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Dynamic NMR Study of Thibencarb (S-4-chlorobenzyl N,N-dimethyl Thiocarbamate)
, M.Sc. Thesis Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
In this project, rotational barrier of C-N bond in thiobencarb (S-alkyl thiocarbamate) has been studied by HNMR spectroscopy. All the spectra were taken at different temperatures, and then by simulation of bandshape broadening pattern, rate constants for all temperatures were calculated. SpinWorks software was used for the simulation of line shape broadening which has two bandshape simulator programs, DNMR and MEXICO. The obtained rate constants were used to calculate the thermodynamic parameters of activation (ΔG‡, ΔH‡, ΔS‡ and Ea). Experimental ΔG‡298 value for thiobencarb was calculated 15.11kcalmol-1 and 15.86 kCalmol-1 in chloroform and acetone solvents respectively. The computational...
Measuring Multidimensional Poverty Using Structural Equation Models
, M.Sc. Thesis Sharif University of Technology ; Souri, Davood (Supervisor)
Abstract
In order to measure poverty, researchers used to consider only the income and the financial aspect of poverty; however, further research has revealed that income in itself cannot be a proper and comprehensive index for measuring poverty, and other factors such as education, health, occupation, personal characteristics, cultural activities, political activities, etc. are also significant in determining the poverty index. Based on the information acquired from "household expenditure-income survey", this study tries to take into account all the factors affecting the poverty index, in four dimensions of economic well-being, capability, political participation and cultural participation. Poverty...
Rolling Contact Analysis of a Cylinder with a FGM Coated Half-Plane
, Ph.D. Dissertation Sharif University of Technology ; Adibnazari, Saeed (Supervisor)
Abstract
This study focuses on the mathematical modeling of the rolling contact problem of an FGM coating-substrate system. The first part presents the uncoupled rolling contact problem of an FGM coated half-plane under the assumption of a central stick zone with two slip zones of the same sign. Considering all possible stick/slip scenarios, the fully coupled rolling contact problem of a graded coating is given in the second part. Finally, the rolling contact problem of two elastically similar cylinders with graded coatings will be discussed. Generally, all mentioned problems can be solved in three consecutive steps. First, the governing equations of the relevant rolling contact problem are...
On the contact mechanics of a rolling cylinder on a graded coating. Part 1: Analytical formulation
, Article Mechanics of Materials ; Vol. 68, issue , 2014 , p. 207-216 ; Guler, M. A ; Adibnazari, S ; Sharif University of Technology
2014
Abstract
In this paper, the fully coupled rolling contact problem of a graded coating/substrate system under the action of a rigid cylinder is investigated. Using the singular integral equation approach, the governing equations of the rolling contact problem are constructed for all possible stick/slip regimes. Applying the Gauss-Chebyshev numerical integration method, the governing equations are converted to systems of algebraic equations. A new numerical algorithm is proposed to solve these systems of equations. Both the coupled and the uncoupled solutions to the problem are found through an implemented iterative procedure. In Part I of this paper, the analytical formulation of the rolling contact...
The effect of material property grading on the rolling contact stress field
, Article Mechanics Research Communications ; Vol. 55, issue , 2014 , p. 45-52 ; Guler, M. A ; Adibnazari, S ; Sharif University of Technology
2014
Abstract
This paper investigates the subsurface stress field induced by a rigid cylinder rolling over a functionally graded coating-substrate system. The Fourier transform is employed to extract the stress components within the graded coating and the homogeneous substrate. The distributions of the stresses are given through the depth and along the coating-substrate interface. The contour plots of normalized Von Mises stresses are provided as well. The results indicate that continuous variation of the shear modulus substantially reduces the difference between the in-plane stresses along the interface. Also, the softening coating leads to the minimum value of the stress concentration near the contact...
Tractive rolling contact mechanics of graded coatings
, Article International Journal of Solids and Structures ; Volume 49, Issue 6 , March , 2012 , Pages 929-945 ; 00207683 (ISSN) ; Adibnazari, S ; Alinia, Y ; Sharif University of Technology
2012
Abstract
In this study, the tractive rolling contact problem between a rigid cylinder and a graded coating is investigated. The main objective of this study is to investigate the effect of the stiffness ratio, the coefficient of friction and the coating thickness on the surface contact tractions, the surface in-plane stress, the stick zone length and the creep ratio parameter that may have a bearing on the fatigue life of the component. Assuming that the shear modulus varies exponentially through the thickness of the coating, the governing integral equations associated with the rolling contact problem are constructed. Furthermore, it is supposed that the contact patch is controlled by a central stick...
Maximizing quality of aggregation in delay-constrained wireless sensor networks
, Article IEEE Communications Letters ; Volume 17, Issue 11 , 2013 , Pages 2084-2087 ; 10897798 (ISSN) ; Yousefi, H ; Talebi, M. S ; Khonsari, A ; Sharif University of Technology
2013
Abstract
In this letter, both the number of participating nodes and spatial dispersion are incorporated to establish a bi-objective optimization problem for maximizing the quality of aggregation under interference and delay constraints in tree-based wireless sensor networks (WSNs). The formulated problem is proved to be NP-hard with respect to Weighted-sum scalarization and a distributed heuristic aggregation scheduling algorithm, named SDMAX, is proposed. Simulation results show that SDMAX not only gives a close approximation of the Pareto-optimal solution, but also outperforms the best, to our knowledge, existing alternative proposed so far in the literature
Rolling contact problem for an orthotropic medium
, Article Acta Mechanica ; Volume 228, Issue 2 , 2017 , Pages 447-464 ; 00015970 (ISSN) ; Zakerhaghighi, H ; Adibnazari, S ; Guler, M. A ; Sharif University of Technology
Springer-Verlag Wien
2017
Abstract
In this paper, the two-dimensional tractive rolling contact problem between a rigid cylinder and an orthotropic half plane is considered. A pair of singular integral equations is derived for the contact tractions using the Fourier transform technique. The governing integral equations are decoupled using the Goodman approximation and then solved numerically. Finally, the distribution of surface tractions is achieved in the contact region. This study emphasizes the significant effect of the orthotropic material parameters and the coefficient of friction on the contact tractions as well as the rolling contact characteristics for an orthotropic medium. © 2016, Springer-Verlag Wien
Metal-organic framework (MIL-100 (Fe)): synthesis, detailed photocatalytic dye degradation ability in colored textile wastewater and recycling
, Article Materials Research Bulletin ; Volume 100 , April , 2018 , Pages 357-366 ; 00255408 (ISSN) ; Abdi, J ; Oveisi, M ; Alinia Asli, M ; Vossoughi, M ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
In this paper, three metal-organic frameworks (Materials of Institut Lavoisier: MILs-100 (Fe)) as porous nanomaterials were synthesized using FeCl3, Fe(NO3)3 and Fe2(SO4)3 and denoted as MIL-100-1, MIL-100-2 and MIL-100-3, respectively. The synthesized MILs-100 (Fe) were characterized by FTIR, SEM, TEM, XRD, UV–vis DRS and zeta potential. Basic Blue 41 (BB41) was used as a model dye to study the photocatalytic dye degradation ability of the synthesized metal organic frameworks. The results showed that the synthesized nanomaterials decolorized BB41. The decolorization kinetics followed first-order kinetic model. The rate constant was 0.0034, 0.0041, 0.0091 and 0.0289 (1/min) for 0.01, 0.02,...
Brace-frame interaction in tension braced MRFs
, Article International Conference on Numerical Analysis and Applied Mathematics, ICNAAM 2008, Psalidi, Kos, 16 September 2008 through 20 September 2008 ; Volume 1048 , 2008 , Pages 364-367 ; 0094243X (ISSN); 9780735405769 (ISBN) ; Mofid, M ; Alinia, M. M ; Greek Ministry of Education and Religious Affairs; European Soc. Computational Methods in Sci. Eng. (ESCMSE) ; Sharif University of Technology
2008
Abstract
This study investigates the possibility of sequential failure analysis of Tension Braced Moment Resisting Frames (TBMRFs) by examining its performance in the linear and nonlinear stages under idealized seismic loading conditions. The results obtained from rigorous analyses by means of numerical methods are utilized to set up and calibrate an analytical model which would appropriately differentiate the contribution shares of the frame and the bracing elements. The paper provides information on key response parameters, including interaction value between frame and brace elements, as well as tensile strength capacity and ductility capability of such systems. © 2008 American Institute of Physics...
Microwave-induced Cannizzaro reaction over neutral γ-alumina as a polymeric catalyst [electronic resource]
, Article Reactive and Functional Polymers ; 01/2002; 51(1):49-53 ; Soleimanzadeh, B ; Marandi, G. B
Abstract
γ-Alumina is used to catalyze the Cannizzaro reaction in the absence of any base under microwave irradiation in high yields. In the case of terephthalaldehyde the reaction is carried out with high selectivity
SnCl4/SiO2: an efficient heterogeneous alternative for one-pot synthesis of β-acetamidoketones
, Article Journal of the Chinese Chemical Society ; Volume 56, Issue 2 , 2009 , Pages 386-391 ; 00094536 (ISSN) ; Mahmoodi Hashemi, M ; Sadeghi, B ; Emtiazi, H ; Sharif University of Technology
2009
Abstract
Enolizable ketones have been reacted in a one-pot method with aromatic aldehydes, acetyl chloride and acetonitrile at room temperature in the presence of SnCl4/SiO2 to furnish the corresponding β-acetamidoketones in improved yields. Acetylation of an aromatic hydroxyl group was observed while using 4-hydroxybenzaldehyde or vanillin and the corresponding β-acetamidoketones were isolated in an excellent yield
Turbulent flow in converging nozzles, part one: Boundary layer solution
, Article Applied Mathematics and Mechanics (English Edition) ; Volume 32, Issue 5 , 2011 , Pages 645-662 ; 02534827 (ISSN) ; Farhanieh, B ; Firoozabadi, B ; Sharif University of Technology
2011
Abstract
The boundary layer integral method is used to investigate the development of the turbulent swirling flow at the entrance region of a conical nozzle. The governing equations in the spherical coordinate system are simplified with the boundary layer assumptions and integrated through the boundary layer. The resulting sets of differential equations are then solved by the fourth-order Adams predictor-corrector method. The free vortex and uniform velocity profiles are applied for the tangential and axial velocities at the inlet region, respectively. Due to the lack of experimental data for swirling flows in converging nozzles, the developed model is validated against the numerical simulations. The...
Numerical investigation of steady density currents flowing down an incline using v2̄ - F turbulence model
, Article Journal of Fluids Engineering, Transactions of the ASME ; Volume 129, Issue 9 , 2007 , Pages 1172-1178 ; 00982202 (ISSN) ; Firoozabadi, B ; Farhanieh, B ; Sharif University of Technology
2007
Abstract
The governing equations of two-dimensional steady density currents are solved numerically using a finite volume method. The v2̄-f turbulence model, based on standard k - s model, is used for the turbulence closure. In this method, all Reynolds stress equations are replaced with both a transport equation for v2̄ and an elliptic relaxation equation for f, a parameter closely related to the pressure strain redistribution term. The Simple-C procedure is used for pressure-velocity coupling. In addition, Boussinesq's approximation is used to obtain the momentum equation. The computed height of the progressive density current is compared to the measured data in the literature, resulting in good...
Numerical simulation of turbid-density current using v2̄ - f turbulence model
, Article 2005 ASME International Mechanical Engineering Congress and Exposition, IMECE 2005, Orlando, FL, 5 November 2005 through 11 November 2005 ; Volume 261 FED , 2005 , Pages 619-627 ; 08888116 (ISSN); 0791842193 (ISBN); 9780791842195 (ISBN) ; Firoozabadi, B ; Farhanieh, B ; Sharif University of Technology
2005
Abstract
The deposition behavior of fine sediment is an important phenomenon, and yet unclear to engineers concerned about reservoir sedimentation. An elliptic relaxation turbulence model (v2̄ - f model) has been used to simulate the motion of turbid density currents laden whit fine solid particles. During the last few years, the v2̄ - f turbulence model has become increasingly popular due to its ability to account for near-wall damping without use of damping functions. In addition, it has been proved that the v2̄ - f model to be superior to other RANS methods in many fluid flows where complex flow features are present. Due to low Reynolds number turbulence of turbidity current,(its critical Reynolds...
Analytical solution for creeping motion of a viscoelastic drop falling through a Newtonian fluid
, Article Korea Australia Rheology Journal ; Vol. 26, issue. 1 , 2014 , pp. 91-104 ; ISSN: 1226119X ; Norouzi, M ; Firoozabadi, B ; Sharif University of Technology
2014
Abstract
In this paper, an analytical solution for steady creeping motion of viscoelastic drop falling through a viscous Newtonian fluid is presented. The Oldroyd-B model is used as the constitutive equation. The analytical solutions for both interior and exterior flows are obtained using the perturbation method. Deborah number and capillary numbers are considered as the perturbation parameters. The effect of viscoelastic properties on drop shape and motion are studied in detail. The previous empirical studies indicated that unlike the Newtonian creeping drop in which the drop shape is exactly spherical, a dimpled shape appears in viscoelastic drops. It is shown that the results of the present...
Theoretical and experimental study on the motion and shape of viscoelastic falling drops through Newtonian media
, Article Rheologica Acta ; Volume 55, Issue 11-12 , 2016 , Pages 935-955 ; 00354511 (ISSN) ; Norouzi, M ; Firoozabadi, B ; Sharif University of Technology
Springer Verlag
2016
Abstract
In this paper, creeping motion of a viscoelastic drop falling through a Newtonian fluid is investigated experimentally and analytically. A polymeric solution of 0.08 % xanthan gum in 80:20 glycerol/water and silicon oil is implemented as the viscoelastic drop and the bulk viscous fluids, respectively. The shape and motion of falling drops are visualized using a high speed camera. The perturbation technique is employed for both interior and exterior flows, and Deborah and capillary numbers are considered as perturbation parameters up to second order. The product of Deborah and capillary numbers is also used as a perturbation parameter to apply the boundary condition on the deformation on the...
Minimizing uplink delay in delay-sensitive 5G CRAN platforms
, Article 2nd IEEE 5G World Forum, 5GWF 2019, 30 September 2019 through 2 October 2019 ; 2019 , Pages 154-160 ; 9781728136271 (ISBN) ; Kanaanian, B ; Khalaj, B. H ; Sharif University of Technology
Institute of Electrical and Electronics Engineers Inc
2019
Abstract
In this paper, we consider the problem of minimizing the uplink delays of users in a 5G cellular network. Such cellular network is based on a Cloud Radio Access Network (CRAN) architecture with limited fronthaul capacity, where our goal is to minimize delays of all users through an optimal resource allocation. Earlier works minimize average delay of each user assuming same transmit power for all users. Combining Pareto optimization and Markov Decision Process (MDP), we show that every desired balance in the trade-off among infinite-horizon average-reward delays, is achievable by minimizing a properly weighted sum delays. In addition, we solve the problem in two realistic scenarios;...
Microwave-induced Cannizzaro reaction over neutral γ-alumina as a polymeric catalyst
, Article Reactive and Functional Polymers ; Volume 51, Issue 1 , 2002 , Pages 49-53 ; 13815148 (ISSN) ; Soleimanzadeh, B ; Marandi, G. B ; Sharif University of Technology
2002
Abstract
Microwave induced Cannizzaro reaction, which was performed in presence of neutral γ-alumina as a polymeric catalyst, was discussed. Cannizzaro reaction was carried out on alumina surface and other unknown products were also obtained. Solvent extraction method was utilized to isolate mild and selective benzyl alcohol and carboxylic acids
Feedback bit reduction for antenna selection methods in wireless systems
, Article 2005 13th IEEE International Conference on Networks jointly held with the 2005 7th IEEE Malaysia International Conference on Communications, Kuala Lumpur, 16 November 2005 through 18 November 2005 ; Volume 1 , 2005 , Pages 229-233 ; 1424400007 (ISBN); 9781424400003 (ISBN) ; Babadi, B ; Hossein Khalaj, B ; Sharif University of Technology
2005
Abstract
A well known method to reduce the intrinsic complexity of Multiple Input Multiple Output (MIMO) systems is to choose a subset of available antennas which have stronger links than the others, in order to perform the specified MIMO algorithm. The data resulted from the antenna selection process (at the receiver side) is sent back to the transmitter side via a feedback channel. There seems to be a need to reduce the number of feedack bits, specially when the number of antennas is not small. In this paper, we investigate the problem of reducing the number of feedback bits in antenna selection techniques. We've proposed two methods using vector quantization techniques to perform feedback bit...