by a CFD simulation. A seven-inlet micromixer comprising an optimized mixing unit was incorporated for uniform distribution of the species. The effects of... 

Periodic cycles of flood and drought are aggravated by global warming, thereby inducing critical desiccation cracks in soils. However, the estimation and prevention of crack propagation is imperfect due to the imprecise field measurements and the underlying soil uncertainties. To address these issues, this study presents an alternative framework to assess the probability of crack propagation. Thus, a series of Monte Carlo sampling (MCS) and Gaussian random fields are employed to quantify the associated uncertainties. The results suggest that matric suction has a governing effect in the course of crack propagation and induces cracking particularly at shallow depths. Crack propagation tends to... 

In the bone tissue engineering field (BTE), it is of significant importance to develop bioactive multifunctional scaffolds with enhanced osteoconductivity, osteoinductivity, and antibacterial properties required for lost bone tissue regeneration. In this work, a bioactive glass-ceramic scaffold was manufactured via a novel polymer-derived ceramics (PDC) manufacturing method. To gain antibacterial properties, the silver ions were incorporated in controlled amount along with other precursors in the PDC processing stage. Microstructural and structural properties of the fabricated silicate-phosphate glass-ceramic scaffold were evaluated by scanning electron microscopy (SEM) equipped with energy... 

In the bone tissue engineering field (BTE), it is of significant importance to develop bioactive multifunctional scaffolds with enhanced osteoconductivity, osteoinductivity, and antibacterial properties required for lost bone tissue regeneration. In this work, a bioactive glass-ceramic scaffold was manufactured via a novel polymer-derived ceramics (PDC) manufacturing method. To gain antibacterial properties, the silver ions were incorporated in controlled amount along with other precursors in the PDC processing stage. Microstructural and structural properties of the fabricated silicate-phosphate glass-ceramic scaffold were evaluated by scanning electron microscopy (SEM) equipped with energy... 

Let R be a ring and f(x1,..., xn) be a polynomial in noncommutative indeterminates x1,..., xn with coefficients from ℤ and zero constant. The ring R is said to be an f-ring if f(r1,..., rn) = 0 for all r1,..., rn of R and a virtually f-ring if for every n infinite subsets X1,..., Xn (not necessarily distinct) of R, there exist n elements r1 ∈ X1,...,rn ∈ Xn such that f(r1,..., rn) = 0. Let R* be the 'smallest' ring (in some sense) with identity containing R such that Char (R) = Char (R*). Then denote by ZR the subring generated by the identity of R* and denote by f̄R the image of f in ZR [x1,..., xn] (the ring of polynomials with coefficients in ZR in commutative indeterminates x1,..., xn).... 

Prediction of thermal crack propagation in desiccated soils is imperfect due to the obscure field measurements, modeling approximations, and the underlying soil uncertainties. To address these issues, a probabilistic framework is developed to quantify the uncertainties and enhance the crack estimation reliability. Hence, the uncertainties associated with the soil properties, including the tensile strength, matric suction, Poisson's ratio, elastic modulus and suction ratio are associated in a probabilistic model. Then, the probabilistic model is utilized with the improved Monte Carlo simulation to calculate the failure probability due to the exceedance of the crack propagation. Furthermore,...