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afshar--bahareh
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Investigation and Modeling of Polymer Electrolyte Membranes in PEM Fuel Cells
, M.Sc. Thesis Sharif University of Technology ; Roshandel, Ramin (Supervisor)
Abstract
Fuel cells convert the chemical energy of hydrogen and oxygen directly into the electricity. Their high efficiency and low emissions have made them a prime candidate for powering the next generation electric vehicles. Polymer electrolyte membrane is a key component of the PEM fuel cells. One of the critical problems to overcome in some PEM fuel cells is the water management because If there is not enough water, the membrane becomes dehydrated which leads to a rapid increase in ohmic resistance. On the other hand, if too much water is present, flooding may occur resulting in the pores of the gas diffusion filled by water and the available passage for reactant gases is decreased. In this work...
Simulation of corrosion protection methods in reinforced concrete by artificial neural networks and fuzzy logic
, Article Journal of Electrochemical Science and Engineering ; Volume 12, Issue 3 , 2022 , Pages 511-527 ; 18479286 (ISSN) ; Shokrgozar, A ; Afshar, A ; Afshar, A ; Sharif University of Technology
International Association of Physical Chemists
2022
Abstract
In this study, the effect of protection methods regarding the corrosion decrement of steel in concrete was simulated by artificial neural networks (ANNs) and fuzzy logic (FL) approaches. Hot dip galvanizing as a protective coating, Ferrogard 901 corrosion inhibitor, a pozzolanic component, such as fly ash (FA) and micro-silica (MS), and eventually rebar AISI-304 were employed in concrete. Reinforced concrete samples were held under impressed voltage of 30 V in 3.5 % NaCl electrolyte for 350 hours toward a stainless-steel auxiliary electrode. Corrosion currents have been modelled using feed forward back propagation ANNs and FL methods. The results demonstrate good consistency between...
Simulation of the effects of pozzolanic additives and corrosion inhibitor on the corrosion of reinforced concrete by artificial neural networks
, Article Revista Romana de Materiale/ Romanian Journal of Materials ; Volume 49, Issue 4 , 2019 , Pages 535-543 ; 15833186 (ISSN) ; Nobakhti, A ; Shokrgozar, A ; Afshar, A ; Sharif University of Technology
Fundatia Serban Solacolu
2019
Abstract
In this research, we simulate the corrosive behavior of steel reinforcements on 5 different mixtures to investigate the effect of two powerful protective methods, including pozzolanic additives and corrosion inhibitor on concrete, by artificial neural networks (ANNs). Related to this model, fly ash (FA), micro silica (MS), and slag were used as pozzolanic materials at an optimum 25%, 10%, and 25% of cement weight, respectively. Moreover, Ferrogard 901 as an inhibitor was also utilized. The producer recommends using12 kg/m3 to get the best possible results. The non-linear corrosion of concrete into a marine solution (3.5% NaCl) was simulated by the feed forward back propagation (FFBP)...
Simulation of the effects of pozzolanic additives and corrosion inhibitor on the corrosion of reinforced concrete by artificial neural networks
, Article Revista Romana de Materiale/ Romanian Journal of Materials ; Volume 49, Issue 4 , 2019 , Pages 535-543 ; 15833186 (ISSN) ; Nobakhti, A ; Shokrgozar, A ; Afshar, A ; Sharif University of Technology
Fundatia Serban Solacolu
2019
Abstract
In this research, we simulate the corrosive behavior of steel reinforcements on 5 different mixtures to investigate the effect of two powerful protective methods, including pozzolanic additives and corrosion inhibitor on concrete, by artificial neural networks (ANNs). Related to this model, fly ash (FA), micro silica (MS), and slag were used as pozzolanic materials at an optimum 25%, 10%, and 25% of cement weight, respectively. Moreover, Ferrogard 901 as an inhibitor was also utilized. The producer recommends using12 kg/m3 to get the best possible results. The non-linear corrosion of concrete into a marine solution (3.5% NaCl) was simulated by the feed forward back propagation (FFBP)...
Corrosion resistance evaluation of rebars with various primers and coatings in concrete modified with different additives
, Article Construction and Building Materials ; Volume 262 , 2020 ; Jahandari, S ; Rasekh, H ; Shariati, M ; Afshar, A ; Shokrgozar, A ; Sharif University of Technology
Elsevier Ltd
2020
Abstract
Corrosion of steel rebars in concrete can reduce the durability of concrete structures in coastal environments. The corrosion rate of these concrete structures can be reduced by using suitable concrete additives and coating on rebars. This paper investigates the corrosion resistance of steel rebars by the addition of pozzolanic materials including fly ash, silica fume, polypropylene fibers, and industrial 2-dimethylaminoethanol (FerroGard 901) inhibitors to the concrete mixture. Three different types of rebars including mild steel rebar st37, and two stainless steel reinforcements, AISI 304 and AISI 316, were used. Various types of primer and coating including alkyd based primer, hot-dip...
Flow stress dependence on the grain size in alumina dispersion-strengthened copper with a bimodal grain size distribution
, Article Materials Science and Engineering A ; Volume 518, Issue 1-2 , 2009 , Pages 41-46 ; 09215093 (ISSN) ; Simchi, A ; Sharif University of Technology
2009
Abstract
The grain size dependence of flow stress in Cu-2.7 vol.%Al2O3 (15 nm) composite with a bimodal structure was studied. It is shown that the yield strength obeys the Hall-Petch equation when an appropriate value of average grain size based on the "rule of mixture" is employed. The Hall-Petch constants (σ0ε and kε) are proportional to strain as ε0.5. An equation for flow stress as a function of true strain and average grain size is proposed. The effect of alumina nanoparticles on the yield strength is shown to be related to large amounts of dislocations density. © 2009 Elsevier B.V. All rights reserved
Enhanced stabilization diagram for automated modal parameter identification based on power spectral density transmissibility functions
, Article Structural Control and Health Monitoring ; Volume 26, Issue 7 , 2019 ; 15452255 (ISSN) ; Khodaygan, S ; Sharif University of Technology
John Wiley and Sons Ltd
2019
Abstract
Operational modal analysis based on power spectral density transmissibility (PSDT) functions is a useful tool to identify the modal parameters with low sensitivity to excitations. For pole extraction from the PSDT function, a proper parametric identification method such as the polyreference least squares complex frequency-domain method or poly-Max method can be used. Then, the poles are selected from a stabilization diagram (SD) with overestimating the system model order. Therefore, spurious modes can be identified that must be distinguished and removed from the system poles. To reach this aim, many techniques have been proposed and applied. In this paper, a new algorithm is proposed to...
Abnormal grain growth in alumina dispersion-strengthened copper produced by an internal oxidation process
, Article Scripta Materialia ; Volume 58, Issue 11 , 2008 , Pages 966-969 ; 13596462 (ISSN) ; Simchi, A ; Sharif University of Technology
2008
Abstract
Cu-2.7 vol.% Al2O3 (15 nm) composite was synthesized by an internal oxidation and hot extrusion process. The grain growth at elevated temperatures was studied and compared with extruded copper powder. Abnormal grain growth via a mechanism analogous to that of site-saturated phase transformation was observed. The critical grain size for the abnormal growth was determined to be 1.1 ± 0.2 μm. The growth rate decreased with time until the grain size approaching a final value ranging from 7.9 to 13.3 μm depending on the temperature. © 2008 Acta Materialia Inc
Managing reengineering operations
, Article 2006 IEEE International Conference on Management of Innovation and Technology, ICMIT 2006, Singapore, 21 June 2006 through 23 June 2006 ; Volume 1 , 2006 , Pages 268-269 ; 1424401488 (ISBN); 9781424401482 (ISBN) ; Sepehri, M ; Sharif University of Technology
2006
Abstract
Fifteen years after introduction of Business Process Reengineering (BPR) and a series of successful and not-so-successful BPR implementation, a revised methodology is needed to incorporate cases of major and sudden organizational or environmental changes with BPR. The new methodology can also be particularly applicable to project oriented businesses. September 11, Tsunami, and other major world events show that nothing is constant but change. A reengineered process may only stay as the environment factors stay the same. Therefore, the processes can no longer be the central focus of reengineering, but the output needs. Technology has enabled us to refocus and apply reengineering constantly to...
Bioglass Coating on 316L Stainless Steel
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Bioactive glasses are able to bond to soft and hard tissues in living body and their application as coating on metallic implants like 316L stainless steel has two important effects: (1) intimate link between bone and materials and (2) corrosion protection of metallic implant in body fluid and protection from tissues in front of corrosion products. Therefore, in this research, 45S5 bioactive glass prepared via sol- gel method was dip coated on 316L stainless steel substrates and its characteristics was investigated.Results of phase analysis showed that by sintering 45S5 bioglass at 600 ˚C for 5 h, an amorph sample with small amount of Na2Ca2Si3O9 was obtained. So, the bioglass coated samples...
Micro Arc Oxidation Coating on Magnesium Alloy AZ31 and Study its CorrosionBehavior in Physiological Solution
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Magnesium and its alloys have been used as biodegradable implements in recent years. However Magnesium implements may corrode in the body before the natural healing process of the damaged tissue. MAO process was studied in order to reduce primary corrosion of Magnesium alloy in Simulated Body Fluid (SBF). MAO coating was created on AZ31 alloy in a nontoxic alkaline-silicate solution at DC current densities of 5, 10, 15 and 20 mA/cm2 for 30 minutes and the current was in form of 20-10-5 mA/cm2 steps that each were applied for 10 minutes. The maximum corrosion resistance was observed for the mentioned step applied current in a 30g/l Sodium Silicate solution. Furthermore the effects of adding...
Simulatin of Reinforcement Corrosion in Pozzolanic Concrete by Neural Network
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
One of the most important factors of reducing durability of concrete structures is corrosion of steel reinforcement in concrete. In this paper, corrosion behavior of reinforcing steel in concrete is investigated in two different methods of protection based on neural network. As regard the first method, pozzolanic additives with optimized percentage were added to Concrete mix design (the percentage of these additives are 25% Weight of cement of fly ash, Micro silica with 10 percent of weight of cement and 25% of Blast Furnace slag weight of cement). In the second approach of protection, 0/5 percent weight of cement of ferrogard 901 inhibitor is added to basic mix concrete design and the...
Improvement of Corrosion Resistance of Concrete Sewer Pipes Against Microbial Corrosion
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Microbiologically Influenced Corrosion (MIC) of concrete sewer ptpes and wastewater collection systems has been reported in many places of the world. Recently, numerous copper compounds have been used for bacterial growth control in sewer pipes. In this thesis, bath parameterswere optimized in order to maximize copper osmosis to the porous concrete matrix.Concrete pipes were electrochemically coated inCopper Lactate bath in a constant current mode (1=0.6 A), while temperature was set to 25, 50, 75 and 95
°Cand pH to 9,10 and 11. Specimens were then characterized by scanning electron
microscopy, optical microscopy, XRD andAAS. Copper Osmosis was highest in pH=9 and...
°Cand pH to 9,10 and 11. Specimens were then characterized by scanning electron
microscopy, optical microscopy, XRD andAAS. Copper Osmosis was highest in pH=9 and...
Corrosion Resistance of Graphene-Titania Coating on 316 Stainless Steel by Electrophoretic Deposition
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
The aim of this thesis was creating Titania/RGO coating with electrophoretic method to evaluate the corrosion resistance of stainless steel 316. At first Graphene Oxide were synthesized with modified Hammers method and their physical, chemical and morphological properties have been investigated using XRD, FTIR, EDX, TGA, UV-Vis and Raman analysis. then Graphene Oxide was added to the bath of titanium and was deposited on 316 stainless steel substrates. Moreover, corrosion protection of coating has been examined using Poarization test and Electrochemical Impedance Spectrometry. The effect of deposition parameters on corrosion properties of composite coatings were examined. The key variables...
Evaluation Effects of Mo, Bi &Sn Biocides On the Anti-Fouling Paints
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this research Feasibility of application of oxide compounds of bismuth, molybdenum and tin as biocide was studied. So some epoxy paints with different ratio of these compounds were formulated. Afterward some tests were performed to assessment paints properties such as leaching rate, antifouling activity, adhesion, corrosion resistance and impact resistance. Results of leaching rate test showed that increase in the ratio of bismuth oxide from 10% to 60%, led to increase leaching rate from 0.029mg.day-1.cm-2 to 0.126mg.day-1.cm-2. beside that Microscopic results showed proved that the ratio of bismuth oxide in the cured coating is 25% of the paint formulate. In similar ratio of biocides,...
Preparation and Characterization of HA/ZrO2 Biocomposite Coating on 316 Stainless Steel Fabricated by Electrodeposition
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this research, role of zirconia nanoparticles as a biocompatible material which has great mechanical properties, was investigated on corrosion behavior and bonding strength of HA coating. HA- ZrO2 composite prepared by a 2-step pulse electrodeposition method. Effect of pH (3.5, 4.5), bath temperature (60, 80 ͦC), current density (0.5, 1, 2 mA/cm2) and zirconia concentration (5, 10, 15 g/L) on coating characteristics were studied. X-ray diffraction was employed for phase analysis. Morphology and microstructure of samples observed utilizing scanning electron microscope (SEM) and elemental analysis was done by EDS. In order to corrosion studies electrochemical impedance spectroscopy (EIS)...
Identification of Vibrational Characteristic of System under Colored Excitation base on the Transmissibility Functions
, M.Sc. Thesis Sharif University of Technology ; Behzad, Mehdi (Supervisor)
Abstract
Operational modal analysis (OMA) techniques are proper methods to identify the modal parameters of the structures such as natural frequencies, damping ratios and mode shapes based on the system responses. First research in this area are stared from civil engineering. Difference between civil structure and industrial machines are in the type of excitation.in most industries such as aerospace or mechanical, colored or harmonic forces due to rotary machines, excited the system. Under this condition, traditional methods in OMA are not capable any more. Many works has been done to modify traditional methods. Most of these work limited to situations that forces are harmonic and harmonic...
An Investigation on Zirconia Nano-particles Coating Deposited on Magnesium AZ91 alloy Using Electrodeposition Method
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Recently magnesium alloys have shown great potential as biodegradable metallic implants. However, due to high corrosion rate in the body environment, these alloys would be degraded before the tissue healing time period. Therefore corrosion resistance of these alloys has to be improved in order to be used in biological environments. In the present work, supposing improvement of corrosion properties of magnesium AZ91D alloy, the alloy has been coated with biocompatible nano-Zirconia particles using Electrophoretic deposition method and the effects of deposition parameters such as bath agitation, Zirconia concentration, current density and duration of deposition process on the properties of the...
Electrodeposition of Graphene-Ni-Mo Coating on Titanium Substrate
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
In this study, linear polarization resistance (LPR) of cathodic pulse electrodeposited graphene- Nickel-Molybdenum coating is optimized by design of experiments approach (central composite design). Applied current density (i), cathodic pulse durations (Ton) and total electrodeposition time (Ttotal) are selected as the substantial factors. The best prediction model proposes a definitive linear relation without any significant interaction of the LPR by analysis of variance. The best value of LPR is achieved equal to 1406KΩ.cm2, obtaining at i of 137.5 A/cm2, Ton of 45.5 ms and Ttotal equal to 315 s. Polarization test is carried out to determine corrosion behavior of the coating. It shows...
Investigating Bio-Capability of HA-ZrO2-TiO2 Nano-Composite Coating by EPD on St. St 316 in Physiologic Solution
, M.Sc. Thesis Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Metallic implants are useful in dental and orthopedic applications. Bio coating is necessary to improve bio-compatibility and bio-activation of metallic implants. For this goal, HA is the most important material. In this research, the goal is to improve bio-compatibility of St. St 316 by coating HA, HA-ZrO2, HA-TiO2, HA-ZrO2-TiO2 using combination of electrodeposition and electrophoretic methods. To form HA, calcium and phosphor salt solution was used then ZrO2- TiO2 nanoparticles was added to solution. In order to analyst the coatings different tests were done. Thickness analysis, XRD, FT-IR, FE-SEM and EDS, bonding Strength, Polarization test, bio-compatibility and surface roughness...