Sharif Digital Repository

In the present study, a one step hydrothermal process was employed to synthesize magnetite nanoparticles using oleic acid as surfactant agent at 140 °C. Effects of reaction time and alkalinity were studied on particles size and morphology. By changing these parameters, some monodisperse spherical nanoparticles with mean particle size between 2.71 and 13.88 nm were synthesized and characterized via TEM, XRD, VSM, TGA and FT-IR techniques. Assuming the Avrami behavior of particles formation, a kinetics equation was proposed for the transformation rate at 140 °C. Using some simplifying assumptions, nucleation and growth rates were calculated for the hydrothermal formation of magnetite... 

Superparamganetic iron oxide-based contrast agents in magnetic resonance imaging (MRI) have offered new possibility for early detection of lymph nodes and their metastases. According to important role of nanoparticle size in biodistribution, magnetite nanoparticles coated with different polyethylene glycol (PEG) concentrations up to 10/1 PEG/iron oxide weight ratio in an ex situ manner. To predict the PEG-coated nanoparticle behavior in biological media, such as blood stream or tissue, colloidal stability evaluation was performed to estimate the coating endurance in different conditions. Accordingly, optical absorbance measurements were conducted in solutions with different values of pH and... 

The solubility of hydrogen sulphide in three ionic liquids, viz. 1-hexyl-3-methylilmidazolium hexafluorophosphate ([hmim][PF6]), 1-hexyl-3-methylimidazolium tetrafluoroborate ([hmim][BF4]), and 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([hmim][Tf2N]), at temperatures ranging from 303.15 K to 343.15 K and pressures up to 1.1 MPa were determined. The solubility values were correlated using the Krichevsky-Kasarnovsky equation and Henry's constants were obtained at different temperatures. Partial molar thermodynamic functions of solvation such as standard Gibbs free energy, enthalpy, and entropy were calculated from the solubility results. Comparison of the values obtained... 

The solubility of hydrogen sulfide in three ionic liquids, 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]), 1-butyl-3-methylimidazolium tetrafluoroborate ([bmim][BF4]), and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][Tf 2N]), at temperatures ranging from (303.15 to 343.15) K and pressures up to 1 MPa was determined. The solubility data were correlated using the Krichevsky-Kasarnovsky equation, and Henry's law constants at different temperatures were obtained. From the solubility data, the partial molar thermodynamic functions of solution such as Gibbs energy, enthalpy, and entropy were calculated. Comparison showed that the solubility of H2S in these... 

In this study, Glucoamylase production by Aspergillus niger was investigated under solid state fermentation using low cost by-products of agricultural processes as substrate. Highest enzyme production was observed when a combination of wheat bran (WB) and corn flour (CF) was used as compared to WB+ rice bran, WB+ rice flour and WB alone. Several compositions of corn flours were experimented. The best combination of WB in addition of 10% corn flour resulted maximum enzyme activities. Study of the fermentations in flasks revealed 373.3 IU/gds and 41.4 g/l for the enzyme activity and protein concentration respectively under conditions of 30± 1°C, pH 4.7 and time 96 h. Optimum conditions... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

Recently, smart water (SmW) and nanocomposite (NC) flooding have shown good potential for enhanced oil recovery (EOR) processes. Although SmW and NCs are found to influence the oil recovery, there are still some controversies regarding their performance on wettability alteration (WA). To address this important question, we synthesized new NC materials with high hydrophilic properties. In this research, in the first stage, a NC was synthesized. The obtained compound was known as (UiO-66-NH2/TiO2/ZnO) (UNTZ). For the identification of NC, scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET), Fourier transform infrared spectroscopy (FTIR), and X-ray Diffraction (XRD) techniques were... 

To efficiently enhance the contrast obtaining from magnetic resonance imaging (MRI), pharmaceutical grade colloidal dispersions of PEG coated iron-based nanoparticles were prepared and compared to conventional pure iron oxide contrast agent. In this study, we synthesized ∼14 nm iron nanoparticles via NaBH4 reduction of iron(III) chloride in an aqueous medium. The resulting nanoparticles were further oxidized by two different methods via (CH3)3NO oxygen transferring agent and exposure to oxygen flow. XRD and electron microscopy analyses confirmed the formation of a second layer on the surface of α-Fe core. As magnetic measurements and Mössbauer spectra of 4-months post prepared nanoparticles... 

Magnetite nanoparticles (mean particle size ranging from 10 to 20 nm) were prepared by a biomoleculeassisted solution-phase approach under ultrasonic irradiation. Cysteine was used as the capping agent in the solution. The results show that cysteine could be an efficient biocapping agent in producing Fe3O4 nanoparticles. The crystal structure and magnetic properties of the nanoparticles were characterized by XRD and VSM techniques, respectively. FT-IR was used to investigate the presence of cysteine on the nanoparticles surface. The influence of pH value of the solution on the size distribution and hydrodynamic size of nanoparticles were studied by TEM and DLS methods, respectively. The MTT... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

Ground improvement techniques are inevitable for weak soils that cannot endure the design load imposed by superstructures. Deep mixing technique (DMT) as one of these methods is promising and effective when a deep soil layer with low bearing capacity is encountered. Such deposits are quite common in the South-west of Iran where the studied site is located. In order to validate the influence of DMT on the enhancement of strength, both in-situ and laboratory tests were conducted. Afterwards, a parametric study was carried out to investigate the influence of key factors including cement content, water–cement ratio, curing time and plasticity index (PI) on the performance of DMT. In summary, a... 

Pore facies analysis plays an important role in the classification of reservoir rocks and reservoir simulation studies. The current study proposes a two-step approach for pore facies characterization in the carbonate reservoirs with an example from the Kangan and Dalan formations in the South Pars gas field. In the first step, pore facieswere determined based on Mercury Injection Capillary Pressure (MICP) data in corporation with the Hierarchical Clustering Analysis (HCA) method. Each pore facies represents a specific type of pore geometry indicating the interaction between the primary rock fabric and its diagenetic overprints. In the next step, polynomial meta-models were established based... 

Large-scale simulation of spiking neural networks on hardware with a remarkable resemblance to their mathematical models is a key objective of the neuromorphic discipline. This issue is, however, considerably resource-intensive due to the presence of nonlinear terms in neuron models. This paper proposes a novel uniform piecewise linear segmentation approach for nonlinear function evaluations. Employing the proposed approach, we present a uniform-segmented adaptive exponential neuron model capable of accurately producing various responses exhibited by the original model and suitable for efficient large-scale implementation. In contrast to previous nonuniform-segmented neuron models, the... 

Ground-state pluripotency is a cell state in which pluripotency is established and maintained through efficient repression of endogenous differentiation pathways. Self-renewal and pluripotency of embryonic stem cells (ESCs) are influenced by ESC-associated microRNAs (miRNAs). Here, we provide a comprehensive assessment of the “miRNome” of ESCs cultured under conditions favoring ground-state pluripotency. We found that ground-state ESCs express a distinct set of miRNAs compared with ESCs grown in serum. Interestingly, most “ground-state miRNAs” are encoded by an imprinted region on chromosome 12 within the Dlk1-Dio3 locus. Functional analysis revealed that ground-state miRNAs embedded in the... 

In this research, a series of numerical simulations were conducted utilizing computational fluid dynamics (CFD) software in order to predict the heat transfer performance of queues nanofluids containing clove-treated graphene nanoplatelets (CGNPs) flowing in a horizontal stainless steel heated pipe. The GNPs were covalently functionalized with clove buds using free radical grafting reaction using an eco-friendly process. The advantage of this synthesis method was that it did not use hazardous acids, which are typically used in traditional treatment methods of carbon nanostructures. The thermo-physical properties of the aqueous nanofluids obtained experimentally were used as inputs for the... 

In this article, the buckling behavior of a nanoplate at the bottom of the channel over which the fluid passes with a one-dimensional flow was investigated. Navier–Stokes equations were used to obtain the applied force from the fluid to the nanoplate. Nonlocal elasticity theory was used to consider nanoscale effects, and this problem was solved using Galerkin’s weighted residual method. In previous research, the buckling behavior of nanoplates was done with the assumption of buckling in a vacuum, but in this study, the environment around the nanoplate is assumed to be a flowing viscous fluid. According to the results presented in this study, the critical buckling load of nanoplates coupled...