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    Characterization of Plasma Etching Process Using Plasmonic Structures

    , M.Sc. Thesis Sharif University of Technology Arian, Kiarash (Author) ; Rashidian, Bizhan (Supervisor)
    Abstract
    plasma characterization has become an essential tool for characterization of etching process in fabrication of nano-electronic devices. The existing methods, such as Langmuir probe and interferometry, have shown drawbacks including disturbing the plasma and sensitivity to mechanical and thermal stability of the measuring systems. In recent years, due to the scale down of microelectronic devices and increase of their sensitivity to disturbance in the plasma etching process, a demand for measuring methods offering less disturbance has arisen. Plasmonic structures, owing to their unprecedented field enhancement and confinement, have been extensively studied. Their sub-wavelength dimensions,... 

    An Integrated Multi-criteria Decision Making Approach for a Sustainable Supply Chain Network Design

    , M.Sc. Thesis Sharif University of Technology Arian, Ebrahim (Author) ; Shavandi, Hassan (Supervisor)
    Abstract
    Growing concerns towards social and environmental issues besides economic in supply chain causes that the sustainable supply chain become one of the most important concepts in a supply chain. Likewise, a supply chain network design which is profound influence on long-run economic, environmental, and social decisions is one of the key and strategic topics in a supply chain. In this study, we represent an integrated approach for a three-layer sustainable supply chain network design with routing and different transportation modes, the objectives of which are minimizing total costs, a minimizing 〖CO〗_2 emissions of transportation, and maximizing total values of social purchasing. In this... 

    Pathwise grid valuation of fixed-income portfolios with applications to risk management

    , Article Heliyon ; Volume 8, Issue 7 , 2022 ; 24058440 (ISSN) Zamani, S ; Chaghazardi, A ; Arian, H ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Numerical calculation of Value-at-Risk (VaR) for large-scale portfolios poses great challenges to financial institutions. The problem is even more daunting for large fixed-income portfolios as their underlying instruments have exposure to higher dimensions of risk factors. This article provides an efficient algorithm for calculating VaR using a historical grid-based approach with volatility updating and shows its efficiency in computational cost and accuracy. Our VaR computation algorithm is flexible and simple, while one can easily extend it to cover other nonlinear portfolios such as derivative portfolios on equities and FX securities. © 2022  

    Optimization of the Capability of Native Microorganisms Isolated from the Landfill of Electronic Wastes in Bioleaching of E-Waste

    , M.Sc. Thesis Sharif University of Technology Arab, Bahareh (Author) ; Yaghmaei, Soheila (Supervisor)
    Abstract
    Given the complex structure of electronic waste and the difficulty of recycling it by traditional methods, the focus is mainly on biohydrometallurgy method, and in particular on bioleaching. To recover metals, various microorganisms are utilized in this method. In light of previous studies, cyanogenic bacteria have been widely used for the extraction of basic and precious metals. Among the species, indigenous microorganisms have a higher ability to resist toxic environments in the bioleaching of metals due to their adaptation by rapid changes in their metabolic system over time. The main objective of this study is to isolate indigenous microorganisms from electronic waste landfill for their... 

    Formulation and Properties of Scaffolds based on Hydroxyapatite Composites Containing Titanium Dioxide and Magnesium Oxide

    , M.Sc. Thesis Sharif University of Technology Arab, Mehdi (Author) ; Nemati, Ali (Supervisor)
    Abstract
    This study investigates the effect of titanium dioxide and magnesium oxide additives on hydroxyapatite synthesized by sol-gel and composite with the predominant phase of hydroxyapatite by in situ method to improve mechanical properties. Scaffold samples were synthesized with nanometer-sized hydroxyapatite and composite powder particles by gel casting and sintered at 1200 ° C. Then, to evaluate the synthesized powders, simultaneous thermal analysis (STA), X-ray diffraction test, FTIR test, FESEM, EDS, and MAP analysis were used. Also, to evaluate the mechanical properties of the scaffolds, a compressive test was used, and to evaluate the scaffolds' density, the Archimedes method was used.... 

    Climate Change and Mortality: Evidence from Iran

    , M.Sc. Thesis Sharif University of Technology Arab, Pouya (Author) ; Vesal, Mohammad (Supervisor)
    Abstract
    Due to the prominence of the evaluation of the consequences of rising temperatures, this paper examines the effects of temperature variation on mortality across different demographic groups in Iran. I use a rich weekly data set from 2009 to 2017 across different demographic groups to understand the potential health impacts of climate change in a developing country. Using several fixed effect regressions, I discover that for an additional day with a mean temperature over 25°C, mortality rate increases by 2.56% relative to the effects of an extra day in 0-5 °C, in the weekly temperature exposure horizon. I test for the harvesting effect by comparing the estimates at weekly and monthly... 

    Prediction of Flow Profiles in Different Well Layers using Fiber Optic Data Analysis

    , M.Sc. Thesis Sharif University of Technology Arab, Alireza (Author) ; Bazargan, Mohammad (Supervisor)
    Abstract
    Downhole temperature measurement is one of the key tools for monitoring and analyzing the performance of production wells, evaluating water injection, and identifying multiphase flows within wells. The development of fiber optic technology and tools such as distributed temperature sensors has enabled the recording of high-resolution and detailed temperature profiles. These data, which measure temperature over a wide range along the wellbore, allow researchers to analyze complex downhole processes and identify fluid entry from various reservoir layers. However, accurately distinguishing the contribution of each layer to the total flow rate, especially under multiphase flow conditions and... 

    Fermionic Approach To The One Dimensional Kondo Necklace Model

    , M.Sc. Thesis Sharif University of Technology Arab, Arian (Author) ; Langari, Abdollah (Supervisor)
    Abstract
    Strongly correlated materials are kind of materials in which novel electric and magnetic properties will appear as a result of strong correlations among their electrons like “heavy fermion materials”. Kondo lattice model is a model to describe heavy fermion materials. If we are merely interested in the magnetic properties of heavy fermions we can replace the Kondo lattice Model with the simpler model called the Kondo-necklace model which consists of the interactions only among the spins of the itinerant (conduction) and localized electrons (magnetic impurities) and also the interactions between the spins of the itinerant electrons. In this thesis we investigate the properties of the one... 

    Experimental Study of Oxygen Reduction Reaction (ORR) on Cu-alloys, Electrocatalysts in Alkaline Solution and Theoretical Investigation of Oxygen Adsorption on Cu-alloys Nano-clusters

    , Ph.D. Dissertation Sharif University of Technology Arab, Ramezan (Author) ; Gobal, Fereydoon (Supervisor)
    Abstract
    In this study, electrochemical oxygen reduction reaction (ORR) was studied on Cu, Pd, Rh, Pd-Cu and Rh-Cu alloys in alkaline solution. Pd-Cu and Rh-Cu alloys were prepared by electrochemical methods. On copper electrode it is found that direct oxygen reduction is accompanied by the electrochemical reductions of copper oxides. Also, mechanism and kinetics of reaction change as the amount of copper oxides increase on the surface. For electrodeposited alloys, it is indicated that the reactivity of Pd-Cu and Rh-Cu alloys toward oxygen reduction is higher than pure Pd and pure Rh. The maximum reactivity among Pd-Cu alloys is related to the sample with 24.5% copper content while the maximum... 

    Cavity Quantum Electro-Dynamics in Ultra-Strong Coupling Regime

    , M.Sc. Thesis Sharif University of Technology Arab, Abbas (Author) ; Khorasani, Sina (Supervisor)
    Abstract
    Cavity Quantum Electro-Dynamics (CQED) in Weak, Strong and Ultra-Strong coupling Regimes are studied. A MATLAB m-file is written which is able to solve any arbitrary CQED configuration. This program demands input data such as number of Quantum Dots, number of energy levels of each Quantum Dot, energies of each energy level of Quantum Dots, Number of cavity modes, eign-frequency of each cavity mode, coupling constant, dipole strength of each allowed transition of Quantum Dots and initial state of system from user and begins to solve the Schrodinger equation for annihilation and atomic ladder operators. In addition, coefficients of each possible ket will be calculated. Since, any approximation... 

    Synthesis and Characterization of Bis[2-(2׳-Hydroxyphenyl)- -oxazolinato]Ni(II) Complex and Investigation of it׳s Catalytic Activity in C-C Coupling Heck Reaction

    , M.Sc. Thesis Sharif University of Technology Arab, Zeynab (Author) ; Bagherzadeh, Mojtaba (Supervisor)
    Abstract
    In this study a new Ni(II)-¬oxazoline complex was synthesized by reaction of Ni(CH3COO)2.4H2O and 2-(2׳-hydroxyphenyl)-2-oxazoline ligand in MeOH solvent. The resulting complex bis[2-(2׳-hydroxyphenyl)-2-oxazolinato]Ni(II), was characterized by different spectroscopic methods. X-ray diffraction showed that this complex is four coordinated with a square planner geometry. The complex was applied as an efficient homogeneous catalyst in C-C coupling Heck reaction of arylhalides with olefins such as methylacrylate. Investigation of the catalytic activity of the complex in Heck reaction between arylhalides and olefins showed high yield and selectivity. For example reaction between iodobenzene and... 

    Portfolio Value-at-Risk and expected-shortfall using an efficient simulation approach based on Gaussian Mixture Model

    , Article Mathematics and Computers in Simulation ; Volume 190 , 2021 , Pages 1056-1079 ; 03784754 (ISSN) Seyfi, S. M. S ; Sharifi, A ; Arian, H ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Monte Carlo Approaches for calculating Value-at-Risk (VaR) are powerful tools widely used by financial risk managers across the globe. However, they are time consuming and sometimes inaccurate. In this paper, a fast and accurate Monte Carlo algorithm for calculating VaR and ES based on Gaussian Mixture Models is introduced. Gaussian Mixture Models are able to cluster input data with respect to market's conditions and therefore no correlation matrices are needed for risk computation. Sampling from each cluster with respect to their weights and then calculating the volatility-adjusted stock returns leads to possible scenarios for prices of assets. Our results on a sample of US stocks show that... 

    Customer Churn Prediction in Therapy Policy in Iran

    , M.Sc. Thesis Sharif University of Technology Khosravi, Mahnaz (Author) ; Aslani, Shirin (Supervisor) ; Arian, Hamidreza (Supervisor)
    Abstract
    Using customer relationship management systems has led to the formation of databases containing businesses customer information. Increased competition in the markets, limited resources and high costs of attracting new customers compared to retaining existing customers have made customer retention an inevitable subject for business owners. Meanwhile, insurance companies, which due to their long history have suitable databases of product information and their customers, have resorted to using their databases to manage the relationship with their customers. In this research, while predicting customers churn in health insurance, as one of the most widely used products of domestic insurance... 

    Comparative evaluation of advanced gas turbine cycles with modified blade cooling models [electronic resource]

    , Article Proceedings of the ASME Turbo Expo ; Volume 4, Pages 537-546 , 2006 Tabari, A ; Sharif University of Technology
    2006
    Abstract
    Advanced gas turbine cycles use advanced blade cooling technologies to reach high turbine inlet temperature. Accurate modeling and optimization of these cycles depend on blade cooling model. In this study, different models have been used to simulate gas turbine performance. The first model is the continuous model and the second is stage-by-stage model with alternative methods for calculating coolant, stagnation pressure loss and SPR. Variation of specific heat and enthalpy with temperature are included in both models. The composition of gas stream in turbine is changed step by step due to air cooling. These models are validated by two case study gas turbine results, which show good agreement... 

    Estimation of a Portfolio's Value-at-Risk Using Variational Auto-Encoders

    , M.Sc. Thesis Sharif University of Technology Moghimi, Mehrdad (Author) ; Arian, Hamidreza (Supervisor) ; Talebian, Masoud (Supervisor)
    Abstract
    One of the most crucial aspects of financial risk management is risk measurement. Advanced AI-based solutions can provide the proper tools for assessing global markets, given the complexity of the global economy and the violation of typical modeling assumptions. A new strategy for quantifying stock portfolio risk based on one of the machine learning models known as Variational Autoencoders is provided in this dissertation. The suggested method is a generative model that can learn the stocks' dependency structure without relying on assumptions about stock return covariance and produce various market scenarios using cross-sectional stock return data with a higher signal-to-noise ratio. We... 

    Adsorption and dissociation of hydrogen peroxide on small Pd xM3-x (M = Pt, Cu; X = 1-3) clusters: A hybrid density functional study

    , Article Molecular Physics ; Volume 109, Issue 14 , May , 2011 , Pages 1797-1804 ; 00268976 (ISSN) Nahali, M ; Gobal, F ; Arab, R ; Sharif University of Technology
    2011
    Abstract
    The adsorption and dissociation of H2O2 on small PdxM3-x (M=Pt, Cu; x = 1-3) clusters is investigated using the B3PW91 hybrid density functional method. Natural bond orbitals are analysed to obtain partial charges on atoms, dipole moments, bond orders, and hybrid orbitals of the PdxM3-x-H2O2 systems. The calculated adsorption energies are in the range of -0.32 to -2.12 eV. Generally, H2O2 adsorbs on top positions through one of its oxygen atoms and only in a few cases reacts with the cluster through both oxygen and hydrogen sides. In the latter case the cluster sites which are negatively charged interact with the hydrogen atoms. Interestingly, on the triplet Pd2Pt cluster, H2O2 dissociates... 

    Determination of antioxidant component and activity of rice bran extract

    , Article Scientia Iranica ; Volume 18, Issue 6 , December , 2011 , Pages 1402-1406 ; 10263098 (ISSN) Arab, F ; Alemzadeh, I ; Maghsoudi, V ; Sharif University of Technology
    2011
    Abstract
    Rice bran is one of the most important co-products in the rice milling. In this research, antioxidant activity of two Iranian rice bran varieties, Fajr and Tarem, extracted by three different solvents (methanol, ethanol and ethyl acetate) was evaluated. The order of antioxidant activity was evaluated by measurement of total phenolic content, antioxidant activity in linoleic acid system, reducing power and scavenging capacity by DPPH radical. The methanolic extract of Fajr rice bran showed a total phenolic content of 3.31 mg Gallic acid/gr rice bran and a DPPH free radical-scavenging activity of 93.91%, achieved at 50 mg/ml concentration, and a percent inhibition of linoleic acid peroxidation... 

    DFT study of nitrogen monoxide adsorption and dissociation on Rh[sbnd]Cu nano clusters

    , Article Journal of Alloys and Compounds ; Volume 695 , 2017 , Pages 1924-1929 ; 09258388 (ISSN) Arab, A ; Nahali, M ; Gobal, F ; Sharif University of Technology
    2017
    Abstract
    Adsorption and dissociation of NO on RhxCu4-x(x = 0–4) nano clusters were investigated using density functional theory. Adsorption energy, total charge on NO, NO bond length, and NO vibrational frequency for various modes of NO adsorption were analyzed. Adsorption from the nitrogen end of NO on the Rh atom(s) of the clusters are more favored and adsorption energies are in the −1.02 eV to −2.59 eV range. NO binds stronger to Rh-Cu mixed clusters compared to pure Cu4 cluster, so N[sbnd]O bond is significantly weakened upon adsorption on the former. NO binding to more atoms of the clusters results in a corresponding decrease of the N[sbnd]O vibrational frequency. Dissociation of NO was also... 

    Effect of Equal Channel Angular Pressing(ECAP) Parameters on Microstructure and Mechanical Properties of Strip Samples of AZ31 Mg Alloy

    , M.Sc. Thesis Sharif University of Technology Arab, Mohammad (Author) ; Akbarzadeh Changiz, Abbas (Supervisor)
    Abstract
    Equal Channel angular pressing (ECAP) is one of the most applicable Severe Plastic Deformation (SPD) Procedures which results in improvement of strength and ductility through grain refinement and an appropriate texture development. In this study, in order to achieve a proper orientation and microstructure, ECAP was performed in different routes and temperatures up to 4 passes on AZ31 magnesium alloy. Microstructure and mechanical properties were studied. X-ray diffraction analysis was performed to study the basal orientation variation and calculation of sub-grain size. In addition, cold rolling at room temperature was done on the fourth pass specimens, in order to study the effect of ECAP... 

    A Hybrid Simulated Annealing Algorithm For Winner Determination problem In Combinatorial Auction

    , M.Sc. Thesis Sharif University of Technology Arab Momeni, Mojtaba (Author) ; Kianfar, Farhad (Supervisor)
    Abstract
    One of the most important issues that an organization faced with is resource management. The proper resource management has the great rule in organization cost reduction. One of the most efficient processes in resource allocation is auction and there is different auction with different mechanism and goals. In an auction there is a set of items and a set of bids, and the task of auctioneer is matching items with suitable bids. Each bid consist of desirable items and the bidder value of that items. In an auction process, after mechanism design of auction and auction implementation we must identify the winners of auction and this is a hard problem even in simple auction.
    In this study we...