Sharif Digital Repository

The efficient catalytic systems were investigated for the oxidation of various sulfide by manganese(III)-oxazoline complexes, [Mn(phox)2(MeOH)2]ClO4 and Mn(phox)3 (Hphox = 2-(2′-hydroxyphenyl)oxazoline). These complexes were found efficient catalysts for the oxidation of sulfides with urea hydrogen peroxide (UHP) in short reaction times (5 min) and under mild condition. Sulfoxides were obtained as the main products together with variable amounts of sulfones. The efficiency of the catalytic system was strongly influenced by the nature of solvents and axial ligands so the best yields were achieved in a mixture of methanol: dichloromethane and in the presence of imidazole as co-catalyst. © 2008... 

This paper presents results from a series of constant normal load direct shear tests on artificially created rock joints, in an attempt to quantify the effects of different factors that contribute to the shear strength along "ideal" rock joints. Particular focus is given to the effect of asperity orientation with respect to the direction of shearing. In many historical rock joint shear strength criteria, the effect of a joint's roughness on the joint shear strength is described based on analysis of only a single profile in the direction of shearing. More recent studies have observed that the distribution of sheared area on a joint surface during shear is significantly affected by the... 

An oxido-peroxido tungsten(VI) complex [WO(O2)L(CH 30H)] using salicylidene benzoyl hydrazine as a tridentate ONO donor Schiff base (H2L) has been synthesized and characterized by elemental analysis, IR, 1H NMR, molar conductance data, and single-crystal X-ray analysis. The complex was used as a catalyst for epoxidation of olefins and oxidation of sulfides. The results show that epoxides and sulfoxides were produced in high yield, turnover number, and selectivity  

The reactions of FeCl3·3H2O and 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (N-O) as a bidentate O, N donor ligand afforded a five-coordinated iron(III) complex, [Fe(N-O) 2Cl], with a distorted trigonal bipyramidal configuration. The complex [Fe(N-O)2Cl] was isolated as an air-stable crystalline solid and was fully characterized, including by single-crystal X-ray structure analysis. The complex [Fe(N-O)2Cl] shows very efficient reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide (UHP) as the oxidant at room temperature under air. To get an insight into the electronic structure of the complex, the experimental studies have been accompanied... 

A novel binuclear iron(III)-salicylaldazine complex has been synthesized and characterized by various techniques such as IR and UV–Vis spectroscopy and X-ray crystallography. The catalytic oxidation of sulfides in the presence of the aforementioned complex was explored at room temperature using urea hydrogen peroxide (UHP) as an oxidant. Effects of different reaction conditions consisting catalyst and oxidant amount, solvent effect and reaction time on the catalytic activity and selectivity in the reaction of methylphenylsulfide oxidation has been surveyed. Perfect selectivity toward sulfoxide was achieved after 15 min in CH3CN by choice of a properly optimized reaction condition. © 2020... 

The reaction of a solution of MoO2(acac)2 in CH3OH and salicylidene 2-picoloyl hydrazone as a tridentate ONO donor Schiff base (ONO) afford a six-coordinated Mo(VI) complex [MoO2(ONO)(CH3OH)], with a distorted octahedral configuration. [MoO2(ONO)(CH3OH)] was isolated as an air-stable crystalline solid and fully characterized by single-crystal X-ray structure analysis. [MoO2(ONO)(CH3OH)] shows reactivity in the oxidation of sulfides to their corresponding sulfoxides using urea hydrogen peroxide as the oxidant at room temperature under air  

A new mononuclear molybdenum(VI)-oxodiperoxo complex [MoO(O 2)2(phox)] with a simple bidentate ligand, 2-(2′-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (Hphox), has been synthesized and characterized by X-ray structure analysis, elemental analysis, infrared, and 1H NMR spectroscopy. A triclinic space group P-1 was determined by X-ray crystallography from single-crystal data of this complex. The resulting complex functioned as a facile sulfide oxidation catalyst with urea hydrogen peroxide as terminal oxidant at room temperature. The catalyst showed efficient reactivity in oxidation of sulfides giving high yield and selectivity  

A five-coordinated Fe(III) complex with the distorted trigonal bipyramidal configuration was synthesized by reactions of FeCl36H2O and 2-(2′-hydroxyphenyl)oxazoline (Hphox) as a bidentate ON donor oxazoline ligand. Complex [Fe(phox)2Cl] was fully characterized, including by single-crystal X-ray structure analysis. DFT calculations were accompanied with experimental results in order to obtain a deeper insight into the electronic structure and vibrational normal modes of complex. Oxidation of sulfides to sulfoxides in one-step was conducted by this complex as catalyst using urea hydrogen peroxide (UHP) in mixture of CH2Cl 2/CH3OH (1:1) under air at room temperature. The results show that using... 

(A) Chakraborty and co-workers have developed a green method for the bulk ring-opening polymerization of lactides in the presence of Cu(OAc)2 as a good catalyst to synthesize polymers with different end-terminal groups.3 These polymerizations are highly controlled leading to the formation of polymers with the expected number of average molecular weights and narrow molecular weight distribution. (B) Garden and co-workers have found that the oxidative addition of anilines with 1,4-naphthoquinone to give N-aryl-2-amino-1,4-naphthoquinones can be performed in the presence of catalytic amounts of copper(II) acetate.4 All the reactions are generally more efficient in that they are cleaner, higher... 

In mathematical programming, an important tool is the use of active set strategies to update the current solution of a linear system after a rank one change in the constraint matrix. We show how to update the general solution of a linear system obtained by use of the scaled ABS method when the matrix coefficient is subjected to a rank one change. © Australian Mathematical Society 2004  

A new manganese(III) complex [(N-O)2Mn(OAc)] was synthesized using 2-(2'-hydroxyphenyl)-5,6-dihydro-1,3-oxazine (N-O) as a bidentate O, N donor. The complex has been characterized by elemental analysis, IR, UV-vis spectroscopy, and X-ray structure analysis. Oxidation of sulfides and epoxidation of olefins, respectively, to their corresponding sulfoxides and epoxides were conducted by this catalyst using urea hydrogen peroxide as oxidant at room temperature under air. The catalyst is efficient in oxidation reactions giving high yields and selectivities  

Tetra-coordinated copper(II) complexes, [CuL2] and [Cu(phox)2], were synthesized by reaction of 1-((4-bromophenylimino)methyl)naphthalen-2-ol, HL, and 2-(2′-hydroxyphenyl)-2-oxazoline, Hphox, ligands with copper acetate, respectively. The complexes were characterized using FT-IR spectroscopy, elemental analyses, and their solid state structures were confirmed by single crystal X-ray diffraction. The catalytic activity of the complexes was evaluated in one-pot azide–alkyne cycloaddition (AAC) click reaction in water without need of any additional agent. The [CuL2] complex showed high catalytic activity in this reaction‌‌‌ and 1,2,3-triazole derivatives were produced in moderate to good... 

Synthesis of dextran-graft-poly(hydroxyethyl methacrylate) gels as a new fluoride biosorbent was considered in this work. For this propose, the Taguchi experimental design method was used for optimizing the synthetic conditions of the gels to reach high level of fluoride absorbency. The effects of three main parameters including concentrations of monomer (hydroxyethyl methacrylate), crosslinking agent (ethylene glycol dimethacrylate), and initiator (ammonium persulfate) on the final properties of the prepared gels were investigated. The proposed mechanism for grafting and chemically crosslinking reactions was proved with equilibrium water absorption, Fourier-transformed infrared, scanning... 

A novel biopolymer-based superabsorbent hydrogel was synthesized through chemical crosslinking by graft copolymerization of partially neutralized acrylic acid onto the hydrolyzed collagen, in the presence of a crosslinking agent and a free radical initiator. The Taguchi method, a robust experimental design, was employed for the optimization of the synthesis reaction based on the swelling capacity of the hydrogels. This method was applied for the experiments and standard L16 orthogonal array with three factors and four levels were chosen. The critical parameters that have been selected for this study are crosslinker (N,N′-methylene bisacrylamide), initiator (potassium persulfate), and monomer... 

We adopt an innovation-driven framework and investigate the sparse/compressible distributions obtained by linearly measuring or expanding continuous-domain stochastic models. Starting from the first principles, we show that all such distributions are necessarily infinitely divisible. This property is satisfied by many distributions used in statistical learning, such as Gaussian, Laplace, and a wide range of fat-tailed distributions, such as student's-t and α-stable laws. However, it excludes some popular distributions used in compressed sensing, such as the Bernoulli-Gaussian distribution and distributions, that decay like exp (-O(|x|p)) for 1 < p < 2. We further explore the implications of... 

In this paper, we establish the connection between the Orthogonal Optical Codes (OOC) and binary compressed sensing matrices. We also introduce deterministic bipolar m × n RIP fulfilling ± 1 matrices of order k such that m ≤ script O sign (k(log2 n) log2 k/ln log2 k). The columns of these matrices are binary BCH code vectors where the zeros are replaced by -1. Since the RIP is established by means of coherence, the simple greedy algorithms such as Matching Pursuit are able to recover the sparse solution from the noiseless samples. Due to the cyclic property of the BCH codes, we show that the FFT algorithm can be employed in the reconstruction methods to considerably reduce the computational... 

Semantic technology is widely used in distributed computational environments to increase interoperability and machine readability of information through giving semantics to the underlying information and resources. Semantic-awareness, distribution and interoperability of new generation of distributed systems demand an authorisation model and framework that satisfies essential authorisation requirements of such environments. In this study, the authors propose an authorisation model and framework based on multi-security-domain architecture for distributed semantic-aware environments. The proposed framework is founded based on the MA(DL)2 logic, which enables policy specification and inference... 

Deep structures consisting of many layers of nonlinearities have a high potential of expressing complex relations if properly initialized. Autoencoders play a complementary role in training a deep structure by initializing each layer in a greedy unsupervised manner. Due to the high capacity presented by autoencoders, these structures need to be regularized. While mathematical regularizers (based on weight decay, sparsity, etc.) and structural ones (by way of, e.g., denoising and dropout) have been well studied in the literature, quite a few papers have addressed the problem of training autoencoder with non-smooth regularization. In this paper, we address the problem of training autoencoder... 

It has been shown that more accurate signal recovery can be achieved with low-coherence dictionaries in sparse signal processing. In this Letter, the authors extend the low-coherence attribute to receptive fields in convolutional neural networks. A new constrained formulation to train low-coherence convolutional neural network is presented and an efficient algorithm is proposed to train the network. The resulting formulation produces a direct link between the receptive fields of a layer through training procedure that can be used to extract more informative representations from the subsequent layers. Simulation results over three benchmark datasets confirm superiority of the proposed... 

Deep neural networks have presented superlative performance in many machine learning based perception and recognition tasks, where they have even outperformed human precision in some applications. However, it has been found that human perception system is much more robust to adversarial perturbation, as compared to these artificial networks. It has been shown that a deep architecture with a lower Lipschitz constant can generalize better and tolerate higher level of adversarial perturbation. Smooth regularization has been proposed to control the Lipschitz constant of a deep architecture and in this work, we show how a deep convolutional neural network (CNN), based on non-smooth regularization...