Sharif Digital Repository

The aim of this dissertation is to investigate the extraction of calcium ions using an emulsion liquid membrane (ELM) with an isotopic perspective. Considering the importance of ion extraction as a preliminary step to isotope separation, the factors affecting the extraction of Ca(II) ions in the ELM process were investigated and optimization of the process was performed in this study. Dicyclohexano-18-crown-6 (DC18C6) was used as the carrier due to isotopic considerations. However, its extractability for calcium ions is limited. In order to address this issue, it is possible to introduce an organic acid, specifically di-(2-ethylhexyl) phosphoric acid (D2EHPA), into the membrane phase. This... 

Today, the Oil industry, much progress has been made in terms of increasing the productivity of reservoirs. In this method, generally one or more fluids are injected into wells to help, extract more oil from the reservoir. Knowledge of the main parameters in this flow of two or three phase fluid in the reservoir is most important. If fractured reservoirs are studied, the multiphase flow are much more complex and require more information about that. Unfortunately, due to the complexity of fractured reservoirs and fluid flow within them, little research has been done on them. The studies about two or three phase flow in fractured reservoirs are classified in two groups, modeling and laboratory... 

In this research, we focus on study and fabrication of organic inorganic solar cells. We use and optimize various methods such as one-step spin-coating, two-step sequential deposition and vapor-assisted solution process (VASP), to prepare high quality perovskite films. One-step deposition is simplest method for deposition of perovskite films. Although perovskite deposition by this method is very simple, the control of uniformity and surface film morphology is difficult. Chlorine inclusion, optimization of annealing conditions, and a sequential solution-based deposition method have been demonstrated to increase film coverage and uniformity. Hence, we use sequential deposition method for... 

Al-6wt%Mg alloy has been enormously exploited in aerospace industry. Since for production of this alloy in the form of sheets of different thickness, the cold rolling process is used, thus to understand the final mechanical properties of the rolled alloy products, their work hardening should be examined. Also, one of the important phenomena that occurs in cold state of the alloy is dynamic strain-aging (DSA), which can cause serrations in realistic stress-strain curve. The aforementioned issue is discussed in the current study. Therefore, the work-hardening values for the mentioned alloy during and after rolling is determined, and then compared with the experimental studies. The results of... 

Quantum entanglement and superposition are wonderful and mysterious phenomena of quantum mechanics. By means of quantum entanglement, two or more systems become partner in state of each other . As a result, measurements on each of these systems affect the status of other systems. Quantum superposition allows a system inhabits several of its possible quantum states simultaneously. These two features are applicable in many technologies in present age. Photons, as an quantum unit of light, are appropriate candidate for utilization these properties. Because they are robust to decoherence and for their preparation exist various methods. Hence, we interested to generation of quantum states of... 

Electrospinning is a method for producing of micro and nanometer polymeric fibers. Nowadays, electrospun fibers have been demanded a lot because of various applications of fibers in optical industries, tissue engineering, and chemical and biological sensors. Producing of more complicated shape of fibers by using two new methods called Electrical Bending and Mechanical Buckling are interested in this field. The aim of this thesis is to prepare such fibers and study the effective parameters on the shapes of them. Fibers are collected on the aluminum and Fluorine-doped tin oxide (FTO) glass. Then they were observed by optical microscope. In the Electrical Bending method, we used PEO: PAMPS and... 

Today, with rapid developments and advances in science and technology, different ways have been studied to reduce energy consumption in various industries. Reducing the drag force and thus reducing the friction force is one of these methods which has many applications (e. g, in submarine construction industries). Creating some microgrooves in the microchannels is one of the most effective methods in order to reduce the friction force in microchannels that has recently been studied. In this method the air is trapped within the microgrooves and when the fluid (e. g, water) enters the channel passes over the trapped air within these microgrooves instead of touching the channel walls (solid... 

Schizophrenia is a devastating disorder that steals the opportunity of having a normal life from the sufferers. Drugs used in treating this disorder usually target psychotic symptoms and do not affect negative symptoms effectively. One of the deficits falling into this category is the impaired reversal learning. These patients usually learn the rules but do not renounce them after the contingencies of reward have been reversed. To investigate the reasons of this impairment, first a hypothesis of how different parts of the brain communicate during reversal learning is proposed using the physiological evidence. Then considering the known relation between the actor-critic model of the... 

The use of renewable energy sources has received much attention due to the increasing need for energy, limited energy resources and the pollution of fossil fuels. Among all types of solar energy conversion technology, photovoltaics has the highest technical potential and Iran’s geographical location is very suitable for benefiting from this energy. So, in this thesis, the fabrication and characterization of nanostructured solar cells based on organic-inorganic perovskites have been investigated. Many research goups have tried to increase the efficiency of perovskite solar cells. The efficiency of this kind of solar cells depends mainly on the light-absorbing layer (perovskite) and its... 

The theory of mass transfer accompanied by chemical reaction for gas-liquid systems was used to measure the specific interfacial area and mass transfer coefficient in a two impinging jets reactor (TIJR) in the presence of γ-Al_2 O_3 nanoparticles.The absorption of oxygen in sulfite solutions used for the determination of mass transfer characteristics. First 3 liters of nanofluids were prepared at concentration of 1 w% then diluted To produce 10 Liters of nanofluids containing 0.3 w%. The stability of this nanofluid was determined using uv-vis to be less more than 95% in the first 3 hours. The influence of weight percent of nanoparticles (0, 0.05, 0.1, 0.15, 0.2, 0.3) on the specific... 

Solar cells, as a part of photovoltaics (PV) industry, have a significant share in the renewable energy market. Perovskite solar cells (PSCs) and thin film solar cells (TFSCs) achieved 23% and 22% power conversion efficiencies (PCEs) respectively. However, the PV industry still faces challenges like “high manufacturing costs” and “stability”. Among the strategies to overcome these challenges are substitution of the costly materials with cheaper, more abundant ingredients along with utilizing inexpensive deposition methods like printing rather than vacuum-based methods such as evaporation and sputtering. Carbon materials attract more attention in the solar cell research community for their... 

One of the main purposes of this project is to propose an efficient and stable algorithm of a semi-discretized formulation for compositional simulation of oil reservoirs. In this algorithm, all the equations including both mass balances and equilibrium equations are solved simultaneously. The gradient terms are discretized by the Finite Volume Method (FVM). The resulting Differential Algebraic Equation, the so-called DAE, are solved by MATLAB functions. Another novel technique developed, handles each block equations set, separately. In this block-by-block scheme, there are two set of equations; the primary (mass balance) and secondary (equilibrium) equations. In the primary ones, the...