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Structural Study of Vitamin B1, B2 and B6 by NMR Spectroscopy and ab-initio Methods
, M.Sc. Thesis Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
The structure and energy of vitamin B1 (Thiamine), vitamin B2 (Riboflavin) and vitamin B6 (Pyridoxine) have been studied employing quantum mechanical calculation, DFT methods at B3LYP level using 6-311+G* basis set. Values of the coupling constants involving carbon-hydrogen and hydrogen-hydrogen on the torsion angle α and β were theoretically calculated. All Karplus equations which represent the correlation between coupling constants 1JCH, 2JHH, 2JCH, 3JHH, 3JCH and proper dihedral angle have been yielded. The effect of three solvents, water, ethanol and carbon¬ tetrachloride with different polarity on coupling constants, energy and structural parameters were calculated employing PCM model....
Multiverse and the Fine-Tuning of the Constants of Nature
, M.Sc. Thesis Sharif University of Technology ; Golshani, Mehdi (Supervisor)
Abstract
In recent decades, the idea of multiverse has been raised in several areas of physics for different reasons. One of the interpretations of quantum mechanics, the inflation theory in cosmology and string theory in fundamental physics have led to the multiverse idea. On the other hand, after the problem of fine-tuning of the constants of nature became a hot topic in recent decades, physicists have tried to find a way to explain this puzzle. One of the most important approaches that have been suggested by some physicists, as a scientific explanation for this problem, is the idea of multiverse and they are even willing to set aside the principle of observability to confirm physical...
PLC Implementation of Fractional Order Controllers
, M.Sc. Thesis Sharif University of Technology ; Tavazoei, Mohammad Saleh (Supervisor)
Abstract
In this thesis, various fractional order controllers (FOCs), e.g., FO-PID, FO-TID, CRONE and FO-Lead/Lag, are implemented using PLC. For this purpose first, several methods are used to approximate the differentiator and integral operators. Based on these methods, the equivalent rational transfer functions of the fractional order controllers are obtained. Then, using STEP7 software, the FOCs are implemented in Siemens PLC. Moreover, to facilitate the use of the implemented FOCs in the industry and to take full advantage of the controllers, WinCC software as an interface between human and machine (HMI) is used. The WinCC software enables the operator to access the PLC through a computer (PC)...
Real Time Trend Forecasting of Noisy Signal Using Deep Recurrent LSTM Network
, M.Sc. Thesis Sharif University of Technology ; Vosoughi Vahdat, Bijan (Supervisor)
Abstract
Artificial neural networks are mathematical models inspired by the nervous system and brain. The types and applications of these networks are very widespread nowadays, and it seems that they can be used to track the signals well and estimate the data of the next. In this research, we try to present a model that can predict the future of the trend of noisy signals that have unpredictable behavior, or in other words, chaotic signals. Such research is also widely used in the medical sciences, including the diagnosis of epileptic seizures or heart attacks. In this research, a study with high volatility financial data has been done as an example on this issue and the proposed model tries to be...
Active distance-based clustering using k-medoids
, Article Lecture Notes in Computer Science (including subseries Lecture Notes in Artificial Intelligence and Lecture Notes in Bioinformatics), 19 April 2016 through 22 April 2016 ; Volume 9651 , 2016 , Pages 253-264 ; 03029743 (ISSN) ; 9783319317526 (ISBN) ; Ghadiri, M ; Soleymani Baghshah, M ; Sharif University of Technology
Springer Verlag
2016
Abstract
k-medoids algorithm is a partitional, centroid-based clustering algorithm which uses pairwise distances of data points and tries to directly decompose the dataset with n points into a set of k disjoint clusters. However, k-medoids itself requires all distances between data points that are not so easy to get in many applications. In this paper, we introduce a new method which requires only a small proportion of the whole set of distances and makes an effort to estimate an upperbound for unknown distances using the inquired ones. This algorithm makes use of the triangle inequality to calculate an upper-bound estimation of the unknown distances. Our method is built upon a recursive approach to...
Concept Extraction of Sequential Patterns for Imitative Learning
, M.Sc. Thesis Sharif University of Technology ; Bagheri Shouraki, Saeed (Supervisor)
Abstract
The aim of this thesis is the concept extraction of sequential patterns for imitative learning for humanoid robots. In such a way that an existent that has the physical and cognitive similarities, begins to extract concepts and learns by observing the behavior of the other existent. In this project, it is assumed a humanoid robot that can understand the concepts such as hello, goodbye and different concepts and does the corresponding actions from the visual and auditory information. In this thesis, a new model has been presented to eliminate the improper and meaningless elasticity in patterns sequence, such as changes in accent or elasticity in movements. This model is called the fuzzy...
Differentiating Signals Recorded from Rat Brain in Response to Different Olfactory Stimuli
, M.Sc. Thesis Sharif University of Technology ; Karbalaei Aghajan, Hamid (Supervisor)
Abstract
The olfactory sense in rats provides crucial information for identifying food sources, detecting threats, and facilitating social interactions. The olfactory bulb is one of the key brain regions involved in the initial processing of olfactory information and its transmission to higher brain areas for more complex processing. However, more advanced cognitive processes such as evaluation and decision-making rely on interactions between other brain regions. Among these, the striatum, as a part of the basal ganglia, plays a role in reward evaluation, reward-based learning, and shaping behaviors associated with sensory stimuli. This region contributes to learning, decision-making, and action...
Two-phase flow separation in axial free vortex flow
, Article Journal of Computational Multiphase Flows ; Volume 9, Issue 3 , 2017 , Pages 105-113 ; 1757482X (ISSN) ; Ganjiazad, R ; Roshandel, R ; Ashjari, M. A ; Sharif University of Technology
2017
Abstract
Multi-phase flows, particularly two-phase flows, are widely used in the industries, hence in order to predict flow regime, pressure drop, heat transfer, and phase change, two-phase flows should be studied more precisely. In the petroleum industry, separation of phases such as water from petroleum is done using rotational flow and vortices; thus, the evolution of the vortex in two-phase flow should be considered. One method of separation requires the flow to enter a long tube in a free vortex. Investigating this requires sufficient knowledge of free vortex flow in a tube. The present study examined the evolution of tube-constrained two-phase free vortex using computational fluid dynamics. The...
3D Numerical Simulation of Two-Phase Immiscible Flow in Axial Vortex Technology and Economic Analysis for Industrial Produced Water Pretreatment Facility in Desalting Plants
, M.Sc. Thesis Sharif University of Technology ; Roshandel, Ramin (Supervisor) ; Ashjari, Mohammad Ali (Supervisor)
Abstract
The phenomenon of vortex flow, is one of the most predominant streams in the nature. This phenomenon yielded by the motion of vortices, produces up to 1000 times acceleration of the Earth’s gravity. The issues of uncontrolled harvesting of oil wells and increase the life of the wells, which cause to increase in the extracted crude salt, reveal the importance of waste management and both handling and refining petroleum. According to global statistics, for every extracted barrel of oil, three barrels of water are yielded. Therefore, 250 million produced water barrels per day is produced.The separator technology with vortex core (brand Voraxial) is one of the latest technologies in waste-water...
Comparing half-metallic, MOKE, and thermoelectric behavior of the CrTiZ (Z = As, P) half-Heuslers: A DFT study
, Article Materials Research Express ; Volume 8, Issue 4 , 2021 ; 20531591 (ISSN) ; Zelati, A ; Boochani, A ; Arman, A ; Mirzaei, S ; Sharif University of Technology
IOP Publishing Ltd
2021
Abstract
Structural, half-metallic, magneto-optic, and thermoelectric properties of CrTiZ (Z = As, P) half-Heusleres compounds are investigated based on density functional theory. These compounds have mechanical stability in the ferromagnetic state with a high bulk modulus. They are often half-metallic with a large and integer magnetic moment and are very attractive in spintronics, magneto-optics applications. The magnetic moments of CrTiAs and CrTiP were 2.9865 μB and 3.00 μB, respectively, which were attributed to their ferromagnetic phase. Additionally, the positive sign of the phonon branches indicates the dynamic stability of these compounds. Applying both GGA and mBJ approximations, CrTiAs and...
The Effect of Rudder Angle on Ship’s Fuel Consumption
, M.Sc. Thesis Sharif University of Technology ; Khorasanchi, Mahdi (Supervisor) ; Zare, Arman (Co-Supervisor)
Abstract
The aim of this research is to investigate the effect of speed and direction of current on ship fuel consumption. A KCS benchmark model has been numerically studied in calm water and fourteen current and wind conditions with the same speed and different directions to determine how the ship performance is dependent on flow conditions. The model has been simulated in an artificial basin propelled by a single right-handed propeller via a CFD commercial code. Numerical results revealed a linear relationship between the deviation of current and wind from head-sea or following-sea conditions and the rudder angle. The head-sea and following-sea currents and winds increased and decreased the lateral...
Dynamic Simulation and Control of Reactive Systems Involving Metabolic Pathways
, M.Sc. Thesis Sharif University of Technology ; Bozorgmehry Bozarjomehry, Ramin (Supervisor) ; Setoodeh, Payam (Co-Supervisor)
Abstract
In this project, modeling, simulation, and control of the Saccharomyces Cerevisiae were studied. In the first section, simulation and control of a structural model of saccharomyces Cerevisiae were performed. Fuzzy Logic Controller (FLC) as a model-independent controller and Global Linearization Controller (GLC) as a model-based controller were designed. Additionally, two types of Kalman filters were designed to predict all states of the structural model: 1-Extended Kalman Filter (EKF), 2- Unscented Kalman Filter (UKF). As a concise explanation, the control action of the GLC is a function of all states of the model, and since that measuring all metabolites is not practical, the EKF and UKF...
Evaluation of the topographical surface changes of silicon wafers after annealing and plasma cleaning
, Article Silicon ; Volume 12, Issue 11 , 2020 , Pages 2563-2570 ; Ţălu, Ş ; Dallaev, R ; Arman, A ; Sobola, D ; Salerno, M ; Sharif University of Technology
Springer Science+Business Media B.V
2020
Abstract
Purpose: The morphological stability of silicon single crystal wafers was investigated, after performing cleaning surface treatments based on moderate temperature annealing and plasma sputtering. Methods: The wafer surfaces were measured by Tapping mode atomic force microscopy in air, before and after the different treatments. The 3D images were segmented by watershed algorithm identifying the local peaks, and the stereometric parameters were extracted thereof. The analysis of variance allowed to better assess the statistically significant differences. Results: All the resulting quantities were critically discussed. It appeared that the different cleaning treatments affected differently the...
Analysis of Authentication Protocols in RFID Systems
,
M.Sc. Thesis
Sharif University of Technology
;
Aref, Mohammad Reza
(Supervisor)
;
Eghlidos, Traneh
(Supervisor)
Abstract
Radio frequency identification systems (RFID) were used in the past to identify physical objects. Along with the development of RFID systems and its wide range of applications in our daily life, the need for privacy in such systems is becoming more and more significant. Authentication protocols are used as the care of secure communication to preserve the privacy and security in RFID systems. In this thesis the security of authentication protocols against general attacks are investigated, using two typical authentication protocols. As an alternative, we use a privacy model as another tool to analyze two other types of authentication protocols. The results reveal the weakness in the design of...
A Machine Learning-Based Hierarchical Risk Parity Approach for Portfolio Asset Allocation on the Tehran Stock Exchange
, M.Sc. Thesis Sharif University of Technology ; Habibi, Moslem (Supervisor) ; Fazli, Mohammad Amin (Co-Supervisor)
Abstract
The process of portfolio construction and optimization can be broken down into three main steps: selecting appropriate assets, allocating capital, and monitoring and adjusting the portfolio. This study focuses on evaluating the performance of the Hierarchical Risk Parity (HRP) method for capital allocation in investment portfolios, specifically in Iran’s capital market. The aim is to enhance the method's effectiveness by implementing alternative correlation calculation approaches, such as Wavelet and Chatterjee correlations. The study utilizes three different portfolios containing assets from the Tehran Stock Exchange, the US stock market, and the cryptocurrency market. The primary objective...
Electrokinetic Flow in pH-Regulated Solid-State/Soft Micro-Nanochannels
,
Ph.D. Dissertation
Sharif University of Technology
;
Saeedi, Mohammad Hassan
(Supervisor)
;
Mousavi, Ali
(Co-Supervisor)
;
Sadeghi, Arman
(Co-Supervisor)
Abstract
In recent years, advances have been made in the field of miniaturization of the devices (in order to increase their efficiency, lessen the materials needed for the constructions and experiments, reduce costs and energy usage) resulting in the dramatic increase of surface to volume ratio in these devices. This progress has led to the dominance of surface forces which can be used to control very important interface phenomena having a special application such as electrokinetic. Using today’s manufacturing technology; it is possible to construct micro-nanochannels made from different materials such as silicon, glass, quartz, polydimethylsiloxane (PDMS), polymethyl methacrylate (PMMA) whose...
The effect of thickness and film homogeneity on the optical and microstructures of the ZrO2 thin films prepared by electron beam evaporation method
, Article Optical and Quantum Electronics ; Volume 53, Issue 8 , 2021 ; 03068919 (ISSN) ; Talebani, N ; Zelati, A ; Ţălu, Ş ; Arman, A ; Mirzaei, S ; Jafari, A ; Sharif University of Technology
Springer
2021
Abstract
In this study, ZrO2 coatings with different thicknesses were grown by the electron beam evaporation technique. The crystalline structure was studied by XRD analysis which suggested the tetragonal and monoclinic phases for ZrO2 coatings. Additionally, the film thickness slightly enhanced the crystallinity. The surface morphology and fractal features were analyzed using Scanning Electron Microscopy (SEM). The surface statistical parameters and the fractal geometry were employed to analyze the impact of the coating thickness and homogeneity on the morphology of the films. The statistical processing and fractal dimension revealed variations in the morphology parameters due to the electron beam...
Plasma surface functionalization of boron nitride nano-sheets
, Article Diamond and Related Materials ; Volume 77 , 2017 , Pages 110-115 ; 09259635 (ISSN) ; Achour, A ; Solaymani, S ; Islam, M ; Vizireanu, S ; Arman, A ; Ahmadpourian, A ; Dinescu, G ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
On silicon substrates, boron nitride nanosheets (BNNS) consisting of interconnected hexagonal boron nitride nano-layers were produced via chemical vapor deposition process at 1200 °C whose roughness's are at the micrometer- and nanometer-scale. The BNNS were functionalized in argon plasma admixed with ammonia or nitrogen or oxygen. The samples were characterized to investigate the surface chemistry and structural changes after plasma treatment using X-ray photoelectron spectroscope and Micro-Raman spectroscope techniques, respectively. While no significant changes in the surface features, upon plasma treatments of the BNNS, were noticed during SEM and TEM examination, the oxygen functional...
Multiferroic behavior of the functionalized surface of a flexible substrate by deposition of Bi2O3 and Fe2O3
, Article Microscopy Research and Technique ; 2021 ; 1059910X (ISSN) ; Sobola, D ; Ţălu, Ş ; Orudzev, F ; Arman, A ; Kaspar, P ; Dallaev, R ; Ramazanov, G ; Sharif University of Technology
John Wiley and Sons Inc
2021
Abstract
Thin films of bismuth and iron oxides were obtained by atomic layer deposition (ALD) on the surface of a flexible substrate poly(4,4′-oxydiphenylene-pyromellitimide) (Kapton) at a temperature of 250°C. The layer thickness was 50 nm. The samples were examined by secondary-ion mass spectrometry, and uniform distribution of elements in the film layer was observed. Surface morphology, electrical polarization, and mechanical properties were investigated by atomic force microscope, piezoelectric force microscopy, and force modulation microscopy. The values of current in the near-surface layer varied in the range of ±80 pA when a potential of 5 V was applied. Chemical analysis was performed by...
Multifractal and optical bandgap characterization of Ta2O5 thin films deposited by electron gun method
, Article Optical and Quantum Electronics ; Volume 52, Issue 2 , 2020 ; Rezaee, S ; Mwema, F ; Luna, C ; Ghosh, K ; Jurečka, S ; Ţălu, Ş ; Arman, A ; Grayeli Korpi, A ; Sharif University of Technology
Springer
2020
Abstract
The micromorphology of tantalum pentoxide (Ta2O5) thin films, deposited on glass substrates by electron gun method, has been analyzed using atomic force microscopy (AFM), UV–Vis–NIR spectrophotometry and multifractal analyses. Two samples were grown at basic pressure of 7 × 10−6 mbar, work pressures of 1.3 × 10−4 and 2.0 × 10−4 mbar, and thicknesses of 0.38 μm and 0.39 μm, respectively. Subsequently, these samples were annealed at 300 °C for 2 h. The physical, structural and optical analyses were investigated by spectroscopic ellipsometry, spectrophotometry and AFM. The measured transmittance spectra were studied based on the Swanepoel method, whose results also yielded to the estimation of...