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Electrospun chitosan/polyvinyl alcohol nanocomposite holding polyaniline/silica hybrid nanostructures: An efficient adsorbent of dye from aqueous solutions
, Article Journal of Molecular Liquids ; Volume 331 , 2021 ; 01677322 (ISSN) ; Tati, A ; Ahmadipouya, S ; Haddadi, S. A ; Arjmand, M ; Sharif University of Technology
Elsevier B.V
2021
Abstract
In this work, the addition of a novel polyaniline (PANI)/silica (SiO2) nanostructure (PSn) in chitosan/polyvinyl alcohol nanofibers (CP) was evaluated to enhance the dye removal capacity of CP. Fourier transform infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS) results confirmed the chemical grafting of SiO2 on PANI nanoparticles. Brunauer-Emmett-Teller (BET) results showed a specific surface area of 61 m2 g−1 for the PSn filled CP nanofiber (CP-PSn). FE-SEM and EDS-elemental mapping results showed the uniform dispersibility of PSn in CP nanofibers. After the addition of PSn into CP, the adsorption capacity of...
Improving dye removal and antifouling performance of polysulfone nanofiltration membranes by incorporation of UiO-66 metal-organic framework
, Article Journal of Environmental Chemical Engineering ; Volume 10, Issue 3 , 2022 ; 22133437 (ISSN) ; Mousavi, S. A ; Shokrgozar, A ; Mousavi, D. V ; Sharif University of Technology
Elsevier Ltd
2022
Abstract
In the present work, a series of polysulfone (PSf) mixed-matrix nanofiltration membranes containing highly water stable UiO-66 metal-organic framework (MOF) were prepared via a simple phase inversion technique. At first, UiO-66 particles were synthesized via a solvothermal technique, activated via two various activation methods, including Soxhlet extraction and centrifugation methods. Then their adsorption performance was investigated for adsorption of anionic methyl orange (MO)/methyl red (MR) and cationic methylene blue (MB)/malachite green (MG) dyes from water. The activated UiO-66 particles via the Soxhlet extraction method (named S-UiO-66) showed better performance for dye adsorption...
Polyurethane-based membranes for CO2 separation: A comprehensive review
, Article Progress in Energy and Combustion Science ; Volume 97 , 2023 ; 03601285 (ISSN) ; Molavi, H ; Ahmadipouya, S ; Rezakazemi, M ; Ghaffarkhah, A ; Kamkar, M ; Shojaei, A ; Arjmand, M ; Sharif University of Technology
Elsevier Ltd
2023
Abstract
The membrane process has been considered a promising technology for effective CO2 capture due to its outstanding features, including a small environmental footprint, reduced energy consumption, simplicity of operation, compact design, ease of scalability and maintenance, and low capital cost. Among the developed polymeric materials for membrane fabrication, polyurethane (PU) and poly(urethane-urea) (PUU) as multi-block copolymers have exhibited great potential for CO2 capture because of their excellent mechanical properties, high thermal stability, good film formation ability, favorable permeation properties, and a large diversity of monomers (i.e., polyol, diisocyanate, and chain extender)...
Superior chemical stability of UiO-66 metal-organic frameworks (MOFs) for selective dye adsorption
, Article Chemical Engineering Journal ; Volume 399 , 2020 ; Mohammadkhani, R ; Ahmadipouya, S ; Shokrgozar, A ; Rezakazemi, M ; Molavi, H ; Aminabhavi, T. M ; Arjmand, M ; Sharif University of Technology
Elsevier B.V
2020
Abstract
The presence of dyes as pollutants in wastewater sources from textile industries can cause significant health issues if they are not adequately treated. Dye adsorption to entrap contaminants in nanoparticle pores has created considerable attention in recent years due to the environmental concerns occurring as a result of spillage of dyes in water bodies. In efforts to understand adsorption capability UiO-66, metal-organic frameworks (MOFs) were developed and examined for the separation of four pollutant dyes containing methyl red (MR), methyl orange (MO), malachite green (MG), and methylene blue (MB), which are widely used in textile industries. The adsorbent structural stability in water,...
CO2/CH4 separation by mixed-matrix membranes holding functionalized NH2-MIL-101(Al) nanoparticles: Effect of amino-silane functionalization
, Article Chemical Engineering Research and Design ; Volume 176 , 2021 , Pages 49-59 ; 02638762 (ISSN) ; Ahmadijokani, F ; Molavi, H ; Rezakazemi, M ; Arjmand, M ; Sharif University of Technology
Institution of Chemical Engineers
2021
Abstract
In this study, NH2-MIL-101(Al) metal-organic frameworks (MOFs) covered with 3-aminopropyltriethoxysilane (APTES) were incorporated into the polyethersulfone (PES) to produce mixed-matrix membranes (MMMs) for CO2 separation. The APTES functionalization was performed to improve the MOF dispersion in the PES matrix. Different analyses such as X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and field emission scanning electron microscopy (FESEM) revealed that the MOFs surface successfully functionalized with APTES. An improvement in CO2/CH4 separation efficiency was observed in MMMs, and the performance...
CO2/CH4 separation by mixed-matrix membranes holding functionalized NH2-MIL-101(Al) nanoparticles: Effect of amino-silane functionalization
, Article Chemical Engineering Research and Design ; Volume 176 , 2021 , Pages 49-59 ; 02638762 (ISSN) ; Ahmadijokani, F ; Molavi, H ; Rezakazemi, M ; Arjmand, M ; Sharif University of Technology
Institution of Chemical Engineers
2021
Abstract
In this study, NH2-MIL-101(Al) metal-organic frameworks (MOFs) covered with 3-aminopropyltriethoxysilane (APTES) were incorporated into the polyethersulfone (PES) to produce mixed-matrix membranes (MMMs) for CO2 separation. The APTES functionalization was performed to improve the MOF dispersion in the PES matrix. Different analyses such as X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), and field emission scanning electron microscopy (FESEM) revealed that the MOFs surface successfully functionalized with APTES. An improvement in CO2/CH4 separation efficiency was observed in MMMs, and the performance...
Magnetic Fe3O4@UiO-66 nanocomposite for rapid adsorption of organic dyes from aqueous solution
, Article Journal of Molecular Liquids ; Volume 322 , 2021 ; 01677322 (ISSN) ; Heidarian Haris, M ; Ahmadijokani, F ; Jarahiyan, A ; Molavi, H ; Matloubi Moghaddam, F ; Rezakazemi, M ; Arjmand, M ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Human society is becoming more intransigent on removing organic dyes from polluted water before discharging to the environment. To fulfill this goal, a magnetic metal-organic framework adsorbent based on functionalized magnetic Fe3O4 nanoparticles and highly water stable UiO-66 with high porosity and sensitivity to the external magnetic field was designed and synthesized via an easy step-by-step self-assembly technique. The synthesized adsorbent magnetic nanoparticles (Fe3O4@UiO-66) were applied to remove organic dyes, i.e., methyl orange (MO) and methylene blue (MB), from a contaminated aqueous solution. The experiments displayed that magnetic Fe3O4@UiO-66 has good adsorption uptake for MO...
Magnetic Fe3O4@UiO-66 nanocomposite for rapid adsorption of organic dyes from aqueous solution
, Article Journal of Molecular Liquids ; Volume 322 , 2021 ; 01677322 (ISSN) ; Heidarian Haris, M ; Ahmadijokani, F ; Jarahiyan, A ; Molavi, H ; Matloubi Moghaddam, F ; Rezakazemi, M ; Arjmand, M ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Human society is becoming more intransigent on removing organic dyes from polluted water before discharging to the environment. To fulfill this goal, a magnetic metal-organic framework adsorbent based on functionalized magnetic Fe3O4 nanoparticles and highly water stable UiO-66 with high porosity and sensitivity to the external magnetic field was designed and synthesized via an easy step-by-step self-assembly technique. The synthesized adsorbent magnetic nanoparticles (Fe3O4@UiO-66) were applied to remove organic dyes, i.e., methyl orange (MO) and methylene blue (MB), from a contaminated aqueous solution. The experiments displayed that magnetic Fe3O4@UiO-66 has good adsorption uptake for MO...
The relationship between an EFL teacher's gender and students' willingness to communicate
, Article International Journal of Communication and Linguistic Studies ; Volume 10, Issue 4 , 2013 , Pages 17-29 ; 23277882 (ISSN) ; Pakzadian, S. S
Common Ground Publishing
2013
Abstract
Learning a foreign language encompasses a process of trial and error that can lead to the progression of the learner's interlanguage, meaning that the learners make use of their language knowledge that receives feedback and brings about progress through diagnosis of the problems and being corrected by the teacher. Therefore, there exists a need to analyze the underlying reasons causing the students to remain taciturn with a low willingness to communicate (WTC) during a language class. There has been much work done investigating the role of the learner's stable personal characteristics (traits) along with their situational changes at a specific time (states) that influence the student's...
An automated simple algorithm for realistic pore network extraction from micro-tomography images
, Article Journal of Petroleum Science and Engineering ; Vol. 123, issue , 2014 , pp. 164-171 ; ISSN: 09204105 ; Jamshidi, S ; Salehi, S
2014
Abstract
Using 3-D scanned data to analyze and extract pore network plays a vital role in investigation of porous media's characteristics. In this paper, a new simple method is developed to detect pores and throats for analyzing the connectivity and permeability of the network. This automated method utilizes some of the common and well-known image processing functions which are widely accessible by researchers and this has led to an easy algorithm implementation. In this method, after polishing and quality control of images, using city-block distance function and watershed segmentation algorithm, pores and throats are detected and 3-D network is produced. This method can also be applied on 2-D images...
Discrimination of heart arrhythmias using novel features in heart rate phase space
, Article Computing in Cardiology ; Volume 40 , Sept , 2013 , Pages 1035-1038 ; 23258861 (ISSN); 9781479908844 (ISBN) ; Rezaei, S ; Salavatian, S
2013
Abstract
In this paper, we try to recognize and distinguish different groups of arrhythmia using novel features which have been obtained from the heart rate's phase space in recent years. For this purpose, we used Triangular Phase Space Mapping (TPSM) and Parabolic Phase Space Mapping (PPSM). For recognition, we used three groups of 15 subjects using the Physionet database (Arrhythmia, Congestive Heart Failure (CHF), and Atrial Fibrillation (AF)) with Normal Sinus Rhythm (NSR). The obtained features discriminate arrhythmia from NSR by p
An intelligent hybrid classification algorithm integrating fuzzy rule-based extraction and harmony search optimization: Medical diagnosis applications
, Article Knowledge-Based Systems ; Volume 220 , 2021 ; 09507051 (ISSN) ; Abdullah, S ; Akhavan Niaki, S. T ; Banihashemi, S ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Uncertainty is a critical factor in medical datasets needed to be overcome for increasing diagnosis efficiency. This paper proposes an intelligent classification algorithm comprising a fuzzy rule-based approach, a harmony search (HS) algorithm, and a heuristic algorithm to classify medical datasets intelligently. Two fuzzy approaches, as well as orthogonal and triangular fuzzy sets, are first utilized to define the attributes of data. Then, an HS algorithm is integrated with a heuristic to generate fuzzy rules to select the best rules in the fuzzy rule-based systems. Moreover, to improve the performance of the proposed classification approach, a three-phase parameter tuning approach is...
Performance evaluation of shared hosting security methods
, Article Proc. of the 11th IEEE Int. Conference on Trust, Security and Privacy in Computing and Communications, TrustCom-2012 - 11th IEEE Int. Conference on Ubiquitous Computing and Communications ; 2012 , Pages 1310-1315 ; 9780769547459 (ISBN) ; Arshad, S ; Khoshkdahan, S ; Sharif University of Technology
2012
Abstract
Shared hosting is a kind of web hosting in which multiple websites reside on one webserver. It is cost-effective and makes the administration easier for websites' owners. However, shared hosting has some performance and security issues. In default shared hosting configuration, all websites' scripts are executed under the webserver's user account regardless of their owners. Therefore, a website is able to access other websites' resources. This security problem arises from lack of proper isolation between different websites hosted on the same webserver. In this survey, we have examined different methods for handling mentioned security issue. Also we evaluated the performance of mentioned...
The behaviour of an artificially cemented sandy gravel
, Article Geotechnical and Geological Engineering ; Volume 23, Issue 5 , 2005 , Pages 537-560 ; 09603182 (ISSN) ; Hosseini, S. M ; Toll, D. G ; Yasrebi, S. S ; Sharif University of Technology
2005
Abstract
The major section of the city of Tehran, Iran has been developed on cemented coarse-grained alluvium. This deposit consists of gravely sand to sandy gravel with some cobbles and is dominantly cemented by carbonaceous materials. In order to understand the mechanical behaviour of this soil, a series of undrained triaxial compression tests and unconfined compression tests were performed on uncemented and artificially cemented samples. Portland cement type I was used as the cementation agent for preparing artificially cemented samples. Uncemented samples and lightly cemented samples (1.5% cement) tested at high confining pressure showed contractive behaviour accompanied with positive excess pore...
An imperialist competitive algorithm approach for multi-objective optimization of direct coupling photovoltaic-electrolyzer systems
, Article International Journal of Hydrogen Energy ; Vol. 39, Issue 33 , 11 November , 2014 , pp. 18743-18757 ; ISSN: 03603199 ; Sayedin, F ; Khavas, S. S
2014
Abstract
In the context of sustainable clean hydrogen production pathways, photovoltaic-electrolyzer systems are one of the most promising alternatives for acquiring hydrogen from renewable energy sources. In fact, determining the optimal set of design and operating variables are always a key issue while coupling directly renewable electricity sources to PEM electrolyzers. Few previous studies have attempted to find the optimal size and operational condition of directly coupled photovoltaic-electrolyzer (PV/El) systems in order to maximize the hydrogen production or to minimize energy transfer loss between photovoltaic devices and the electrolyzer. Nevertheless an easy and efficient approach still...
Kalman filter based packet loss replacement in presence of additive noise
, Article 2012 25th IEEE Canadian Conference on Electrical and Computer Engineering: Vision for a Greener Future, CCECE 2012 ; 2012 ; 9781467314336 (ISBN) ; Ghorshi, S ; Tahaei, A
2012
Abstract
A major problem in real-time packet-based communication systems, is misrouted or delayed packets which results in degraded perceived voice quality. If packets are not available on time, the packets are considered as lost. The easiest solution in a network terminal receiver is to replace silence for the duration of lost speech segments. In a high quality communication system, to avoid degradation in speech quality due to packet loss, a suitable method or algorithm is needed to replace the missing segments of speech. In this paper, we introduce an adaptive filter for replacement of lost speech segment. In this method Kalman filter as a state-space based method will be used to predict the...
Investigation of Mesh Sensitivity Influence to Determine Crack Characteristic by Finite Element Methods
, Article Journal of Failure Analysis and Prevention ; Volume 16, Issue 3 , 2016 , Pages 506-512 ; 15477029 (ISSN) ; Mirjavadi, S. S ; Asli, S. A ; Sharif University of Technology
Springer New York LLC
2016
Abstract
In this research, an extended finite element model has been investigated. Investigation of opening and closure stress always has been one of the difficult parameters to analysis of results; therefore, the utilization of finite element methods would be a good and logical alternative for this purpose. In addition, linear elastic fracture criteria are used for validation of numerical results from the simulation. In this work, a detailed analysis of the influence of different parameters in the results of a specific specimen with a semi-elliptical tooling groove in terms of closure and opening stress is presented, and the impact of optimum element size in fracture characteristic in various load...
Investigation of the effect of nanosilica on rheological, thermal, mechanical, structural, and piezoelectric properties of poly(vinylidene fluoride) nanofibers fabricated using an electrospinning technique
, Article Industrial and Engineering Chemistry Research ; Volume 56, Issue 44 , 2017 , Pages 12596-12607 ; 08885885 (ISSN) ; Ahmad Ramazani, S. A ; Talebi, S ; Fattahpour, S ; Hasany, M ; Sharif University of Technology
2017
Abstract
The effects of different nano-SiO2 contents on the rheological properties of poly(vinylidene fluoride) (PVDF) solution and mechanical, thermal, structural, and piezoelectric properties of composite nanofibers were investigated. Results showed an increase in fiber diameter (∼125 to 350 nm) and ∼450% increase in tensile strength as the content of nano-SiO2 particles increased. The degree of crystallinity decreased by 19% as the nano-SiO2 content increased by 2% (w/w). Further investigation demonstrated that silica could significantly improve the piezoelectric properties of PVDF nanofibers as the output voltage showed an increase in the presence of silica attributed to change in the crystalline...
A method for real-time safe navigation in noisy environments
, Article 2013 18th International Conference on Methods and Models in Automation and Robotics, MMAR 2013, Miedzyzdroje ; 2013 , Pages 329-333 ; 9781467355063 (ISBN) ; Kamali, E ; Niknezhad, M. R ; Monfared, S. S. M. S ; Sharif University of Technology
2013
Abstract
The challenge of finding an optimized and reliable path dates back to emersion of mobile robots. Several approaches have been developed that have partially answered this need. Satisfying results in previous implementations has led to an increased utilization of sampling-based motion planning algorithms in recent years, especially in high degrees of freedom (DOF), fast evolving environments. Another advantage of these algorithms is their probabilistic completeness that guarantees delivery of a path in sufficient time, if one exists. On the other hand, sampling based motion planners leave no comment on safety of the planned path. This paper suggests biasing the Rapidly-exploring Random Trees...
A generalization of the swartz equality
, Article Glasgow Mathematical Journal ; Vol. 56, issue. 2 , May , 2014 , pp. 381-386 ; ISSN: 00170895 ; Fakhari, S. A. S ; Yassemi, S ; Sharif University of Technology
2014
Abstract
For a given (d-1)-dimensional simplicial complex Γ, we denote its h-vector by h(Γ)=(h 0(Γ),h 1(Γ),...,hd (Γ)) and set h -1(Γ)=0. The known Swartz equality implies that if Δ is a (d-1)-dimensional Buchsbaum simplicial complex over a field, then for every 0 ≤ i ≤ d, the inequality ihi (Δ)+(d-i+1)h i-1(Δ) ≥ 0 holds true. In this paper, by using these inequalities, we give a simple proof for a result of Terai (N. Terai, On h-vectors of Buchsbaum Stanley-Reisner rings, Hokkaido Math. J. 25(1) (1996), 137-148) on the h-vectors of Buchsbaum simplicial complexes. We then generalize the Swartz equality (E. Swartz, Lower bounds for h-vectors of k-CM, independence, and broken circuit complexes, SIAM J....