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akbar-shirazian--soheil
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Fabricating Graphene Paper and Determining Its Electrical and Mechanical Properties and Using It for Proliferation and Differentiation of Neural Stem Cells
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
Nowadays, tissue engineering and stem cells-based therapies have outlined a promising prospect in neural networks regeneration. But it usually requires biocompatible and conductive scaffolds for culturing neural stem cells and directing their differentiation toward the neurons. Graphene due to its unique physical and chemical properties has attracted much interest in tissue engineering. For this purpose, in this study biocompatible graphene oxide foams have been used for neural stem cell culturing. For the first time, graphene oxide foam were fabricated by precipitation of chemically exfoliated graphene oxide sheets in an aqueous suspension onto the PET substrate at ~80 oC under UV...
Studying the Problem of Maximum Matching in Stochastic Environments
, M.Sc. Thesis Sharif University of Technology ; Ghodsi, Mohammad (Supervisor)
Abstract
The problem studied in this research is the online stochastic bipartite matching. In this problem the vertices of one side of the given graph arrive in an online manner, with respect to a probability distribution. Also the edges of the graph exist according to a given probability distribution and one should perform queries from an oracle to know about the existence of an edge. The given graph shall be weighted or unweighted. The goal here is to find a maximum matching in the graph that is as close to the omniscient optimum as possible, while the number of queries performed per vertex is limited. In the general case of the problem, there are no specific conditions, but in other versions,...
Near infrared laser stimulation of human neural stem cells into neurons on graphene nanomesh semiconductors
, Article Colloids and Surfaces B: Biointerfaces ; Volume 126 , 2015 , Pages 313-321 ; 09277765 (ISSN) ; Ghaderi, E ; Shirazian, S. A ; Sharif University of Technology
2015
Abstract
Reduced graphene oxide nanomeshes (rGONMs), as p-type semiconductors with band-gap energy of ~1. eV, were developed and applied in near infrared (NIR) laser stimulation of human neural stem cells (hNSCs) into neurons. The biocompatibility of the rGONMs in growth of hNSCs was found similar to that of the graphene oxide (GO) sheets. Proliferation of the hNSCs on the GONMs was assigned to the excess oxygen functional groups formed on edge defects of the GONMs, resulting in superhydrophilicity of the surface. Under NIR laser stimulation, the graphene layers (especially the rGONMs) exhibited significant cell differentiations, including more elongations of the cells and higher differentiation of...
Predictive construction of phase diagram of ternary solutions containing polymer/solvent/nonsolvent using modified Flory-Huggins model
, Article Journal of Molecular Liquids ; Volume 263 , 2018 , Pages 282-287 ; 01677322 (ISSN) ; Nazem, H ; Rezakazemi, M ; Shirazian, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
The Flory-Huggins (FH) model has been one of the most used models in theoretical calculations which has been proved to be sensitive to values assigned as interaction parameters. In this work, a predictive equation is implemented to implicitly couple the concept of compressible regular solution theory of Ruzette and Mayes into the original FH model to obtain a new concertation-dependent interaction parameter equation. Then, the modified model (m-FH) is applied for construction of phase diagram of ternary solutions containing polymer/solvent/nonsolvent where experimental data for ternary systems were collected from the literature. In order to compare and analyze the model performance, the...
Modelling of Frictional Cracks by the Extended Finite Element Method Considering the Effect of Singularity
, M.Sc. Thesis Sharif University of Technology ; Khonsari, Vahid (Supervisor) ; Mohammadi, Soheil (Co-Advisor)
Abstract
When a crack is subjected to a compression field, it will close and its edges will get into contact with each other. Depending on the direction and magnitude of the loads and also the coefficient of friction, ‘stick’ or ‘slip’ situationsbetween the edges will occur. This type of crack is known as ‘frictional crack.’ In this project, first these cracks are studied analytically and the order of singularity is derived using asymptotic analysis and also the analytical fields are determined for both ‘isotropic’ and ‘orthotropic’ materials. Then, numerical simulations are carried out using extended finite element method which is considered as the most powerful means for analyzing the problems...
Density Functional Theory Study of Electric Fields Effect on Gold Nanoparticles
, M.Sc. Thesis Sharif University of Technology ; Khoei, Amir Reza (Supervisor) ; Shahsavari,Rozbeh (Supervisor)
Abstract
Unique properties of Gold at nanoscale have made it one of the most popular substances used in nanotechnology. The interaction of Gold and Thiolates is one of the most favorite fields of research. Extensive studies about this interaction have revealed the importance and usage of this system in future technology. Due to difficulties of experimentationat nanoscale, computer simulations arevery important. Although interatomic potentials lead to higher computational speeds, they have deficiencies in precise simulation of some phenomena. Ab-initio methods, such as density functional theory, provide powerful tools to increase the accuracy. In this research, the interaction of gold and thiolates...
Rolled graphene oxide foams as three-dimensional scaffolds for growth of neural fibers using electrical stimulation of stem cells
, Article Carbon ; Volume 97 , 2016 , Pages 71-77 ; 00086223 (ISSN) ; Ghaderi, E ; Shirazian, S. A ; Rahighi, R ; Sharif University of Technology
Elsevier Ltd
2016
Abstract
Graphene oxide foam (GOF) layers with thicknesses of ∼15-50 μm and density of ∼10 graphene oxide (GO) sheets/μm were fabricated by precipitation of chemically exfoliated GO sheets in an aqueous suspension at ∼80 °C under UV irradiation. Then, rolled GOFs with desirable scales were developed as electrically conductive 3D-scaffolds and applied in directional growth of neural fibers, through differentiation of human neural stem cells (hNSCs) into neurons under an electrical stimulation. X-ray photoelectron spectroscopy indicated that the UV irradiation resulted in partial deoxygenation of the layers. Scanning electron microscopy and Raman spectroscopy confirmed the presence of multilayer GO...
Experimental investigation and thermodynamic modeling of amino acids partitioning in a water/ionic liquid system
, Article Journal of Molecular Liquids ; Volume 260 , 15 June , 2018 , Pages 386-390 ; 01677322 (ISSN) ; Ghotbi, C ; Habibi Zare, M ; Shirazian, S ; Sharif University of Technology
Elsevier B.V
2018
Abstract
Amino acids partitioning including phenylalanine, glutamic acid, and tryptophan in aqueous and ionic liquid phases at temperature of 298.15 K and atmospheric pressure were measured. 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide used in this work can produce two phases with water immediately. The effect of aqueous solution pH on amino acids partitioning was studied and revealed that amino acid partitioning coefficient was decreased with increasing pH. This phenomenon pertains to the electrostatic interaction between cations of amino acid and the anions of ionic liquid which is decreased when pH increases. Considering the effect of pH, liquid-liquid equilibrium data of amino...
Theoretical and Numerical Analysis of Shock Waves Propagation in Porous Medium
, Ph.D. Dissertation Sharif University of Technology ; Ahmadi, Mohammad Mehdi (Supervisor) ; Mohammadi, Soheil ($item.subfieldsMap.e)
Abstract
Particulate porous mateials have always been of interest in terms of reducing shock waves effects in different protective applications. Therefore, the physics governing the flow in porous media is especially significant for which different models have been presented by the researchers. The complexities of these media have caused many existing models to be unable to properly predict the behavior of granular media under shock loadings. On the other hand, the complexity of the equations makes the numerical solution of them cumbersome and costly in a way that many researchers do not solve the whole coupled equations and reduce their number. In addition, current high-resolution TVD solutions of...
Mass transfer through PDMS/zeolite 4A MMMs for hydrogen separation: Molecular dynamics and grand canonical Monte Carlo simulations
, Article International Communications in Heat and Mass Transfer ; Volume 108 , 2019 ; 07351933 (ISSN) ; Amirkhani, F ; Khadem, S. A ; Rezakazemi, M ; Asghari, M ; Shirazian, S ; Sharif University of Technology
Elsevier Ltd
2019
Abstract
In industry, utilizing membrane separation technology to purify natural gas streams is of remarkable significance. Molecular Simulation was used in the current article to study the structural and gas separation properties of polydimethylsiloxane (PDMS)/zeolite 4A Mixed Matrix Membranes (MMMs). To explore the optimal performance of MMMs, several structural analyses, namely Fractional Free Volume (FFV), Radial Distribution Function (RDF), X-Ray Diffraction (XRD) and also Glass Transition Temperature (Tg) as one of the most important properties of membranes have been evaluated. Also, the solubilities and diffusivities of periodic cells were respectively measured using MSD and adsorption...
Bioactivity of Surface Modified Titanium Alloy Ti-6Al-4V ELI by Pack Siliconizing in Simulated Body Fluid
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor) ; Ziaei Moayyed, Ali Akbar (Supervisor)
Abstract
Titanium alloy Ti-6Al-4V ELI with high biocompatibility and corrosion resistance, has a lot of applications in biomedical engineering. Disadvantage of this alloy is it’s disability to create a fast and good contact with the host/bone environment, after implanting in the body. Beside that it has low wear resistance. Nowadays to optimize the wear resistance, bioactivity and osteoconduction of surface of implants which are made from this alloy, the surface morphology are optimized in size and distribution. Different surface treatments are used for producing rough and porous surfaces to improve bioactivity along with wear resistance. In this study, surface modification of Ti-6Al-4V ELI was done...
Characterization of Metallurgical and Geometrical Parameters on Fracture Behavior of Pure Titanium thin Sheets
, M.Sc. Thesis Sharif University of Technology ; Ekrami, Ali Akbar (Supervisor) ; Ziaei Moayyed, Ali Akbar (Supervisor)
Abstract
Commercially pure titanium (CP-Ti) is an important groups of titanium family and because of high strength, low density, high corrosion resistance and biocompatibility, this group of titanium is a suitable choice for application at chemical, petrochemical and medicine industry. Nowadays surgeons have a tendency toward use of CP-Ti instead of Ti-6Al-4V alloy. Moreover, because of body anatomy limitation, use of thick sheets result in high volume and damage soft tissue. Therefore, for sheet thickness reduction, study of the effects of metallurgical and geometrical parameter on fracture behavior of thin sheets is important. In this study, the fracture behavior of CP-Ti thin sheets investigated....
Investigation of the Role of Fiber Reinforcement on the Performance of Rubber Based Friction Material
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
Friction composites, as a part of vehicle safety system, should hold some characteristics such as high wear resistance, low weight, durability, low noise, stable friction coefficient, availability and low price. It is very interested to use mixture of rubber and resin in friction materials to reach good properties of both rubber and resin simultaneously. This mixture is especially used in railway’s brake pads. Fibrous reinforcement is another important ingredient in friction composites. Asbestos used to be the most significant fibrous reinforcement due to its appropriate tribological specifications but the recent ban on asbestos by environmental protection agency has forced the friction...
Experimental and Theoretical Investigation on the Frictional Performance of Friction Materials of Brake System
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
Various composite friction materials containing 40 vol.% organic binder (phenolic resin plus styrene-butadiene-rubber (SBR)) with varying phenolic-resin/SBR ratio were prepared. The content of phenolic resin in each composite was indicated by the resin value (RV) index ranging between 0-100%. The composites with RVs greater than 50% form resin-based friction materials in which the primary binder is the phenolic resin. For RVs less than 50%, the composites become the rubber-based materials where the primary binder is the SBR. The analysis of mechanical properties exhibited that the conformability of the composites increases upon incorporation of SBR. The frictional analysis revealed that type...
Neutral Spin Collective Mode in Carbon Nanotubes
, M.Sc. Thesis Sharif University of Technology ; Jafari, Akbar (Supervisor)
Abstract
In 2002 Baskaran and Jafari published an article that was about a spin-1 collective mode. Similarity between carbon nanotubes and graphene was a motivation for working on this project, in order to find another spin mode by considering random phase approximation as a simple way of finding collective motion of a physical systems. Moreover rolling graphene sheet induce diffrent physical properties as a result of chiral axis . In this project we focus only on achiral nanotubes and at last find two collective modes in this structures
Investigation on the Effect of MWCNT on the Properties of NR/SBR Rubber Blend and the Comparison with Conventional and High Structure Carbon Blacks
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
In recent years, using the nanoparticles has caused a great revolution and development into the materials structure and the polymer science developed corresponding to important role of it in consumer goods. So Carbon Nano Tubes (CNTs) belonging to the precious physical, Mechanical and thermal properties has been studied. The CNT is mixed by mechanical and solution methods with elastomeric matrix. In this research the mechanical method used, because of industrial applications. Although, there are many challenges against dispersion owing to weak cohesion between CNTs and matrix in the mechanical method. The progress in rubber composites reinforced by CNTs and other reinforcement and as well as...
Evaluating and Improving the Reliability of Reversible Adiabatic Logic Styles
, M.Sc. Thesis Sharif University of Technology ; Ejlali, Alireza (Supervisor)
Abstract
Adiabatic logic families are a group of logic circuits which operate based on adiabatic principles to tremendously reduce power consumption. These families have basic difference with common logic families in transistor level structure and there signals are not quadrangular but trapezoidal. Also, in these systems the source lines and clock pulse are the same. Research on Adiabatic families needs theoretical information in reversible computing. So we will start this project with explaining fundamental information in this field. After that some of these logic families are introduced and three important and widely used of them (SCRL-RERL-2LAL) are chosen to simulate. In each of these families...
Fabrication and Characterization of Phenolic Resin/Glass Fiber/Organoclay Nanocomposites
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
In this research the effects of addition of clay in phenolic glass fiber reinforced composite has been investigated. Layered clay/phenolic nanocomposite resin systems were first prepared with 0.5, 1.5 and 2.5 wt% of Cloisite Na+ (CN) and Cloisite 30B (CB). After that the suspension was hold in an ultrasonic bath for 30 min in order to enhance nanodispersion of the clay platelet within the resin. The phenolic/clay solution was used to impregnate the glass fabric using the solvent impregnation method. After suspension for 2 days in the room with natural condition, the impregnated fabrics were pre-cured at 135 ˚C in an oven for 3.5 min to obtain B-stage prepregs. Seven layers of prepregs (150...
Modeling and Optimization of Composite Brake Friction Materials Formulation
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
Automotive brake pad is one of the most widely used composites. Commonly, more than 10 components are applied to make these materials and due to the large number of components and interactions between them, choice, explaination of the behavior and optimization of brake friction materials are some industry's challenges. Until now, some methods have been presented to design and optimization of these materials, but due to different complexities, there is lack of practical method that could be used for explaining the tribological behavior, engineering calculation and optimization of brake friction materials. Today, formulation of the current brake pads in the industry has mainly come from trial...
An Investigation on the Behavior of Nanoparticle Filled Brake Friction Materialls
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor)
Abstract
The most common type of polymer based composite friction materials are usually in vehicles as the brake pads are used and must characteristics such as high wear resistance, low weight, durability, low noise and stable friction coefficient. Polymer matrix, in addition to providing other material suitable for storage, the final properties, including mechanical properties, heat, friction and wear is also effective. Thermoset resin polymer matrixes (usually phenolic resin) are used in the brake pads which used for automotive and in some cases, rubber particles as powder formulations may be entered, in order to achieve good properties of rubber and resin simultaneously. Nanofillers because of...