Sharif Digital Repository

Aromatic aldehydes and ketones are readily acetalized or ketalized under microwave irradiation in the presence of water as a solvent  

A four-step synthetic strategy was applied to achieve novel methacrylic monomers. 5-Norbornene-2,2-dimethanol was prepared from a Diels–Alder reaction of cyclopentadiene and acrolein, followed by the treatment of the adduct with an HCHO/KOH/MeOH solution. The resulting 1,3-diol (1) was then acetalized with different aromatic aldehydes having OH groups on the ring to produce four spiroacetal derivatives. The reaction of methacryloyl chloride with the phenolic derivatives led to four new methacrylic monomers that were identified spectrochemically (mass, FTIR, 1H-NMR, and 13C-NMR spectroscopy). Free radical solution polymerization was used to prepare novel spiroacetal–norbornene containing... 

A hot gas generator is a compact heat exchanger that produces high temperature or enthalpy gases. This paper presents two methods for controlling the system. The first one is an adaptive sliding mode controller that is a Lyapunov based method and proposed to confront the dynamic modeling deficiencies and system uncertainties. The second one is a linear adaptive controller that gives a new attractive ability to the system which can track a complicated requested path. Each of the presented controllers has some capabilities that may be preferred to other. In this paper, these methods are extensively compared by several transient inputs. On the other hand, since heat exchangers are typically... 

A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition  

In this paper the question of the emission of fermions in the process of dilaton black hole evolution and its characteristics for different dilaton coupling constants α are studied. The main quantity of interest, the greybody factors, are calculated both numerically and in analytical approximation. The dependence of the rates of evaporation and behaviour on the dilaton coupling constant is analysed. Having calculated the greybody factors, we are able to address the question of the final fate of the dilaton black hole. For that we also need to perform dynamical treatment of the solution by considering the backreaction, which will show a crucial effect on the final result. We find a transition... 

In pebble bed reactors, the core is filled with thousands of graphite and fuel pebbles. Fuel pebbles in these reactors consist of TRISO particles, which are embedded in a graphite matrix stochastically. The reactor core is also stochastically filled with pebbles. These two stochastic geometries comprise the so-called double heterogeneous nature of this type of reactor. In this paper, a pebble bed reactor, the HTR-10, is used to demonstrate a treatment of this double heterogeneity using the MCNP5 Monte Carlo code and MATLAB programming. In this technique, TRISO particles are modeled in a pebble using the expanded FILL and LATTICE features of MCNP5. MATLAB is used to generate random numbers... 

The aim of this research is bonding of three-layered St/AZ31/St composite by roll-bonding process. The roll-bonding process was performed at three preheating temperatures, 340, 400 and 450°C, with thickness reduction of 30 to 68% and different thicknesses of intermediate layer (AZ31). In order to improve the bonding strength, the as-rolled specimens were annealed at constant temperature of 375°C. For evaluation of bond strength and investigating the formation of a diffusion layer, the results of peel test and microscopic images were studied. Tensile specimens were prepared along the rolling direction to measure the mechanical properties of the composite. The results showed that by increasing... 

Abstract: We consider the back reaction of the energy due to quantum fluctuation of the background fields considering the trace anomaly for Schwarzschild black hole. It is shown that it will result in modification of the horizon and also formation of an inner horizon. We show that the process of collapse of a thin shell stops before formation of the singularity at a radius slightly smaller than the inner horizon at the order of (Formula presented.). After the collapse stops the reverse process takes place. Thus we demonstrate that without turning on quantum gravity and just through the effects the coupling of field to gravity as trace anomaly of quantum fluctuations the formation of the... 

In this work, cold rolling behavior of stainless steel 304L is investigated and the effects of different process parameters on the occurrence of strain-induced martensite and mechanical properties are studied. The rolling experiments are conducted under different rolling speeds and reductions in which a set of samples is deformed at room temperature and the other set is first cooled to the temperature of − 10 °C and then rolled. Afterward, the developed microstructures and mechanical properties of the rolled steel are evaluated employing different testing techniques. In order to justify the results, mathematical modeling of cold rolling operation is also performed using Abaqus/Explicit to... 

Background: Although kinematic assessment has potentials for better evaluation of the movement quality, they are not widely used in clinics. Besides the equipment cost, the contradictory results of their clinimetric analysis are presumed as a major reason. This raises concerns about whether the current kinematic indices are intrinsically sound and truly reflect the quality of the subjects’ movement. Methods: A list of essential requirements for the kinematic indices (KIs) was proposed. Monotonic response to the change in the movement quality, independence from the task geometry and the subjects’ upper limb dimensions and speed, and robustness against the measurement error was investigated....