Sharif Digital Repository

In this project, synthesis of sol-gel derived Pb(Zr0.52Ti0.48)O3 nanotubes in the form of PZT-CNT hybrid, was accomplished by using multi-walled carbon nanotubes as sacrificial template. Simultaneous thermal analyses proved that the as-derived amorphous material crystallized at a significantly low temperature by a considerably low activation energy. X-ray diffraction and selected area electron diffraction patterns showed that the final crystal structure is tetragonal perovskite. Raman spectroscopy results proved that significant changes happened at the surface of carbon nanotubes which are believed to be due to coating. Electron images supported the deposition of a coating on the surfaces of... 

Titanium and its alloys have wide applications in industry and recently researches have been expanded in this area. The main reasons are unique features of titanium such as biological behavior, corrosion resistance and high strength to weight ratio. The fundamental problem of titanium is low wear resistance that leads to be worn in industrial applications. For more efficiency of titanium, extensive efforts have been made for solving this problem, one of the best solutions is coating.Micro Arc Oxidation (MAO) is a novel method to create ceramic coatings on metals to improve wear and corrosion resistance. In this research nano alumina particles were added to electrolyte to create... 

In recent years, mesoporous nanocrystalline TiO2 films have been regarded extensively. This kind of materials due to having unique surface area, structural and bulk properties, is used in many technological applications. In this work, a stable TiO2 sol was prepared using F127 Copolymer template and evaporation induced self-assembly method (EISA). The mesoporous TiO2 powders and thin films were then prepared. The as-deposited thin films were aged under five different conditions for 72h. Finally the samples were heat treated at 350°C, 400°C and 450°C. N2 adsorption/desorption results verified formation of mesoporous structure. Moreover, x-Ray diffraction patterns exhibited that the synthesized... 

In the present work preparation of Ni-TiO2 films and their microstructural and mechanical properties were studied. For film preparation, DC current mode of electrochemical deposition method was used in Watts Nickel bath with different concentrations of transparent TiO2 sol up to 30 mL/L. It presents a new generation of nano Ni-TiO2 coating as a composite film for corrosion and erosion resistance applications. The best wear volume of 0.0046 mm3 was achieved for 30 mL/L Ni-TiO2 nanocomposite in comparison to 0.0071 mm3 for pure Ni film. Moreover, the coating hardness increased to ~345 HV50 for Ni-TiO2 nanocomposite. Corrosion rate of the coatings improved down to 1.10E-05 mm/year with addition... 

Methiocarb [3,5-dimethyl-4-(methylthio) phenyl methylcarbamate] is an N-methylcarbamate with neurotoxic action. Because carbamate pesticides are acetylcholinesterase inhibitors, they are considered to be carcinogens and mutagens. Methiocarb pesticide is widely used throughout the world particularly effective as fungicides, insecticide and bird repellent. To prevent its harmful effects on animals, humans, and the environment, it is of crucial importance to develop simple and sensitive methods for in-situ detection of methiocarb. This research describes a simple and low-cost method for on-site monitoring of methiocarb insecticide. Gold nanoparticles (AuNPs) aggregation caused by methiocarb,... 

Perovskite solar cells are the new generation of solar cells, and are mainly introduced in two types of structures.1) planer and 2) mesoscopic structure. The difference between these two structures derives from the absence of mesoporous layer in the planer structures. The mesoporous layer acts as an electron transporting layer, and is mainly a titanium dioxide semiconductor. To apply the mesoporous layer, the preparation of the TiO2 paste is needed.The synthesis of titanium dioxide nanopowder for the preparation of TiO2 paste requires high temperature heat treatment and is not desirable in terms of energy consumption.Another weakness of this layer is the presence of surface defects, which... 

This work describes the effect of hydroxyapatite with different morphology including nanorods and whisker on the properties of hydroxyapatite/polycaprolactone (HA/PCL) composite. Biodegradable polymer/Hydroxyapatite (HA) composites with the morphology of nanorods and whisker of (HA) as bone replacement scaffolds are synthesized by sol-gel and hydrothermal methods, respectively with a Ca/P ratio of 1.67 and 20:80 (HA/PCL).The crystallization behavior and porosity of HA/PCL composite are studied by scanning electron microscope and X-Ray diffraction. The response of bone marrow-derived human mesenchymal stem cells (hMSCs) in terms of cell proliferation and differentiation to the osteoblastic... 

In the present work, we have designed a novel CdS/CdTe solar cell based on CdS nanowires, as a window layer, and CdTe nanoparticles, as a absorber layer. CdS nanowires and CdTe nanoparticles were synthesized by solvothermal method. The samples were characterized by X-ray diffraction diffractometer (XRD), field emission scanning electron microscope (FE-SEM), Atomic Force Microscope (AFM) and Ultraviolet–Visible (UV–vis) spectroscopy spectrometer. Photocurrent measurements were carried out using a 150 W xenon lamp with an air-mass (AM) 1.5 filter. The performance of the solar cell based on the CdS nanowire (NW-CdS) film with 225 nm thickness and CdTe nanoparticle (NP-CdTe) film with 6 μm... 

The unsteady phenomena occur in rotors of helicopters, wind turbines and compressors. Investigation of the unsteady flow is a very important test, since it can affect and restrict the performance of rotors of helicopters and wind turbine's blades when operating at high angles of attack. Dynamic tests, such as pitching and plunging oscillations are one of the best methods for studying these phenomena due to the complexity of the unsteady flows. In analyzing the results of dynamic tests one must consider the interference effects of wind tunnel walls. Different investigations show that in dynamic tests, the interference effects of flow field around the model, wind tunnel walls and support of... 

Chatter in machining systems is a limiting factor of workpiece surface, tool and machine life and material removal rate. Because of this, studying and modeling of vibrations is very important in the machining. This study is much importer in the boring operation because boring bar's length to diameter ratio is very high and so it is very sensitive to vibrations. As we know, vibration characteristics of a machine change between its operating condition and its resting mode. Because of this it's better to study machine's vibrations when it's working. This study requires some methods that can find operating parameters of machine. The aim of this work is to find these parameters. For finding these... 

In the present work, one dimensional ZnO nanostructures were grown by seed-assisted hydrothermal method. Hydrothermal processing parameters were controlled to obtain ZnO nanorods with diameter lower than 120 nm. The products were characterized by FE-SEM, EDAX, XRD, PL, and ATR-FTIR analyses. ZnO nanoparticles were also synthesized via a simple solvothermal method and their photo peropeties were compared with onedimensional nanostructures. Thereafter dye-sensitized solar cells based on TiO2-ZnO double layer nanostructured film were fabricated. It was observed that DSSC efficiency increased with decreasing the thickness of the film. The highest efficiency of 2.41% was obtained  

Dye-sensitized solar cells (DSSCs) are Photoelectrochemical cells using wide band gap nanoporous oxide semiconductors sensitized by dye molecules. For achieving high efficiency DSSCs preparation of photoanode electrode with high surface aea which leads to adequate dye absorption is necessary. In order to achieve proper morphology, thickness, particles size and porosity, producing a TiO2 nano-structured paste is required. TiO2 powder was prepared using sol-gel method. following a calcination process at 300 degrees, XRD patterns showed presence of anatase and brookite structures with average crystallite size of 9 nm. Additives such as diethylene glycol, acetylacetone and Triton X-100 were used... 

In present work, hydroxyapatite nano-rods are synthesized using a simple sol-gel method with calcium nitrate and potassium dihydrogenphosphate as calcium and phosphorus precursors respectively and ammonia was used for adjusting the pH=9. To obtain rod shape hydroxyapaite powder, multi wall carbon nanotubes were added to the solution, nHA powder was calcinated at 60 and 450 ℃. In second step, chitosan-gelatin/nanoHA solution were prepared by blending chitosan and gelatin in different concentrations with nanoHA powder, then the solution was freeze dried to maintain a composite scaffold. The prepared HA powder and bio-composite scaffold were characterized by X-ray diffraction (XRD), field... 

The Mesoporous Titanium Dioxide film using Sol-Gel method and Evaporation-Induced Self-Assembly technique (EISA) was prepared. In this study, in order to employ the best coatings in anode electrode of dye-sensitized solar cell, different conditions of making this film, the effective parameters in final structure, and various methods of coating were analyzed. After optimizing the conditions of film creating, images of field emission scanning electron microscope (FESEM) proved the formation of a layer of mesoporous structure which thickness after three times of coating is about 1.5 micrometers. In order to increase the energy conversion efficiency of solar cells, a new formulation for... 

With development of nanotechnology in medicine, nanoparticles are used for detection of tumor and cancer biomarkers. Magnetic nanoparticles are widely used for therapeutic and diagnostic objectives, because of their biocompatibility, ease of preparation and strong magnetic properties. Genistein (C15H10O5) is a soy isoflavone which is used for its anti-cancer activities. It is used for inhibition of cell proliferation, cell growth, and tumor invasion. The aim of this study is to assess the impact of nano-conjugation of geinstein as chemotherapeutic agent against cancer. For preparation of typical iron oxide Nanoparticles, Magnetite nanoparticles were synthesized by coprecipitating iron (II)... 

In this study, application of a Magnetic Nanofluid consisting of Magnetite as Nanoparticle and Water as base fluid in DASC systems is investigated. The DASC system is modeled theoretically and behavior of such system is predicted.In this study a comparison between magnetite Nanofluid and some other common Nanofluids is conducted. The study shows that Magnetite Nanofluid has a better performance and efficiency than Water, Al2O3 Nanofluid and SiO2 Nanofluid. Also magnetite Nanofluid and TiO2 Nanofluid function are almost similar.Also effect of external magnetic field on the performance of magnetite Nanofluid is investigated. It is showed that when the magnetic Nanofluid is subjected to an... 

In this thesis, pure –known as T- and chromium doped titanium dioxide nanoparticles –known as -CTx- with different dopant atomic ratio (0.1 to 5 %at.) were synthesized using a facile, fast and efficient method. FESEM and XRD studies showed no morphologic and structural change via Cr doping of nanoparticles (size in the range of 20-30 nm). However, according to DRS analysis, Cr intrusion in TiO2 crystal structure, drastically reduced band gap energy of pure TiO2 from 3.14 eV to 1.81 eV for CT3 powder and improved absorption range of UV-Vis spectrum. Mott-Schottky plots indicated that, Cr doping, caused reduction in donor density of TiO2 and an upward shift in the conduction band edge.... 

Structure and morphology of titanium dioxide have an excessive effect on the photovoltaic properties of dye-sensitized solar cells (DSCs). Different approaches have been used to improve the efficiency of these cells. One is using a scattering layer. Studies have been shown that properties of scattering layer such as composition and morphology have great effect on photovoltaic properties of solar cell. In this project, the effect of cubic morphology of TiO2 as a scattering agent in photoanode of DSCs is studied. Titanium dioxide with various morphologies including nanoparticles, solid and hollow cubic structures have been synthesized by solvothermal and hydrothermal methods, respectively. The... 

Dye-sensitized solar cell (DSSCS) is the third-generation of solar cells based on semiconductors formed between a photo sensitized anode and counter cathode which make a photo electrochemical system. They haven’t been commercially marketed due to their lower efficiency than the previous generations. In order to achieve the higher efficiency, the electron injection and light absorption must be increased. One way to increase electron injection is doping the semiconductor with an external ion to reduce lattice band gap. In this work, we made powder and Nano-structured film of titanium dioxide doped with various molar ratios of Mg by the sol-gel process. The effect of Mg:Ti molar ratio on... 

A new strategy for enhancing the efficiency of TiO2 dye sensitized solar cells (DSSCs) doped with Ni ions with different molar percentages (i.e., 0, 0.5, 1, 5 and 10 mol%) was reported. The samples were prepared by sol-gel route and characterized by means of XRD, DRS, UV-visible, FESEM and photovoltaic measurment techniques. It was found that Ni-doped TiO2 nanoparticles had a mixture of anatase, rutile and brookite crystal structures. Moreover, the band gap energy was decreased with increasing Ni molar ratio, The highest cell efficiency of 5.4% was achieved for 1mol% Ni-doped TiO2, being 42% greater than that of pure TiO2 nanoparticles